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Catalytic oxidation of fatty acids. II. Epoxidation and oxidative cleavage of unsaturated fatty acid esters containing additional functional groups

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Abstract

Methyl esters of monounsaturated fatty acids were oxidized with aqueous hydrogen peroxide in biphasic organic-aqueous systems in the presence of catalyst [Me(n-C8H17)3N]3{PO4[WO(O2)2]4}. Epoxidation and oxidative cleavage of the C=C bond were found to proceed with high conversion and selectivity in the absence of organic solvents and under rather mild conditions (T < 100 °C, 1 atm).

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Acknowledgements

The work was financially supported by the RAS Program of Basic Research (Project No. 5.7.3, 2009). The authors are grateful to the Russian Foundation for Basic Research for access to the STN International databases via the STN Center at the Institute of Organic Chemistry, Russian Academy of Sciences, Novosibirsk, Russia.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    Tatiana B. Khlebnikova, Zinaida P. Pai & Yulia V. Mattsat

  2. Institute of Cytology and Genetics, Novosibirsk, 630090, Russia

    Larisa A. Fedoseeva

Authors
  1. Tatiana B. Khlebnikova
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  2. Zinaida P. Pai
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  3. Larisa A. Fedoseeva
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  4. Yulia V. Mattsat
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Correspondence to Tatiana B. Khlebnikova.

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Khlebnikova, T.B., Pai, Z.P., Fedoseeva, L.A. et al. Catalytic oxidation of fatty acids. II. Epoxidation and oxidative cleavage of unsaturated fatty acid esters containing additional functional groups. React Kinet Catal Lett 98, 9–17 (2009). https://doi.org/10.1007/s11144-009-0054-9

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  • DOI: https://doi.org/10.1007/s11144-009-0054-9

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