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Study of palladium catalyst deactivation in synthesis of 4,10-diformyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane

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Abstract

Polycyclic nitramine hexanitrohexaazaisowurtzitane (HNIW, CL-20) is synthesized via hydrodebenzylation of a precursor over palladium-based catalyst. In the present work, we studied the influence of the synthesis method of the palladium-based catalyst on the catalyst behavior during the hydrodebenzylation reaction of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.03,11.05,9] dodecane.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia

    Anton P. Koskin, Irina L. Simakova & Valentin N. Parmon

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  1. Anton P. Koskin
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  2. Irina L. Simakova
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  3. Valentin N. Parmon
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Correspondence to Irina L. Simakova.

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Koskin, A.P., Simakova, I.L. & Parmon, V.N. Study of palladium catalyst deactivation in synthesis of 4,10-diformyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane. React Kinet Catal Lett 92, 293–302 (2007). https://doi.org/10.1007/s11144-007-5203-4

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  • DOI: https://doi.org/10.1007/s11144-007-5203-4

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