Abstract
The paper examines the structurization and stress state of ion-plasma condensates of Ti-W-B refractory materials exposed to radiation in deposition. High imbalance is found, which is characteristic of materials condensed with ion bombardment, the mean atomic energy of film-forming particles ranging from several to several tens of electron volts. Models for optimizing the structure and stress state of condensates exposed to radiation to improve their mechanical properties are discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A List of Scientific and Popular Scientific Papers by G. V. Samsonov, Corresponding Member of Ukrainian Soviet Socialist Republic [in Russian], Inst. Probl. Materialovev. AN USSR, Kiev (1978), p. 99.
G. V. Samsonov and A. P. Épik, Refractory Coatings [in Russian], Metallurgiya, Moscow (1973), p. 394.
G. V. Samsonov, T. I. Serebryakova, and V. A. Neronov, Borides [in Russian], Atomizdat, Moscow (1975), p. 374.
Yu. A. Kunitskii, V. V. Morozov, and V. Ya. Shlyuko, High-Temperature Electrode Materials [in Russian], G. V. Samsonov (ed.), Vyshcha Shkola, Kiev (1977), p. 231.
M. V. Luchka, M. V. Kindrachuk, P. I. Mel’nik, etc., Wear-Resistant Diffusion-Deposited Composite Coatings [in Russian], Tekhnika, Kiev (1983), p. 163.
Yu. A. Kunitskii, V. N. Korzhik, and Yu. S. Borisov, Noncrystalline Metallic Materials and Coatings in Technology [in Russian], Tekhnika, Kiev (1988), p. 198.
V. F. Loskutov, V. T. Khizhnyak, Yu. A. Kunitskii, and M. V. Kindrachuk, Diffusion Carbide Coatings [in Russian], Tekhnika, Kiev (1991), p. 168.
G. V. Samsonov, I. F. Pryadko, and L. F. Pryadko, Electron Localization in Solid Body [in Russian], Nauka, Moscow (1976), p. 338.
L. F. Pryadko and Yu. A. Kunitskii, Principles for Predicting Physical and Chemical Properties [in Russian], Kiev (1976), p. 50.
M. M. Ristić, L. F. Pryadko, Yu. A. Kunitskii, et al., Prognosis of the Physico-Chemical Properties of Materials, Center for Multidisciplinary Studies of Belgrade University, Belgrade (1996), p. 156.
A. F. Andreeva, “Preparation and properties of oxide films of rare earth metals,” Powder Metall. Met. Ceram., 37, No. 1–2, 91–93 (1998).
J. Ye, S. Ulrich, K. Sell, et al., “Correlation between plasma particle fluxes, microstructure and properties of titanium diboride thin films,” Sur.& Coat. Techn., 174–175, 959–963 (2003).
O. V. Sobol, S. N. Dub, O. N. Grigorjev, et al., “Structure influence on mechanical properties of Ti-W-B system nano-crystalline coatings,” Func. Mat., 13, No. 1, 105–112 (2006).
A. P. Shpak, O. I. Nakonechna, Yu. A. Kunitskii, and O. V. Sobol’, Mechanical Properties of Titanium-Based Coatings [in Ukrainian], Inst. Metallofiz. NAN Ukrainy, Kiev (2005), p. 84.
O. V. Sobol’, “Phase composition, structure, substructural characteristics, and macrostressed state of ion-plasma nanocrystalline condensates of the quasibinary TiB2-W2B5 system,” Nanosystems, Nanomaterials, Nanotechnologies, 4, No. 3, 707–727 (2006).
O. V. Sobol, “Phase composition, structure and stressed state of tungsten films produced by ion-plasma spraying,” Fizika Metallov i Metallovedinie, 91, No. 1, 60–67 (2001).
O. V. Sobol’, S. N. Dub, O. N. Grigor’ev, et al., “Phase composition, structure, stress state, and mechanical characteristics of triode-sprayed W-Ti-B condensates,” Sverkhtverd. Mater., No. 5, 38–47 (2005).
D. I. Svergun and L. A. Feigin, X-Ray and Neutron Low-Angle Scattering [in Russian], Nauka, Moscow (1986), p. 280.
A. P. Shpak, P. G. Cheremskoy, Yu. A. Kunitskii, and O. V. Sobol’, Cluster and Nanostructured Materials [in Russian], Vol. 3, Akademperiodika, Kiev (2005), p. 516.
A. P. Shpak, O. V. Sobol’, P. G. Cheremoskoy, et al., “Applying a method of low-angle x-ray scattering to study the ordering kinetics in nanostructured condensates,” Nanosystems, Nanomaterials, Nanotechnologies, 4, No. 2, 373–388 (2006).
O. V. Sobol, O. N. Grigorjev, Yu. A. Kunitsky, et al., “Peculiarities of structure state and mechanical characteristics in ion-plasma condensates of quasibinary system borides W2B5-TiB2, Sc. Sint., 38, 63–72 (2006).
O. V. Sobol, “Phase composition, structure and stress state of magnetron sputtered W-Ti condensates,” Func. Mat., 13, No. 4, 577–583 (2006).
O. V. Sobol, “Influence of deposition condition and annealing temperature on phase composition and structure of W-B system ion-plasma condensates,” Func. Mat., No. 3, 387–392.
O. V. Sobol’, A. N. Stetsenko, L. V. Schastlivaya, and V. E. Fil’chikov, “Structural state of nonstoichiometric interstitial phases in magnetron-sputtered tungsten-based condensates,” Proc. 2nd Int. Sci. Symp. on Nanostructured Functional Coatings and Materials for Industry, Vol. 1, IPP Kontrast, Kharkov (2007), pp. 65–69.
O. V. Sobol’, “Nanostructured ordering in W-Ti-B condensates,” Fiz. Tverd. Tela, 49, Issue 6, 1104–1110 (2007).
A. F. Burenkov, F. F. Komarov, M. A. Kumakhov, and M. M. Temkin, Spatial Energy Release from Cascade of Atomic Collisions in Solids [in Russian], Énergoatomizdat, Moscow (1985), p. 248.
O. V. Sobol, “Study of concentration and structural ordering in nano-crystalline ion-plasma condensates of (W, Ti)C solid solution,” Func. Mat., 14, No. 3, 392–397 (2007).
Author information
Authors and Affiliations
Additional information
__________
Translated from Poroshkovaya Metallurgiya, Vol. 47, No. 1–2 (459), pp. 72–83, 2008.
Rights and permissions
About this article
Cite this article
Shpak, A.P., Sobol’, O.V., Kunitskii, Y.A. et al. Radiation factor: Effect on the structure and stress state of condensates produced by ion sputtering of Ti-W-B refractory materials. Powder Metall Met Ceram 47, 54–62 (2008). https://doi.org/10.1007/s11106-008-0009-0
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11106-008-0009-0