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Sulfur resistance of binary Cu–Ni-oxide composites based on yttrium-stabilized zirconia doped with Pd, Pt, Rh in the oxidative conversion of methane

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Abstract

The effect of platinum group metals (Pd, Pt, Rh) on the activity and sulfur resistance of the Cu–Ni-oxide composites over yttrium-stabilized zirconia in the reaction of methane oxidation by oxygen has been studied. The promoting effect of platinum metals depends on the composition of the reaction mixture (the stoichiometry of partial or deep oxidation, the presence of sulfur dioxide). The enhancement of activity in the deep oxidation of methane, which is greatest for the palladium doped sample, is related to the oxidative–reductive properties of the composites in accordance with TPR-H2 data. The sulfur resistance of Pd-doped Cu–Ni oxide composite is attributed to the formation of an adsorbed (PdO·SO2) complex, capable of methane oxidation.

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References

  1. Itome M, Nelson AE (2006) Catal Lett 106:21

    Article  CAS  Google Scholar 

  2. Keegan CW, Joyce SC (2005) J Power Sources 140:280

    Article  Google Scholar 

  3. Haering C, Roosen A, Schichl H (2005) Solid State Ion 176:261

    Article  CAS  Google Scholar 

  4. Haering C, Roosen A, Schichl H (2005) Solid State Ion 176:253

    Article  CAS  Google Scholar 

  5. Aguilar L, Zha S, Cheng Z, Winnick J, Liu M (2004) J Power Sources 135:17

    Article  CAS  Google Scholar 

  6. Hennings U, Reimert R (2007) Appl Catal B 70:498

    Article  CAS  Google Scholar 

  7. Cheng Z, Liu M (2007) Solid State Ion 178:925

    Article  CAS  Google Scholar 

  8. Luo T, Gorte RJ (2004) Appl Catal B 53:77

    Article  CAS  Google Scholar 

  9. Jones JM, Dupont VA, Brydson R, Fullerton DJ, Nasri NS, Ross AB, Westwood AVK (2003) Catal Today 81:589

    Article  CAS  Google Scholar 

  10. Shashkova TK, Kantserova MR, Chedryk VI, Vasylyev OD, Orlyk SN (2008) Pol J Chem 82:371

    CAS  Google Scholar 

  11. Fujimoto K, Ribeiro FH, Avalos-Borjia M, Iglesia E (1998) J Catal 179:431

    Article  CAS  Google Scholar 

  12. Perez-Hernandez R, Mondragon Galicia G, Mendoza Anaya D, Palacios J, Angeles-Chavez C, Arenas-Avatorre J (2008) Int J Hydrogen Energy 33:4569

    Article  CAS  Google Scholar 

  13. Luo T, Vohs JM, Gorte RJ (2002) J Catal 210:397

    Article  CAS  Google Scholar 

  14. Boreskov GK (1954) Catalysis in the manufacture of sulfuric acid [in Rus.]. Goskhimizdat, Moscow

    Google Scholar 

  15. Gracia FJ, Guerrero S, Wolf EE et al (2005) J Catal 233:372

    Article  CAS  Google Scholar 

  16. Pyatnitskii YuI, Orlyk SN, Martesnyuk-Kukharuk MG (1983) Kinet Catal 24:1415

    CAS  Google Scholar 

  17. Martsenyuk-Kukharuk MG, Orlyk SN, Martsenyuk-Kukharuk AP (1992) Theor. Exp Chem 28:188

    Article  Google Scholar 

  18. Pazmino JH, Msller JT, Mulla SS et al (2011) J Catal 282:13

    Article  CAS  Google Scholar 

  19. Pyatnitsky YuI, Pavlenko M, Ilchenko NI (2000) Introduction to non-linear kinetics in heterogeneous catalysis. Nova Science Publishers, Hauppauge

    Google Scholar 

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Authors and Affiliations

  1. L.V. Pisarzhevsky Institute of Physical Chemistry, NAS of Ukraine, 31 Prosp. Nauky, Kiev, 03028, Ukraine

    Tetiana K. Shashkova, Svitlana M. Orlyk & Yuriy I. Pyatnitsky

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  1. Tetiana K. Shashkova
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  2. Svitlana M. Orlyk
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  3. Yuriy I. Pyatnitsky
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Correspondence to Tetiana K. Shashkova.

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Shashkova, T.K., Orlyk, S.M. & Pyatnitsky, Y.I. Sulfur resistance of binary Cu–Ni-oxide composites based on yttrium-stabilized zirconia doped with Pd, Pt, Rh in the oxidative conversion of methane. Reac Kinet Mech Cat 110, 75–85 (2013). https://doi.org/10.1007/s11144-013-0591-0

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  • DOI: https://doi.org/10.1007/s11144-013-0591-0

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