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Kinetic studies on the effect of mixed organic substrates on Briggs–Rauscher oscillatory reaction

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Abstract

Experimental studies on BR system employing mixed organic substrates and Mn(II) as the catalyst are reported keeping Malonic acid as the common substrate whereas itaconic acid, citraconic acid (CsA) and mesaconic acid (MsA) act as the co-substrates. It may be noted that no oscillations were observed when the co-substrates were used alone and the addition of these to the main system provides different modes of oscillatory behavior such as entrainment, independent, partial inhibition or complete inhibition. The oscillatory parameters like induction period, time period and iodide ion concentration show a different trend while changing the concentrations of mixed organic substrates, potassium iodate, manganese (II) sulfate, hydrogen peroxide and sulfuric acid. The favorable reaction conditions and most appropriate reagent concentrations for optimal oscillatory behavior of the system under investigation are reported. The effect of organic substrates on Dushman reaction, which is one of the essential reaction steps in BR system, has been investigated using spectrophotometry and cyclic voltammetry. Further, the EPR studies indicate the important role of free radicals in influencing the reaction dynamics. Further, the rate of iodination reaction of the organic substrates is dependent on their structure/available reaction sites for iodination and as such this work proposes a new approach to distinguish between cis/trans (CsA/MsA) isomers using spectrophotometry.

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Acknowledgements

The authors acknowledge the Department of Chemistry, University of Kashmir for infrastructural facilities used for carrying out this work. The authors also declare that they have no conflict of interest with anybody regarding this work.

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Authors and Affiliations

  1. Department of Chemistry, University of Kashmir, Srinagar, Jammu & Kashmir, 190006, India

    Nisar Ahmad Dar Farhad & Ghulam Mustafa Peerzada

  2. Postgraduate Department of Chemistry, Government College for Women Nawakadal, Srinagar, Jammu & Kashmir, 190002, India

    Nadeem Bashir Ganaie

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  1. Nisar Ahmad Dar Farhad
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  2. Ghulam Mustafa Peerzada
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  3. Nadeem Bashir Ganaie
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Correspondence to Nadeem Bashir Ganaie.

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Farhad, N.A.D., Peerzada, G.M. & Ganaie, N.B. Kinetic studies on the effect of mixed organic substrates on Briggs–Rauscher oscillatory reaction. Reac Kinet Mech Cat 135, 1313–1334 (2022). https://doi.org/10.1007/s11144-022-02174-1

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