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Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals

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Abstract

Electron spin resonance spectra of non-Kramers bivalent iron (Fe2+) ions have been detected in synthetic and natural beryl crystals with an iron impurity. The observed ESR spectra have been attributed to resonance transitions of Fe2+ ions from the ground (singlet) state to excited (doublet) levels with the splitting Δ = 12.7 cm–1 between the levels. The experimental angular and frequency dependences of the resonance field of the ESR signal have been described by the spin Hamiltonian with the effective spin S = 1. The analysis of the ESR data and optical absorption spectra indicates that the Fe2+ ions are situated in tetrahedral positions and substitute Be2+ cations in the beryl structure.

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Authors and Affiliations

  1. Kazan Physicotechnical Institute, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

    G. S. Shakurov & R. I. Khaibullin

  2. Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. G. Tomas, D. A. Fursenko & R. I. Mashkovtsev

  3. Kazan (Volga region) Federal University, Kazan, Russia

    O. N. Lopatin & A. G. Nikolaev

  4. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russia

    B. P. Gorshunov & E. S. Zhukova

  5. Moscow Institute of Physics and Technology (State University), Dolgoprudnyi, Moscow region, 141700, Russia

    B. P. Gorshunov & E. S. Zhukova

Authors
  1. G. S. Shakurov
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  2. R. I. Khaibullin
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  3. V. G. Tomas
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  4. D. A. Fursenko
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  5. R. I. Mashkovtsev
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  6. O. N. Lopatin
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  7. A. G. Nikolaev
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  8. B. P. Gorshunov
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  9. E. S. Zhukova
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Corresponding author

Correspondence to G. S. Shakurov.

Additional information

Original Russian Text © G.S. Shakurov, R.I. Khaibullin, V.G. Tomas, D.A. Fursenko, R.I. Mashkovtsev, O.N. Lopatin, A.G. Nikolaev, B.P. Gorshunov, E.S. Zhukova, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 8, pp. 1576–1582.

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Shakurov, G.S., Khaibullin, R.I., Tomas, V.G. et al. Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals. Phys. Solid State 59, 1600–1606 (2017). https://doi.org/10.1134/S1063783417080236

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  • DOI: https://doi.org/10.1134/S1063783417080236

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