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Phenol hydroxylation over cubic/monoclinic mixed phase CuO nanoparticles prepared by chemical vapor deposition

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Abstract

CuO/SiO2 catalysts were synthesized by chemical vapor deposition, and the resulting supported CuO nanoparticles with loadings of 0.2–2 mmol/g are mixed phases of monoclinic and cubic CuO, and highly dispersed on the substrate SiO2 with an average particle size around 4 nm. An interaction between CuO and the support is confirmed by FT-IR and more surface acidity is generated due to a loading of CuO on the support. The prepared CuO/SiO2 catalysts exhibit a much higher dispersion degree of CuO than those by impregnation, and thus much better catalytic performances in phenol hydroxylation to catechol and hydroquinone.

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Acknowledgements

The authors gratefully acknowledge the financial supports from the Natural Science Foundation of Jiangsu Province (BK2012681) and Ph.D. Programs Foundation of Ministry of Education of China (20123250120008) and A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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  1. Guojun Shi

    Present address: School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, Jiangsu Province, People’s Republic of China

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, Jiangsu Province, People’s Republic of China

    Yan Bao, Binbin Chen & Jinyang Xu

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  1. Guojun Shi
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  2. Yan Bao
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Correspondence to Guojun Shi.

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Shi, G., Bao, Y., Chen, B. et al. Phenol hydroxylation over cubic/monoclinic mixed phase CuO nanoparticles prepared by chemical vapor deposition. Reac Kinet Mech Cat 122, 289–303 (2017). https://doi.org/10.1007/s11144-017-1229-4

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