Abstract
The oxidation of cyclohexanol with hydrogen peroxide in the presence of tungsten-based catalysts was studied in this paper. The effect of phase transfer catalysts was discussed and clarified. [CTA]9[SbW9O33] showed the best activity and good recyclability with a conversion over 95%.
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S. Das, T. Punniyamurthy: Tetrahedron Lett., 44, 6033 (2003).
D.R. Park, H. Kim, J.C. Jung, S.H. Lee, J. Lee, I.K. Song: React. Kinet. Catal. Lett., 93, 43 (2008).
G.Y. Bai, H.L. Wang, H.S. Ning, F. He, G.F. Chen: React. Kinet. Catal. Lett., 94, 375 (2008).
H.B. Ji, T.T. Wang, M.Y. Zhang, Q.L. Chen, X.N. Gao: React. Kinet. Catal. Lett., 90, 251 (2007).
R.V. Stevens, K.T. Chapman, H.N. Weller: J. Org. Chem., 45, 2030 (1980).
Y. Ishii, K. Yamawaki, T. Ura, H. Yamada, T. Yoshida, M. Ogama: J. Org. Chem., 53, 3587 (1988).
K. Manju, S. Sugunan: React. Kinet. Catal. Lett., 85, 37 (2005).
U.R. Pillai, E. Sahle-Demessie: Appl. Catal. A: Gen., 276, 139 (2004).
K.M. Choi, S. Ikeda, S. Ishino, K. Ikeue, M. Matsumura, B. Ohtani: Appl. Catal. A: Gen., 278, 269 (2005).
S.J. Zhang, S. Gao, Z.W. Xi, J. Xu: Catal. Commun., 8, 531 (2007).
B.S. Chhikara, R. Chandra, V. Tandon: J. Catal., 230, 436 (2005).
T. Iwahama, S. Sakaguchi, Y. Nishiyama, Y. Ishii: Tetrahedron Lett., 36, 1523 (1995).
K. Sato, M. Aoki, J. Takagi, R. Noyori: J. Am. Chem. Soc., 119, 12386 (1997).
D. Bogdal, M. Lukasiewicz: Synlett, 1, 143 (2000).
R.H. Ingle, N.K.K. Raj, P. Manikandan: J. Mol. Catal. A: Gen., 262, 52 (2007).
M. Bösing, A. Nöh, I. Loose, B. Krebs: J. Am. Chem. Soc., 120, 7252 (1998).
U. Kortz, N.K. Al-Kassem, M.G. Savelieff, N.A.A. Kadi, M. Sadakane: Inorg. Chem., 40, 4742 (2001).
R.A. Sheldon, I.W.C.E. Arends, A. Dijksman: Catal. Today, 57, 157 (2000).
C.E. Huckba, F.G. Keyes: J. Am. Chem. Soc., 70, 1640 (1948).
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Bai, G., Jia, C., Xu, K. et al. Tungsten-based catalysts for the oxidation of cyclohexanol: The effect of phase transfer catalysts. React Kinet Catal Lett 96, 109–116 (2009). https://doi.org/10.1007/s11144-009-5391-1
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DOI: https://doi.org/10.1007/s11144-009-5391-1