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Synthesis and Characterization of Polymethylmethacrylate by Using Glow Discharge Electrolysis Plasma

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Abstract

An approach for polymerization to produce polymethylmethacrylate (PMMA) was developed, in which the reaction was initiated by the glow discharge electrolysis (GDE) rather than chemical initiators. The highest number-average molecular weight (M n) and the lowest polydispersity index (PDI) of the resulting polymer were 1.12 × 106 g/mol and 1.21, respectively. The following parameters such as the applied voltage, discharge time, the content of methylmethacrylate (MMA), the amount of a suspension stabilizer (polyvinyl alcohol), polymerization temperature and time were examined in detail, which could affect the conversion, molecular weight and polydispersity index. The M n and PDI of polymer can be monitored by changing the discharge parameters and polymerization conditions. PMMA was characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FT-IR), cold field emission scanning electron microscopy (FESEM), nuclear magnetic resonance (NMR) and thermogravimetric analysis (TGA). Results indicate that using the GDE technique to initiate the polymerization reaction is successful, because the product obtained has the same properties with one obtained by chemical method, for example, in chemical structure, tacticity and thermal stability. Moreover, the polymer particles for the former are smaller than the latter. The kinetic observation was that the polymerization of MMA initiated by the GDE plasma obeys the first order of reaction with an obvious induction period.

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References

  1. Zhou XD, Ni PH, Yu ZQ (2007) Polymer 48:6262–6271

    Article  Google Scholar 

  2. Zhou Y, Zhu J, Zhu XL, Cheng ZP (2006) Radiat Phys Chem 75:485–492

    Article  ADS  Google Scholar 

  3. Teo BM, Prescott SW, Ashokkumar M, Grieser F (2008) Ultrason Sonochem 15:89–94

    Article  Google Scholar 

  4. Zhang ZB, Zhu XL, Zhu J, Cheng ZP (2006) Polym Bull 56:539–548

    Article  Google Scholar 

  5. Filardo G, Caputo G, Galia A, Calderaro E, Spadaro G (2000) Macromolecules 33:278–283

    Article  ADS  Google Scholar 

  6. Gu CB, Wang DJ, Wang XQ, Huang Y, Zhen Z, Liu XH (2002) J Appl Polym Sci 86:1731–1735

    Article  Google Scholar 

  7. Chen GJ, Zhu XL, Zhu J, Cheng ZP (2004) Macromol Rapid Commun 25:818–824

    Article  Google Scholar 

  8. Joshi R, Schulze RD, Meyer-Plath A, Friedrich JF (2008) Plasma Process Polym 5:695–707

    Article  Google Scholar 

  9. Blanc D, Last A, Franc J, Pavan S, Loubet JL (2006) Thin Solid Films 515:942–946

    Article  ADS  Google Scholar 

  10. Tanglumlert W, Prasassarakich P, Supaphol P, Wongkasemjit S (2006) Surf Coat Tech 200:2784–2790

    Article  Google Scholar 

  11. Guo YB, Hong FC-N (2003) Diam Relat Mater 12:946–952

    Article  Google Scholar 

  12. Chau JLH, Hsieh C-C, Lin Y-M, Li A-K (2008) Prog Org Coat 62:436–439

    Article  Google Scholar 

  13. Sengupta SK, Singh R, Srivastava AK (1998) J Electrochem Soc 145:2209–2213

    Article  Google Scholar 

  14. Gao JZ, Wang AX, Fu Y, Wu JL, Ma DP, Guo X, Li Y, Yang W (2008) Plasma Sci Technol 10:30–38

    Article  ADS  Google Scholar 

  15. Denaro AR, Hickling A (1958) J Electrochem Soc 105:265–270

    Article  Google Scholar 

  16. Hickling A, Ingram MD (1964) J Electroanal Chem 8:65–81

    Article  Google Scholar 

  17. Sengupta SK, Singh R, Srivastava AK (1998) Indian J Chem 37:558–560

    Google Scholar 

  18. Sengupta SK, Sandhir U, Misra N (2001) J Polym Sci Part A Polym Chem 39:1584–1588

    Article  Google Scholar 

  19. Gao JZ, Wang AX, Li Y, Fu Y, Wu JL, Wang YD, Wang YJ (2008) React Funct Polym 68:1377–1383

    Article  Google Scholar 

  20. Zhang ZB, Zhu XL, Zhu J, Cheng ZP (2006) Polymer 47:6970–6977

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported in part by the Key Project of Science and Technology of Education Ministry (00250), the Natural Science Foundation of Gansu Province (3ZS041-A25-028), the Project of KJCXGC-01, NWNU, and Gansu Key Lab of Polymer Materials, China.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, China

    Aixiang Wang, Jinzhang Gao, Li Yuan & Wu Yang

  2. College of Chemistry and Chemical Engineering, Linyi Normal University, Linyi, 276005, China

    Aixiang Wang

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  1. Aixiang Wang
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  2. Jinzhang Gao
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  3. Li Yuan
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  4. Wu Yang
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Correspondence to Jinzhang Gao.

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Wang, A., Gao, J., Yuan, L. et al. Synthesis and Characterization of Polymethylmethacrylate by Using Glow Discharge Electrolysis Plasma. Plasma Chem Plasma Process 29, 387–398 (2009). https://doi.org/10.1007/s11090-009-9185-z

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  • DOI: https://doi.org/10.1007/s11090-009-9185-z

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