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Microstructure and Phase Analysis of Ethyl Silicate-Bonded Alumina-Zircon Refractories

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Refractories and Industrial Ceramics Aims and scope

Abstract

Alumina-zircon refractories are prepared using an aqueous ethyl silicate solution as the gel-polymerized bond. Test specimens are heat-treated by reaction sintering at different temperature (1450 – 1600°C) and holding times (1 – 4 h) to yield new refractory phases zirconium dioxide and mullite. The specimens are tested for strength, porosity, sintering shrinkage, apparent density, and chemical and phase composition using x-ray diffractometry and electron scanning microscopy. Reactive sintering is shown to be a effective route towards obtaining ethyl-silicate-bonded alumina-zircon refractories with tailored microscopic and physical properties.

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REFERENCES

  1. A. J. Rigby, The Microstructure and Properties of Ethyl Silicate-Bonded Refractories. M.S. Thesis, Department of Ceramics of the University of Leeds, Leeds (1982).

    Google Scholar 

  2. H. D. Cogan and S. A. Setterstrom, “Properties of ethyl silicate,” Chem. Eng. News, 24(18) (September 25), 2499–2501 (1946).

    CAS  Google Scholar 

  3. H. G. Emblem, “Ethyl silicate-bonded refractories,” Mater. Chem. Phys., No. 8, 265–277 (1983).

    Google Scholar 

  4. H. G. Emblem, “Some uses of alkyl silicates in refractory technology,” Ceramurgia Int., 1, 136–138 (1975).

    Article  CAS  Google Scholar 

  5. Ya. I. Shklennik, “Classification of ethyl silicate binder solutions,” Russ. Casting Production, No. 5, 209–210 (1970).

  6. M. Holmstrom, T. Chartier, and P. Boch, “Reaction-sintered ZrO2-mullite composite,” Mater. Sci. Eng., A109, 105–109 (1989).

    Google Scholar 

  7. K. Das, S. K. Das, B. Mukherjee, and G. Banerjee, “Microstructural and mechanical properties of reaction-sintered mullite-zirconia composite with magnesia as additive,” Interceram., 47(5), 304–312 (1998).

    CAS  Google Scholar 

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Translated from Novye Ogneupory, No. 4, pp. 82 – 86, April, 2005.

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Sarydikmen, H., Kushkonmaz, N. Microstructure and Phase Analysis of Ethyl Silicate-Bonded Alumina-Zircon Refractories. Refract Ind Ceram 46, 212–216 (2005). https://doi.org/10.1007/s11148-005-0088-0

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  • DOI: https://doi.org/10.1007/s11148-005-0088-0

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