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The crystal structures of chiral (R/S) (C8H11N)2·CuCl2

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Abstract

Two opposite configuration (R/S) of chiral complexes (C8H11N)2·CuCl2 were obtained from the reaction of chiral d(+)/l(−)-α-ethylphenyl amine with copper chloride (II) in dry ethanol. The crystal structures of 1a and 1b were characterized by IR, elemental analysis and X-ray crystallography.

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References

  1. Y. Zhang, X.G. Meng, Z.R. Liao, D.F. Li, C.L. Liu, J. Coord. Chem. 62, 876–885 (2009)

    Article  CAS  Google Scholar 

  2. I.V. Shishkov, F. Rominger, P. Hofmann, Organometallics 28, 1049–1059 (2009)

    Article  CAS  Google Scholar 

  3. C. Tan, X.H. Liu, L.W. Wang, J. Wang, X.M. Feng, Org. Lett. 10, 5305–5308 (2008)

    Article  CAS  Google Scholar 

  4. K. Watanabe, T. Hirasawa, K. Hiroi, Chem. Pharm. Bull. 50, 50372–50379 (2002)

    Google Scholar 

  5. M. Luo, L. Jiang, S.T. Liu, Inorg. Chem. Commun. 13(9), 1009–1013 (2010)

    Article  Google Scholar 

  6. M. Luo, B. Yan, Tetrahedron Lett 51(42), 5577–5580 (2010)

    Article  CAS  Google Scholar 

  7. G.M. Sheldrick, SHELXS-97, program for X-ray crystal structure solution (Göttingen University, Germany, 1997)

    Google Scholar 

  8. G.M. Sheldrick, SHELXL-97, program for X-ray crystal structure refinement (Göttingen University, Germany, 1997)

    Google Scholar 

  9. G.H. Stout, L.H. Jensen, X-ray structure determination: a practical guide (MacMillan, New York, 1968)

    Google Scholar 

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Correspondence to Luo Mei.

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Mei, L., Jie, S., Shi-Ming, Z. et al. The crystal structures of chiral (R/S) (C8H11N)2·CuCl2 . Res Chem Intermed 36, 1049–1054 (2010). https://doi.org/10.1007/s11164-010-0218-2

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  • DOI: https://doi.org/10.1007/s11164-010-0218-2

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