Skip to main content
SpringerLink
Log in

Synthesis and characterization of a mesoporous HMS and its use as support of platinum catalysts

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

Abstract

Two mesoporous silicas (HMS) with high surface area and a pore diameter size of 2 nm were synthesized by a sol–gel method. Platinum catalysts were prepared with a 1 wt% metal content. A commercial silica supported catalyst was used for comparison. The catalysts were characterized by H2-TPR, TEM and 29Si-CP-MAS-NMR. The catalytic activity was measured by the hydrodechlorination of 1,2-dichloroethane. The enhanced activity of the mesoporous catalysts was related to the platinum particle size.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Bizz S, Occelli ML (1998) Catal Rev Sci Eng 40(3):329–407

    Article  Google Scholar 

  2. Pauly TR, Liu Y, Pinnavaia TJ, Bilingue SJL, Rieker TP (1999) J Am Chem Soc 121:8835–8842

    Article  CAS  Google Scholar 

  3. Trong On D, Desplantier-Giscard D, Danumah C, Kaliaguine S (2003) Appl Catal A 253:545–602

    Article  Google Scholar 

  4. Kostova NG, Spojakina AA, Jiratova K, Solcova O, Dimitrov LD, Petrov LA (2001) Catal Today 65:217–223

    Article  CAS  Google Scholar 

  5. Matachowski L, Pamin K, Poltowicz J, Serwicka EM, Jones W, Mokaya R (2006) Appl Catal A 313:106–111

    Article  CAS  Google Scholar 

  6. Moller K, Bein T (1998) Chem Mater 10:2950–2954

    Article  CAS  Google Scholar 

  7. Manzer LE (1992) Catal Today 13:13–19

    Article  CAS  Google Scholar 

  8. Mohapatra SK, Sahoo B, Keune W, Selvam P (2002) Chem Commun 14:1466–1467

    Article  Google Scholar 

  9. Dal Santo V, Dossi C, Recchia S, Colavita PE, Vlaic G, Psaro R (2002) J Mol Catal A 182:157–166

    Article  Google Scholar 

  10. López E, Ordoñez S, Diez FV (2005) Appl Catal B 62:57–65

    Google Scholar 

  11. Lambert S, Polard JF, Pirard JP, Heinrichs B (2004) Appl Catal B 50:127–140

    Article  CAS  Google Scholar 

  12. Kovalchuk VI, d’Itri JL (2004) Appl Catal A 271:13–21

    Article  CAS  Google Scholar 

  13. Kawabata J, Atake I, Ohishi Y, Shishido T, Tian Y, Takachi K, Takehira K (2006) Appl Catal B 66:151–160

    Article  CAS  Google Scholar 

  14. Cesteros Y, Salagre P, Medina F, Sueiras JE (2002) Catal Lett 79:83

    Article  CAS  Google Scholar 

  15. Tanev PI, Chibwe M, Pinnavaia TJ (1994) Nature 368:321

    Article  CAS  Google Scholar 

  16. Pinnavaia TJ, Zhang W (1998) Stud Surf Sci Catal 117:23

    Article  CAS  Google Scholar 

  17. Zhang W, Pauly TR, Pannavaia TJ (1997) Chem Mater 9:2491

    Article  CAS  Google Scholar 

  18. Brinker CJ, Scherer GW (1996) Sol-gel-science: the physics and chemistry of sol-gel processing. Academic Press Inc., New York

    Google Scholar 

  19. Satterfield CN (1980) Heterogeneous catalysis in practice. McGraw Hill, New York

    Google Scholar 

  20. Prado AGS, Airoldi C (2002) J Mater Chem 12:3823–3826

    Article  CAS  Google Scholar 

  21. Lieske H, Lietz G, Spindler H, Volter J (1983) J Catal 81:8–16

    Article  CAS  Google Scholar 

  22. Lietz G, Spindler H, Lieske H, Hanke W, Volter J (1983) J Catal 81:17–25

    Article  CAS  Google Scholar 

  23. Huo Q, Margolese DI, Stucky GD (1996) Chem Mater 8:1147–1160

    Article  CAS  Google Scholar 

  24. Fuentes S, Figueras F (1978) J Catal 54:397

    Article  CAS  Google Scholar 

  25. Coq B, Ferrat G, Figueras F (1986) J Catal 101:434–438

    Article  CAS  Google Scholar 

  26. Heinrichs B, Noville F, Schoebrechts JP, Pirard JP (2003) J Catal 220:215–225

    Article  CAS  Google Scholar 

  27. Bozelli W, Chen YM, Chuang SSC (1992) Chem Eng Commun 115:1–11

    Article  Google Scholar 

  28. López-Gaona JA, De los Reyes JA, Aguilar J, Martín N (2010) React Kinet Mech Catal 99(1):177–182

    Google Scholar 

  29. Avdeev A, Kovalchuk VI, Zhidomirov GM, d’Itri JL (2005) Surf Sci 583:46

    Article  CAS  Google Scholar 

  30. Vadlamannati LS, Luebke DR, Kovalchuk VI, d’Itri JL (2000) Stud Surf Sci 130:233

    Article  Google Scholar 

Download references

Acknowledgments

We would like to acknowledge to Dr. Enrique Lima for the results of 29Si-CP-MAS-NMR measurements. The authors are grateful to the financial support of the PROMEP-SEP project (CA/UAMI/98).

Author information

Authors and Affiliations

  1. Departamento de Química, UAM-Iztapalapa, Av. San Rafael Atlixco 186, 09340 DF, Mexico City, México

    Nancy Martín, Alejandro López-Gaona, Margarita Viniegra, Patricia Villamil & Gilberto Córdoba

Authors
  1. Nancy Martín
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Alejandro López-Gaona
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Margarita Viniegra
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Patricia Villamil
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Gilberto Córdoba
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nancy Martín.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martín, N., López-Gaona, A., Viniegra, M. et al. Synthesis and characterization of a mesoporous HMS and its use as support of platinum catalysts. Reac Kinet Mech Cat 101, 491–500 (2010). https://doi.org/10.1007/s11144-010-0237-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-010-0237-4

Keywords

Search

Navigation