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The Grafting of Per-(2,3,6-O-allyl)-β Cyclodextrin onto Derivatized Cotton Cellulose via Thermal and Atmospheric Plasma Techniques

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Abstract

In recent years, cyclodextrin applications have been expanding to include textile finishing, providing new and unique functionalities to the fabric substrates. In this work the grafting of Per-(2,3,6-O-allyl)-β cyclodextrin by plasma and conventional thermofixation methods is described. The fabric substrate was cotton and activated by the surface modification of the fibers by the synthesis of iododeoxycellulose, cellulose peroxide, and a cellulose diazonium salt. Several plasma machines and conventional thermal techniques for fixation were studied. Iododeoxycellulose gave the best results by thermofixation and the in situ mode of the APJeT atmospheric plasma machine. Linoleic, ricinoleic, oleic acids were included in the grafted cyclodextrin fabrics as possible wound healing agents. The cyto-compatibility of the treated samples either included or un-included with fatty acids shows promising results.

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References

  1. Grigoriu AM, Luca C, Grigoriu A (2008) Cyclodextrin applications in the textile industry. Cell Chem Tech 42:103–112

    Google Scholar 

  2. Akira H, Akihito H, Yoshinori T (2006) Cyclodextrin-based supramolecular polymer. Adv Polym Sci 201:1–43

    Article  Google Scholar 

  3. Jozsef S (1998) Introduction and general overview of cyclodextrin chemistry. Chem Rev 98:1743–1753

    Article  Google Scholar 

  4. Martin EM (2004) Cyclodextrins and their uses: a review. Process Biochem 39:1033–1046

    Article  ADS  Google Scholar 

  5. Edward ML (2008) Plasma treatment for improved bonding: a review. J Adhes 30(1):199–218

    Google Scholar 

  6. Shishoo R (2007) Plasma technologies for textiles. Woodhead Publishing, Cambridge, pp 247–275

    Book  Google Scholar 

  7. Vaideki K, Jayakumar S, Rajendran R (2009) Investigation on the enhancement of antimicrobial activity of neem leaf extract treated cotton fabric using air and oxygen DC plasma. Plasma Chem Plasma Process 29:515–534

    Article  Google Scholar 

  8. Halil TS (2008) RF-argon plasma induced surface modification of paper. Surf Rev Lett 15(4):503–508

    Article  Google Scholar 

  9. Marian JT, Cornelia V, Carmen MT, Maria CP (2008) Grafting of Spanish broom (Spartium Junceum) fibers with fatty acids under cold plasma conditions. Cellul Chem Technol 42(7–8):317–333

    Google Scholar 

  10. Boris V, Ariella S, Abraham JD (2008) The isolation of ricinoleic acid from castor oil by salt-solubility-based fractionation for biopharmaceutical application. J Am Chem Soc 85:169–184

    Article  Google Scholar 

  11. Tyroxe LV, Donald JD, Clark MW (1973) Rot resistance and biocidal activity of halodeoxycellulose fabrics. Text Res J 43:715–718

    Article  Google Scholar 

  12. Vigo TL, Daighly BJ, Welch CM (1972) Reaction of cellulose with chlorodimethylformiminium chloride and subsequent reaction with halide ions. Polym Lett 10:397–406

    Article  Google Scholar 

  13. Wade RH, Reeves WA (1964) Preparation and some properties of the diazonium salt of cotton. Text Res J 34:836–841

    Article  Google Scholar 

  14. Yupaporn K, Anawat A, Mongkol S (2008) Treatment of oxidized cellulose fabric with chitosan and its surface activity towards anionic reactive dyes. Cellulose 15:599–608

    Article  Google Scholar 

  15. Liu XD, Nishi N, Tokura S, Sakairi A (2001) Chitosan coated cotton fiber: preparation and physical properties. Carbohydr Polym 44:233–238

    Article  Google Scholar 

  16. Yoshitaka O, Tatsuo U, Hitoshi K (1979) Formation of peroxide on aldehyde cellulose and its ability to initiate graft copolymerization. J Appl Polym Sci 23:837–845

    Article  Google Scholar 

  17. Hitoshi K, Yoshitaka O (1979) Decomposition of peroxide on carboxymethyl cellulose and its ability to initiate graft copolymerization. J Appl Polym Sci 23:241–247

    Article  Google Scholar 

  18. Uno A, Olof S (1962) A colorimetric method for the determination of carbonyl groups in cellulose. Anal Chim Acta 27:434–440

    Article  Google Scholar 

  19. Lahiani-Skiba M, Bouzbouz S (2010) Synthesis of per-substituted hydrophilic and hydrophobic β-Cyclodextrin derivatives. J Incl Phenom Macrocycl Chem. doi:10.1007/s10847-010-9749-9

  20. Stavroula GS, Constantinos AG, Moschos GP (1999) Interaction of β-cyclodextrin with unsaturated and saturated straight chain fatty acid anions studied by phenolphthalein. J Incl Phenom Macrocycl Chem 34:85–96

    Article  Google Scholar 

  21. Dominique D, Amelie B, Shan-Chen Y, Celine P, Monique S (2003) Cyclodextrin and emulsions. Int J Pharm 266:85–90

    Article  Google Scholar 

  22. Wang C, Chen S (2004) Anchoring β-cyclodextrin to retain fragrances on cotton by means of heterobifunctional reactive dyes. Color Technol 120:14–19

    Article  Google Scholar 

  23. Hirotsu T (2006) Plasma graft polymerization of glycidyl methacrylate and cyclodextrin immobilization. Thin Solid Films 506–507:173–175

    Article  Google Scholar 

  24. Schofield WCE, McGettrick JD, Badyal JP (2006) A substrate-independent approach for cyclodextrin functionalized surfaces. J Phys Chem B 110:17161–17166

    Article  Google Scholar 

  25. Myung HL, Kee JY, Sohk-Won K (2000) Grafting onto cotton fiber with acrylamidomethylated β-cyclodextrin and its application. J Appl Polym Sci 78:1986–1991

    Article  Google Scholar 

  26. Hebeish A, El-Hilw ZH (2001) Chemical finishing of cotton using reactive cyclodextrin. Color Technol 117:104–111

    Article  Google Scholar 

  27. Voncina A, Majcen LM (2005) Grafting of cotton with β-cyclodextrin via poly(carboxylic acid). J Appl Polym Sci 96:1323–1328

    Article  Google Scholar 

  28. Kaewprasit C, Hequest E, Abidi N, Gourlot JP (1998) Application of methylene blue adsorption to cotton fiber specific surface area measurement: part I. Methodology. J Cotton Sci 2:164–173

    Google Scholar 

  29. Forster S, Mohr C, Viol W (2005) Investigations of an atmospheric pressure plasma jet by optical emission spectroscopy. Surf Coat Technol 200:827–830

    Article  Google Scholar 

  30. Cherl WP, Seck JK, Sook JP, Jeong HK, Jung KK, Gu BP, Jeong OK, Yeong LH (2002) Inclusion complex of conjugated linoleic acid (CLA) with cyclodextrin. J Agric Food Chem 50:2977–2983

    Article  Google Scholar 

  31. Retrieved from: http://www.txccc.org/home/content_images/HORTON_MTT_Cell_Assay_Protocol.PDF. 15 October 2010

  32. Tseng HJ, Hsu S, Mien-Win W, Tien HH, Pei CT (2009) Nylon textiles grafted with chitosan by open air plasma and their antimicrobial effect. Fibers Polym 10(1):53–59

    Article  Google Scholar 

  33. Garcia JL, Asadine A, Pachernik J, Lehocky M, Junkar I, Humpolicek P, Saha P, Valasek P (2010) Cell proliferation of HaCaT keratinocytes on collagen films modified by argon plasma treatment. Molecules 15:2845–2856

    Article  Google Scholar 

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Correspondence to Samuel M. Hudson.

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Nada, A.A., Hauser, P. & Hudson, S.M. The Grafting of Per-(2,3,6-O-allyl)-β Cyclodextrin onto Derivatized Cotton Cellulose via Thermal and Atmospheric Plasma Techniques. Plasma Chem Plasma Process 31, 605–621 (2011). https://doi.org/10.1007/s11090-011-9300-9

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  • DOI: https://doi.org/10.1007/s11090-011-9300-9

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