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Catalytic activity of vanadium oxide catalysts prepared by electrodeposition for the selective catalytic reduction of nitrogen oxides with ammonia

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Abstract

A facile synthesis of nanostructured vanadium oxide catalysts grown inside a honeycomb ceramic filter by electrodeposition without heat treatment is reported. The prepared catalysts are investigated for a selective catalytic reduction (SCR) of nitrogen oxide (NOx) with ammonia (NH3) in the temperature ranges from 250 to 450 °C. The SCR test results indicate that the NOx removal efficiency of the as-deposited sample is comparable to that of the sample heat treated at 600 °C as well as that of the sample prepared by conventional wash coating method. The nanostructured catalysts show similar NOx removal efficiencies after several recycles. Both polycrystalline and amorphous phases co-exist in the electrodeposited V-oxide catalysts confirmed by X-ray diffraction and selective area electron diffraction. The V-oxide catalysts show stronger V=O bond peaks and higher ratio of V4+/V5+ and Oα/Oβ on their surfaces as characterized by Raman spectroscopy and X-ray photoelectron spectroscopy.

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Acknowledgments

This research was supported by the National Research Foundation of Korea (2015R1A2A1A15053002).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Korea University, Seoul, 02841, Republic of Korea

    Su Hyo Kim, Yoo Sang Jeon, Bum Chul Park & Young Keun Kim

  2. Basic Industry Division, Material Testing Center, Korea Testing Laboratory, Seoul, 08389, Republic of Korea

    Jin Sun Cha, Min-Chul Shin & Jun-Kwang Song

Authors
  1. Su Hyo Kim
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  2. Jin Sun Cha
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  3. Yoo Sang Jeon
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  4. Bum Chul Park
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  5. Min-Chul Shin
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  7. Young Keun Kim
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Correspondence to Young Keun Kim.

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Kim, S.H., Cha, J.S., Jeon, Y.S. et al. Catalytic activity of vanadium oxide catalysts prepared by electrodeposition for the selective catalytic reduction of nitrogen oxides with ammonia. Reac Kinet Mech Cat 118, 633–641 (2016). https://doi.org/10.1007/s11144-016-1010-0

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  • DOI: https://doi.org/10.1007/s11144-016-1010-0

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