Skip to main content
Log in

Assessing the Internal Structure of Cross-Linked Carbon Nanofibers by Chemical Methods

  • NANOSTRUCTURED MATERIALS
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

The structure of cross-linked carbon nanofibers of DNIPRO industrial carbon fabric produced by pyrolysis of hydrated cellulose is assessed, and their oxidation temperature (Tox = 923 ± 10 K) is found. Fractionated extraction of carbon (as CO2) in a purified oxygen flow is measured by coulometry of the extracted CO2 versus time at Tox. A selective chemical procedure for qualitative identification and determination of cross-linked carbon nanofibers in carbon nanomaterials of arbitrary composition is developed for the first time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

References

  1. V. V. Garbuz and V. V. Zakharov, “Theoretical and methodological evaluation of the ratio between structure and composition in sorption and oxidizing properties of carbon nanotubes,” in: 8th Int. Conf. ICHMS’2005 (September 5–11, 2005, Sevastopol, Ukraine), AHEU, Kyiv (2005), pp. 618–619.

  2. V. V. Garbuz, V. V. Zakharov, L. N. Kuzmenko, and S. V. Nuzhda, “Oxidation of nanoforms in a carbon matrix,” in: 8th Int. Conf. ICHMS’2005 (September 5–11, 2005, Sevastopol, Ukraine), AHEU, Kyiv (2005), pp. 704–705.

  3. V. V. Garbuz, A Device for Producing Carbon Nanomaterials (CNM) in a CO Catalytic Decomposition Chamber [in Ukrainian], Ukrainian Declaration Invention Patent, C01B31/02, No. 2003087446; appl. March 6, 2003; publ. June 15, 2004; Bulletin No. 6.

  4. V. V. Garbuz and V. V. Zakharov, “Formation and oxidation of carbon nanomaterials,” Nanostrukt. Materialoved., No. 1, 74–83 (2007).

  5. A. A. Konkin (ed.), Heat-Resistant, Oxidation-Resistant, and Noncombustible Fibers [in Russian], Khimiya, Moscow (1978), Part 2, pp. 222–313.

  6. ISO/TS 80004-1:2010, Nanotechnologies. Vocabulary. Part 1: Core Terms, ed. 2010-10-15, ISO (2010), p. 4.

  7. ISO/TS 80004-3:2010, Nanotechnologies. Vocabulary. Part 3: Carbon Nano-objects, ed. 2010-05-01, ISO (2010), p. 7.

  8. ISO/TS 27687-3:2008, Nanotechnologies. Terminology and Definitions for Nano-objects. Nanoparticle, Nanofiber and Nanoplate, ed. 2008-08-15, ISO (2008), p. 7.

  9. ISO/TR 11360-3:2010, Nanotechnologies. Methodology for the Classification and Categorization of Nanomaterials, ed. 2010-07-15, ISO (2010), p. 32.

  10. ISO/TR 12885:200.8, Nanotechnologies. Health and Safety Practices in Occupational Settings Relevant to Nanotechnologies, ed. 2008-10-01, ISO (2008), p. 86.

  11. ISO/TR 11360: 2010(E), Nanotechnologies. Methodology for the Classification and Categorization of Nanomaterials, first ed. 2010-07-15, ISO (2010), p. 25.

  12. ISO/TS 10929:2012, Nanotechnologies. Characterization of Multiwall Carbon Nanotube (MWCNT) Samples, ed. 2012-01-15, ISO (2012), p. 6.

  13. ISO/TS 11888:2011, Nanotechnologies. Characterization of Multiwall Carbon Nanotubes. Mesoscopic Shape Factors, ed. 20111-11-15, ISO (2011), p. 17.

  14. ISO/TS 10797:2011, Nanotechnologies. Characterization of Single-Wall Carbon Nanotubes Using Scanning Electron Microscopy and Energy Dispersive X-Ray Spectrometry Analysis, ed. 2011-07-15, ISO (2011), p. 26.

  15. ISO/TS 10797:2012, Nanotechnologies. Characterization of Single-Wall Carbon Nanotubes Using Transmission Electron Microscopy, ed. 2012-06-01, ISO (2012), p. 34.

  16. ISO/TS 10867:2010, Nanotechnologies. Characterization of Single-Wall Carbon Nanotube Samples Using Evolved Gas Analysis/Gas Chromatograph-Mass Spectrometry, ed. 2010-12-01, ISO (2010), p. 10.

  17. ISO/TS 10868:2011, Nanotechnologies. Characterization of Single-Wall Carbon Nanotubes Using Ultraviolet-Visible-Near Infrared (UV-Vis-NIR) Absorption Spectroscopy, ed. 2011-09-01, ISO (2011), p. 19.

  18. ISO/TS 11251:2010, Nanotechnologies. Characterization of Volatile Components in Single-Wall Carbon Nanotubes Using Ultraviolet-Visible-Near Infrared (UV-Vis-NIR) Absorption Spectroscopy, ed. 2011-09-01, ISO (2011), p. 19.

  19. ISO/TS 11251:2010, Nanotechnologies. Characterization of Single-Wall Carbon Nanotubes Using Thermogravimetric Analysis, ed. 2011-11-15, ISO (2011), p. 22.

  20. K. Danzer, E. Than, and D. Molch, Analytics. Systematic Review [in German], Akademische Verlagsgesellschaft, Leipzig (1976).

  21. H. Remy, Course of Inorganic Chemistry [in German], Akademische Verlagsgesellschaft, Leipzig (1957).

    Google Scholar 

  22. V. Garbuz, A. Kushchevskii, T. Pavlygo, and G. Serdyuk, DSTU ISO 4491-4. Metallic Powders. Determination of Oxygen Content by Reduction Methods. Part. 4. Total Oxygen by Reduction Extraction [in Ukrainian], Derzhstandart Ukrainy, Kyiv (2011), p. 24.

  23. V. V. Garbuz, V. V. Zakharov, V. B. Muratov, et al., “Catalyst distribution in arc synthesis of carbon nanostructured materials,” Nanostrukt. Materialoved., No. 1, 74–81 (2006).

    Google Scholar 

  24. V. A. Dubok, V. I. Kornilova, L. E. Pechentkovskaya, et al., Improvement in Chemical Analysis Methods for Refractory Compounds and Metallic Alloys [in Russian], Naukova Dumka, Kyiv (1988), p. 40.

    Google Scholar 

  25. GOST 27417–87. Metallic Powders. Oxygen Determination Methods [in Russian], Izd. Standartov, Moscow (1988), p. 9.

  26. H. Lux, Experimental Methods in Inorganic Chemistry [in German], J. A. Barth, Leipzig (1954).

    Google Scholar 

  27. Chemist Handbook, Vol. 4: Gas Analysis [in Russian], Khimiya, Moscow–Leningrad (1965), pp. 582–589.

  28. V. V. Garbuz, “Gas analysis methods,” in: V. V. Skorokhod and G. G. Gnesin (eds.), Inorganic Materials Science: Encyclopedia in 2 Vols., Vol. 1: Fundamentals of Materials Science [in Russian], Naukova Dumka, Kyiv (2008), pp. 858–875.

    Google Scholar 

  29. V. V. Garbuz, L. S. Kherovimchuk, V. A. Petrova, et al., “Classification of nanomaterials,” Nanostrukt. Materialoved., No. 3, 78–83 (2012).

    Google Scholar 

  30. S. P. Young, C. C. Young, S. K. Keun, et al., “High yield purification of multiwall carbon nanotubes by selective oxidation during thermal annealing,” Carbon, 39, No. 5, 655–661 (2001).

  31. V. Domnich, S. Reynaud, R. A. Haber, and M. Chhowalla, “Boron carbide: structure, properties, and stability under stress,” J. Am. Ceram. Soc., 94, No. 11, 3605–3628 (2011).

    Article  Google Scholar 

  32. “High-temperature chemistry,” in: I. V. Petryanov (ed.), New Chemistry [Russian translation], Izv. Akad. Nauk SSSR, Moscow (1959), pp. 32–34.

  33. M. Terrones, “Carbon nanotubes: synthesis and properties, electronic devices and other emerging applications,” Int. Mater. Rev., 49, No. 6, 325–377 (2004).

    Article  Google Scholar 

  34. V. V. Garbuz, M. D. Bega, V. A. Petrova, et al., “Studying the oxidation of commercial boron carbide powders by chemical analysis methods,” Powder Metall. Met. Ceram., 53, No. 7–8, 490–496 (2014).

    Article  Google Scholar 

  35. V. P. Sergeiev, V. N. Sokolovskii, V. N. Klevtsov, et al., “On development of porous structure in activation of carbon fiber materials,” Khim. Tverd. Topl., No. 1, 116–120 (1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Garbuz.

Additional information

Translated from Poroshkovaya Metallurgiya, Vol. 56, Nos. 1–2 (513), pp. 50–58, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Garbuz, V.V., Sergeiev, V.P., Suvorova, L.S. et al. Assessing the Internal Structure of Cross-Linked Carbon Nanofibers by Chemical Methods. Powder Metall Met Ceram 56, 38–44 (2017). https://doi.org/10.1007/s11106-017-9869-5

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-017-9869-5

Keywords

Navigation