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Synthesis and catalase-like activity of a dimanganese(II) complex with a pentadentate L-prolin-based ligand

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Abstract

The preparation, spectroscopic properties, and catalase-like activity of the dimanganese(II) complex [Mn2L(OAc)(H2O)2](H2O)2 (H3L: 2,6-bis[(prolin-1-yl)methyl]4-t-butylphenol) are reported. The title compound was a suitable catalyst for the disproportionation of H2O2 into water and dioxygen under ambient conditions. Kinetic measurements resulted in the bimolecular rate law of d[O2]/dt = k[H2O2][Mn2L(OAc)(H2O)2](H2O)2].

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References

  1. P. Nicholls, G.R. Schonbaum: Catalases. in The Enzymes, Vol. VIII, 2nd Edn (P.D. Boyer, H. Lardy, K. Myrback, Eds), p. 147. Academic Press, New York 1963.

    Google Scholar 

  2. V.V. Barynin, A.I. Grebenko: Dokl. Acad. Nauk. SSSR. 286, 461 (1986).

    CAS  Google Scholar 

  3. G.S. Allgood, J.J. Perry: J. Bacteriol., 168, 563 (1986).

    CAS  Google Scholar 

  4. Y. Kono, I. Fridovich: J. Biol. Chem., 258, 6015 (1983).

    CAS  Google Scholar 

  5. W.F. Beyer, I. Fridovich: Biochemistry, 24, 6460 (1985).

    Article  CAS  Google Scholar 

  6. T. Amo, A. Haruyuki, T. Imanaka: J. Bacteriol., 184, 3305 (2002).

    Article  CAS  Google Scholar 

  7. S.V. Antonyuk, V.R. Melik-Adamyan, A.N. Popov, V.S. Lamzin, P.D. Hempstead, P.M. Harrison, P.J. Artymiuk, V.V. Barynin: Crystallogr. Reports, 45, 105 (2000).

    Article  Google Scholar 

  8. V.V. Barynin, M.M. Whittaker, S.V. Antonyuk, V.S. Lamzin, P.M. Harrison, P.J. Artymiuk, J.W. Whittaker: Structure, 9, 725 (2001).

    Article  CAS  Google Scholar 

  9. V.L. Kinnula, J.D. Crapo: Am. J. Respir. Crit. Care Med., 167, 1600 (2003).

    Article  Google Scholar 

  10. D.P. Riley: Chem. Rev., 99, 2573 (1999).

    Article  CAS  Google Scholar 

  11. B.J. Day: Drug Discovery Today, 9, 557 (2004).

    Article  CAS  Google Scholar 

  12. D.F. Shriver, M.A. Drezdzon: The Manipulation of Air-sensitive Compounds, John Wiley & Sons, New York 1986.

    Google Scholar 

  13. D.D. Perrin, W.L. Armarego, D.R. Perrin: Purification of Laboratory Chemicals, 2nd Ed., Pergamon, New York 1990.

    Google Scholar 

  14. I. Sougandi, R. Mahalakshmi, R. Kannappan, T.M. Rajendiran, R. Venkatesan, P.S. Rao: Transit. Met. Chem., 27, 512 (2002).

    Article  CAS  Google Scholar 

  15. A. Gelasco, S. Bensiek, V.L. Pecoraro: Inorg. Chem., 37, 3301 (1998).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Pannonia, H-820, Veszprém, Hungary

    József Kaizer, Róbert Csonka & Gábor Speier

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  1. József Kaizer
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  2. Róbert Csonka
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  3. Gábor Speier
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Correspondence to Gábor Speier.

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Kaizer, J., Csonka, R. & Speier, G. Synthesis and catalase-like activity of a dimanganese(II) complex with a pentadentate L-prolin-based ligand. React Kinet Catal Lett 94, 157–163 (2008). https://doi.org/10.1007/s11144-008-5320-8

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  • DOI: https://doi.org/10.1007/s11144-008-5320-8

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