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Synergetic promotion of Ba, Cs and Cl to silver supported catalyst for butadiene epoxidation

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Summary

Ag/α-Al2O3 catalysts promoted by Ba, Cs and Cl were prepared and evaluated for butadiene epoxidation. The results indicated that Cs could enhance butadiene conversion, Cl was favorable for improving the selectivity to vinyloxirane (VO), and Ba probably plays an important role for catalyst stability during the long time on stream operation.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Huanling Song

  2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Gexin Chen

  3. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Shuben Li

  4. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Shuwen Luo

  5. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Cailan Yao

  6. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

    Jishuan Suo

Authors
  1. Huanling Song
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  2. Gexin Chen
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  3. Shuben Li
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  4. Shuwen Luo
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  5. Cailan Yao
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  6. Jishuan Suo
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Song, H., Chen, G., Li, S. et al. Synergetic promotion of Ba, Cs and Cl to silver supported catalyst for butadiene epoxidation. React Kinet Catal Lett 85, 45–49 (2005). https://doi.org/10.1007/s11144-005-0241-2

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  • DOI: https://doi.org/10.1007/s11144-005-0241-2

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