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Observations on the hydrogen peroxide-iodic acid-manganese(II)-organic species oscillating system

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Abstract

The effect of acidity and manganese (II) concentration on the title reaction has been examined for acetone and malonic acid as the organic species. Cerium (III) has been shown to replace manganese (II) without loss of the oscillatory behavior. Some mechanistic details are given.

Abstract

Был исследован эффект кислотности и концентрации марганца (II) в заглавной реакции на примере ацетона и малоновой кислоты, как органических компонентов. Было обнаружено, что замена марганца (II) на церий (III) не приводит к исчезновению осциллирующего поведения. Приводятся некоторые детали механистической модели.

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  1. Hastings College of Further Education, TN38 OHX, Sussex, England

    D. O. Cooke

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  1. D. O. Cooke
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Cooke, D.O. Observations on the hydrogen peroxide-iodic acid-manganese(II)-organic species oscillating system. React Kinet Catal Lett 4, 329–336 (1976). https://doi.org/10.1007/BF02342574

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  • DOI: https://doi.org/10.1007/BF02342574

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