Skip to main content
Log in

Proton magnetic resonance and the state of hydrogen in beryllium hydroxide

  • Published:
Refractories and Industrial Ceramics Aims and scope

Abstract

Proton magnetic resonance spectra of beryllium hydroxide β-Be(OH)2 and products of its thermal decomposition are studied at room temperature and 123 K. It is shown, based on these spectra and differential thermal analysis and x-ray diffractometry data, that, heated to above 500 K, β-Be(OH)2 decomposes into a finely dispersed BeO and H2O to convert finally to an amorphous beryllium oxyhydroxide. At above 600 K, a crystalline BeO is formed involving dehydration of the finely dispersed BeO and amorphous oxyhydroxide phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. V. Jaski, R. Jain, K. K. Pandya, et al., “Compton profile study of bonding in BeO,” Chem. Phys., 111(1), 163–167 (1999).

    Google Scholar 

  2. J. E. Jaffe and P. Zapol, “Atomic relaxation of the BeO (1010) surface,” Surface Science, 381, 563–567 (1997).

    Article  Google Scholar 

  3. P. E. Van Camp and P. E. van Doren, “Ground state properties and structural phase transformations of beryllium oxide,” J. Phys.: Condens. Matter, 8, 3385–3390 (1996).

    Article  Google Scholar 

  4. R. M. Kolenkova, T. D. Blistanova, R. M. Bakasheva, and A. V. Zakirova, “A study of the physicochemical properties of Beryllium hydroxide,” Izv, Vyssh. Uchebn. Zaved. Tsvent. Metall., No. 4, 82–85 (1973).

  5. S. V. Bleshinskii, V. F. Abramova, N. G. Druzhinin, et al., Chemistry of Beryllium [in Russian], AN Kirg. SSR, Frunze (1955).

    Google Scholar 

  6. N. Narai-Szabo, Inorganic Crystal Chemistry, Hungarian Academy of Science, Budapest (1969).

    Google Scholar 

  7. S. P. Gabuda, R. N. Pletnev, and M. A. Fedotov, Nuclear Magnetic Resonance in Inorganic Chemistry [in Russian], Nauka, Moscow (1988).

    Google Scholar 

  8. Minerals. Handbook, Vol. 2, Issue 3 (eds. F. V. Chukhov and É. M. Bonshted-Kupletskaya) [in Russian], Nauka, Moscow (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Novye Ogneupory, No. 7, pp. 39–41, July, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pletnev, R.N., Kiiko, V.S., Makurin, Y.N. et al. Proton magnetic resonance and the state of hydrogen in beryllium hydroxide. Refract Ind Ceram 46, 273–275 (2005). https://doi.org/10.1007/s11148-006-0023-z

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11148-006-0023-z

Keywords

Navigation