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The Effects of Al Addition on the Oxidation Behavior of Ni–Fe–Cr–Nb Alloys at 800 °C in Air

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Abstract

High temperature oxidation of Ni–19Fe–19Cr–5Nb alloys (based on the chemical composition of Alloy718) with different Al contents were investigated to elucidate the effect of Al on oxidation kinetics and scale formation during exposure at 800 °C in air. The experimental results indicated that the oxidation kinetics decreased with increasing Al content. The beneficial effect of Al could be attributed to be a result of the formation of γ′-Ni3Al, which stabilizes γ′′-Ni3(Nb,Al) and kinetically prohibits the coarsening of γ′′-Ni3(Nb,Al) phases. Faster dissolution of finer γ′′-Ni3(Nb,Al) precipitates due to greater γ-matrix / γ′′-Ni3(Nb,Al) interface region in as-received Al-containing alloys could supply greater Nb flux for the formation of CrNbO4, which promotes the formation of an exclusive Cr2O3 scale at the initial stage of oxidation.

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Acknowledgements

This research was partially supported by Nosaka Yoshio Research Grant. This support is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Mechanical Engineering, Nagaoka University of Technology, Nagaoka, Japan

    Yen-Ling Kuo & Makoto Nanko

  2. Department of Mechanical Systems Engineering, Tokyo Metropolitan University, Tokyo, Japan

    Koji Kakehi

  3. Division of Materials Science and Engineering, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido, Japan

    Shigenari Hayashi

Authors
  1. Yen-Ling Kuo
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  2. Koji Kakehi
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  3. Makoto Nanko
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  4. Shigenari Hayashi
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Contributions

Y.L. Kuo: Methodology, Investigation, Visualization, writing-original draft. S.Hayashi: Validation, writing-review & editing. K.Kakehi and M. Nanko: review & editing.

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Correspondence to Yen-Ling Kuo.

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Kuo, YL., Kakehi, K., Nanko, M. et al. The Effects of Al Addition on the Oxidation Behavior of Ni–Fe–Cr–Nb Alloys at 800 °C in Air. High Temperature Corrosion of mater. (2024). https://doi.org/10.1007/s11085-024-10238-x

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  • DOI: https://doi.org/10.1007/s11085-024-10238-x

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