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Selective hydrogenation of 1-hexyne/1-hexene mixture on mesoporous silica gel doped with dysprosium, lanthanum, and modified with silver

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Abstract

Selective hydrogenation of 1-hexyne/1-hexene mixture was studied in the temperature range of 100–150 °C (hydrogen pressure of 3 atm) on a catalyst based on mesoporous silica gel (MPS) doped with dysprosium, lanthanum and modified with silver (Dy–Ag/MPS, La–Ag/MPS). The catalysts were studied by scanning electron microscopy, X-ray fluorescence, X-ray diffraction analysis, Fourier-transform infrared spectroscopy, temperature programmed reduction and inductively coupled plasma mass spectrometry. It was found that the conversions of 1-hexyne on Dy–Ag/MPS are higher than on La–Ag/MPS. Moreover, it has been shown that the Dy–Ag/MPS sample exhibits greater efficiency and selectivity for 1-hexene in the hydrogenation of a 1-hexyne/1-hexene mixture. In addition, it was shown that the selectivity of Dy–Ag/MPS for 1-hexene remains the same with an increase of 1-hexyne concentration in the mixture.

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Funding

This work was supported by the Grant FSSS-2020-0016 within the framework of the state assignment of the Ministry of Education and Science of the Russian Federation.

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  1. Samara University, 34, Moskovskoye Shosse, Samara, Russia, 443086

    Aleksander A. Tokranov, Elena O. Tokranova, Roman V. Shagifulin, Larisa V. Pavlova, Irina M. Mukhanova, Igor A. Platonov & Andzhela V. Bulanova

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  1. Aleksander A. Tokranov
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Tokranov, A.A., Tokranova, E.O., Shagifulin, R.V. et al. Selective hydrogenation of 1-hexyne/1-hexene mixture on mesoporous silica gel doped with dysprosium, lanthanum, and modified with silver. Reac Kinet Mech Cat 136, 217–231 (2023). https://doi.org/10.1007/s11144-022-02344-1

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