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Exploration of Ni@Zn-MOCP via a wet impregnation strategy as a hydrogenation catalyst

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Abstract

In the current paper, the metal organic coordination polymer Zn4O(OH)2(BDC)2(H2O)2.7 (Zn-MOCP) with high thermal and chemical stability was synthesized by a direct mixing method at room temperature. Then the catalyst Ni@Zn-MOCP (7.5 wt% Ni) was successfully prepared via a wet impregnation strategy employing Ni(acac)2 (acac = acetylacetonate) as the precursor. The hydrogenation of crotonaldehyde was utilized as the probe reaction to explore its catalytic activity. The samples were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), N2 adsorption–desorption measurements, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). PXRD patterns of Ni@Zn-MOCP showed good coincidence with that of Zn-MOCP, and the pore texture of Zn-MOCP was still maintained after impregnation. Most of Ni(acac)2 over Zn-MOCP were reduced to Ni0 after reduction based on XPS analysis. In terms of the turnover of frequency (TOF) of crotonaldehyde, Ni@Zn-MOCP (53.6 h−1) exhibited much higher activity than the industrial catalyst Ni/SiO2 (29.5 h−1). Furthermore, the reusability of the catalyst Ni@Zn-MOCP over the hydrogenation for crotonaldehyde was tested.

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Acknowledgments

We gratefully acknowledge the financial support of the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, People’s Republic of China

    Huahua Zhao, Lingjun Chou & Huanling Song

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Huahua Zhao

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  1. Huahua Zhao
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  2. Lingjun Chou
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  3. Huanling Song
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Correspondence to Huanling Song.

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Zhao, H., Chou, L. & Song, H. Exploration of Ni@Zn-MOCP via a wet impregnation strategy as a hydrogenation catalyst. Reac Kinet Mech Cat 104, 451–465 (2011). https://doi.org/10.1007/s11144-011-0375-3

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  • DOI: https://doi.org/10.1007/s11144-011-0375-3

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