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Catalytic activity of H3PMo12−XWXO40 and H6P2MO18−XWXO62 heteropolyacid (HPA) catalysis in the direct preparation of dichloropropanol (DCP) from glycerol

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Abstract

H3PMo12−XWXO40 (X=0−12) and H6P2Mo18−XWXO62 (X=0−18) heteropolyacid catalysts were applied to the direct preparation of dichloropropanol from glycerol. Acid properties of the catalysts were determined by NH3-TPD measurements. The catalytic performance increased with increasing acid strength of the catalyst. Among the catalysts tested, the H3PW12O40 catalyst of highest acid strength showed the best catalytic performance.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul, 151-744, South Korea

    Sang Hee Lee, Dong Ryul Park, Heesoo Kim, Joohyung Lee, Ji Chul Jung, Sunyoung Park, Kyung Min Cho & In Kyu Song

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  1. Sang Hee Lee
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  2. Dong Ryul Park
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  3. Heesoo Kim
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  4. Joohyung Lee
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  5. Ji Chul Jung
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  6. Sunyoung Park
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  7. Kyung Min Cho
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  8. In Kyu Song
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Lee, S.H., Park, D.R., Kim, H. et al. Catalytic activity of H3PMo12−XWXO40 and H6P2MO18−XWXO62 heteropolyacid (HPA) catalysis in the direct preparation of dichloropropanol (DCP) from glycerol. React Kinet Catal Lett 94, 71–76 (2008). https://doi.org/10.1007/s11144-008-5303-9

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  • DOI: https://doi.org/10.1007/s11144-008-5303-9

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