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Catalysis of the water gas shift reaction by cis-[Rh(CO)2(AMINE)2](PF6) complexes in an aqueous tetrabutylammonium hydrogensulfate solution

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Abstract

Rhodium(I) complexes, cis-[Rh(CO)2(amine)2](PF6) (amine = 4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) dissolved in an aqueous solution of tetrabutylammonium hydrogensulfate (N(C4H9)4HSO4), catalyze the water-gas shift reaction (WGSR). The role of the coordinated amine on the catalytic activity was examined.

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Authors and Affiliations

  1. Centro de Equilibrios en Solución, Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Caracas, Venezuela

    Germán Gascón, Marisol C. Ortega, José D. Suárez & Alvaro J. Pardey

  2. Centro de Investigación y Desarrollo de Radiofármacos, Facultad de Farmacia, Universidad Central de Venezuela, Caracas, Venezuela

    Clementina Longo

Authors
  1. Germán Gascón
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  2. Marisol C. Ortega
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  3. José D. Suárez
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  4. Alvaro J. Pardey
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  5. Clementina Longo
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Corresponding author

Correspondence to Alvaro J. Pardey.

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Gascón, G., Ortega, M.C., Suárez, J.D. et al. Catalysis of the water gas shift reaction by cis-[Rh(CO)2(AMINE)2](PF6) complexes in an aqueous tetrabutylammonium hydrogensulfate solution. React Kinet Catal Lett 94, 85–89 (2008). https://doi.org/10.1007/s11144-008-5281-y

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  • DOI: https://doi.org/10.1007/s11144-008-5281-y

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