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Synthesis of new crystalline Pu(V) compounds from solutions: I. Structure and characteristics of a double Pu(V) phthalate with [Co(NH3)6]3+ in the outer sphere

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Abstract

The conditions of synthesis of Pu(V) phthalates by conversion of Pu(VI) into the pentavalent state with addition of H2O2 in the presence of excess of phthalate ions (L) were determined. Subsequent addition of [Co(NH3)6]Cl3 allowed isolation of crystalline [Co(NH3)6][PuO2L2]⋅2H2O isostructural with [Co(NH3)6][NpO2L2]⋅2H2O studied previously. The thermal behavior and IR spectra of both compounds were studied.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia

    N. N. Krot, A. A. Bessonov, M. S. Grigor’ev, I. A. Charushnikova & V. I. Makarenkov

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  1. N. N. Krot
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  2. A. A. Bessonov
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  3. M. S. Grigor’ev
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  4. I. A. Charushnikova
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  5. V. I. Makarenkov
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Translated from Radiokhimiya, Vol. 46, No. 6, 2004, pp. 516–520.

Original Russian Text Copyright © 2004 by Krot, Bessonov, Grigor’ev, Charushnikova, Makarenkov.

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Krot, N.N., Bessonov, A.A., Grigor’ev, M.S. et al. Synthesis of new crystalline Pu(V) compounds from solutions: I. Structure and characteristics of a double Pu(V) phthalate with [Co(NH3)6]3+ in the outer sphere. Radiochemistry 46, 560–564 (2004). https://doi.org/10.1007/s11137-005-0027-4

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  • DOI: https://doi.org/10.1007/s11137-005-0027-4

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