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Effects of Ga, Sn Addition and Microstructure on Oxidation Behavior of Near-α Ti Alloy

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Abstract

We investigated the effects of adding Ga or Sn, with almost the same Al equivalent, on the oxidation behaviors of near-α Ti alloy with the bimodal structure and lamellar structure. The replacement of Sn with Ga decreased the alloy weight gain during oxidation, suppressed oxide growth, and improved adherence between the oxide and substrate. A lamellar alloy structure showed a lower weight gain during oxidation compared to the bimodal structure. Unlike conventional near-α alloys, recrystallization occurred near the oxide/substrate interface in Ga-modified alloy, which may contribute to the release of stress, improvement of the adherence between the oxide and substrate, and prevention of oxide-scale spallation from the Ga-modified alloy. A possible mechanism for the recrystallization in the Ga-modified alloy was also discussed.

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Acknowledgements

The authors gratefully acknowledge the support of the following staff members of the National Institute for Materials Science: Dr. Ayako Ikeda, Mr. Takaaki Hibaru, Mr. Shuji Kuroda, Mr. Kazuhiko Iida, and Mr. Koji Nakazato.

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Authors and Affiliations

  1. Kyushu University, Fukuoka, 810-0395, Japan

    Y. Yang & T. Kitashima

  2. National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047, Japan

    Y. Yang, T. Kitashima, T. Hara, Y. Hara, Y. Yamabe-Mitarai, M. Hagiwara & S. Iwasaki

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  1. Y. Yang
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  2. T. Kitashima
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  3. T. Hara
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  4. Y. Hara
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  5. Y. Yamabe-Mitarai
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  6. M. Hagiwara
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  7. S. Iwasaki
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Correspondence to T. Kitashima.

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Yang, Y., Kitashima, T., Hara, T. et al. Effects of Ga, Sn Addition and Microstructure on Oxidation Behavior of Near-α Ti Alloy. Oxid Met 88, 583–598 (2017). https://doi.org/10.1007/s11085-017-9741-5

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  • DOI: https://doi.org/10.1007/s11085-017-9741-5

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