Skip to main content
SpringerLink
Log in

Synthesis of Double Uranyl Phthalates of the M4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ nH2O Type with M = NH4, K, and Cs. Crystal Structure of K4[(UO2)4O2(C6H4C2O4)4] ⋅ 3H2O

  • Published:
Radiochemistry Aims and scope

Abstract

Double U(VI) phthalates with NH +4 , K+, and Cs+ ions in the outer sphere were synthesized. The X-ray phase analysis shows that their structures are similar. Single crystals were prepared and the structure of K4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ 3H2O was solved. In the [(UO2)4O2(C6H4C2O4)4]4− anions forming the main structural motif, each bridging oxygen atom μ3-O combines one pentagonal and two hexagonal bipyramids, which, in turn, are combined in centrosymmetrical tetramers. The phthalate ions have coordination capacity equal to 3; each ligand coordinates U(1) in the bidentate fashion via one carboxy group and U(2) in the bidentate fashion to form a planar seven-membered chelate ring.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Krot, N.N., Bessonov, A.A., Grigor’ev, M.S., et al., Radiokhimiya, 2004, vol. 46, no.5, pp. 389–395.

    Google Scholar 

  2. Grigoriev, M.S., Antipin, M.Yu., Krot, N.N., and Bessonov, A.A., Radiochim. Acta, 2004, vol. 92, pp. 405–409.

    CAS  Google Scholar 

  3. Charushnikova, I.A., Krot, N.N., and Starikova, Z.A., Radiokhimiya, 2004, vol. 46, no.6, pp. 513–515.

    Google Scholar 

  4. Shirley, R., The CRYSFIRE System for Automatic Powder Indexing: User’s Manual, Guildford: Lattice, 2000.

    Google Scholar 

  5. Altermatt, U.D. and Brown, I.D., Acta Crystallogr., Sect. A, 1987, vol. 43, no.1, pp. 125–130.

    Google Scholar 

  6. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., Sect. A, 1968, vol. 24, no.3, pp. 351–359.

    Google Scholar 

  7. Sheldrick, G.M., Acta Crystallogr., Sect. A, 1990, vol. 46, no.6, pp. 467–473.

    Google Scholar 

  8. Sheldrick, G.M., SHELXL93. Program for the Refinement of Crystal Structures, Gottingen: Univ. of Gottingen, 1993.

    Google Scholar 

  9. Charushnikova, I.A., Krot, N.N., and Starikova, Z.A., Radiokhimiya, 2001, vol. 43, no.5, pp. 434–437.

    Google Scholar 

  10. Charushnikova, I.A., Krot, N.N., and Starikova, Z.A., Radiokhimiya, 2001, vol. 43, no.5, pp. 438–442.

    Google Scholar 

  11. Lintvedt, R.L., Heeg, M.J., et al., Inorg. Chem., 1982, vol. 21, no.6, pp. 2350–2356.

    CAS  Google Scholar 

  12. Charpin, P., Lance, M., et al., Acta Crystallogr., Sect. C, 1986, vol. 42, no.12, pp. 1691–1694.

    Google Scholar 

  13. Rose, D., Chang, Y.-D., Chen, Q., and Zubieta, J., Inorg. Chem., 1994, vol. 33, no.23, pp. 5167–5168.

    CAS  Google Scholar 

  14. Mit’kovskaya, E.V., Mikhailov, Yu.N., et al., Zh. Neorg. Khim., 2003, vol. 48, no.5, pp. 755–759.

    CAS  Google Scholar 

  15. Van den Bossche, G., Spirlet, M.R., et al., Acta Crystallogr., Sect. C, 1987, vol. 43, no.5, pp. 837–839.

    Google Scholar 

  16. Aberg, M., Acta Chem. Scand., Sect. A, 1976, vol. 30, no.7, pp. 507–514.

    Google Scholar 

  17. Turpeinen, U., Hamalainen, R., et al., Acta Crystallogr., Sect. C, 1996, vol. 52, no.5, pp. 1169–1171.

    Google Scholar 

  18. Grigor’ev, M.S., Antipin, M.Yu., and Krot, N.N., Radiokhimiya, 2003, vol. 46, no.3, pp. 206–211.

    Google Scholar 

  19. Charushnikova, I.A., Krot, N.N., and Starikova, Z.A., Radiokhimiya, 2004, vol. 46, no.5, pp. 396–400.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Charushnikova, N. N. Krot & V. I. Makarenkov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. N. Polyakova

Authors
  1. I. A. Charushnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Krot
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. N. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Makarenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Radiokhimiya, Vol. 47, No. 3, 2005, pp. 219–223.

Original Russian Text Copyright © 2005 by Charushnikova, Krot, Polyakova, Makarenkov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Charushnikova, I.A., Krot, N.N., Polyakova, I.N. et al. Synthesis of Double Uranyl Phthalates of the M4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ nH2O Type with M = NH4, K, and Cs. Crystal Structure of K4[(UO2)4O2(C6H4C2O4)4] ⋅ 3H2O. Radiochemistry 47, 241–246 (2005). https://doi.org/10.1007/s11137-005-0080-z

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11137-005-0080-z

Keywords

Search

Navigation