Skip to main content
SpringerLink
Log in

Sulfur Localization in NiPtAl/Superalloy Systems After High Temperature Isothermal Oxidation

  • Original Paper
  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

Sulfur distribution and its evolution after isothermal oxidation have been studied using secondary ion mass spectrometry. In this work, the systems consist of a Ni-based single-crystal superalloy with a (Ni,Pt)Al bond coat. Two superalloys are compared: AM1 and MCNG. The latter contains Hf as a reactive element. Isothermal oxidations are performed at 1,100 °C under synthetic air for 1, 10, 50, 500 and 1,000 h. After oxidation, sulfur is detected both in the internal and external zones of the bond coat, at the bond coat/oxide interface and inside the oxide scale. An increase of the sulfur signal with oxidation time is registered at the bond coat/oxide interface for the MCNG-based systems whereas the opposite trend is observed for the AM1-based ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Y. Zhang, W. L. Lee, J. A. Haynes, I. G. Wright, B. A. Pint, K. M. Cooley, and P. K. Liaw, Metallurgical and Materials Transactions A 30A, 2679 (1999).

    Google Scholar 

  2. V. K. Tolpygo, D. R. Clarke, and W. H. Murphy, Metallurgical and Materials Transactions A 32, 1467 (2001).

    Google Scholar 

  3. R. Molins, and P. Y. Hou, Surface and Coatings Technology 201, 3841 (2006).

    Article  Google Scholar 

  4. R. Molins, I. Rouzou, and P. Y. Hou, Oxidation of Metals 65, 263 (2006).

    Article  Google Scholar 

  5. T. Gheno, D. Monceau, D. Oquab, and Y. Cadoret, Oxidation of Metals 73, 95 (2010).

    Article  Google Scholar 

  6. R. Molins, I. Rouzou, and P.Y. Hou, Materials Science and Engineering A 454–455, 80 (2007).

    Article  Google Scholar 

  7. P. Y. Hou, Journal of Material Science 44, 1711 (2009).

    Article  Google Scholar 

  8. J. G. Smeggil, and G. G. Peterson, Oxidation of Metals 29, 103 (1988).

    Article  Google Scholar 

  9. J. A. Haynes, B. A. Pint, K. L. More, Y. Zhang, and I. G. Wright, Oxidation of Metals 58, 513 (2002).

    Article  Google Scholar 

  10. P. Y. Hou, and J. Stringer, Oxidation of Metals 38, 323 (1992).

    Article  Google Scholar 

  11. H. J. Grabke, D. Wiemer, and H. V. Viefhaus, Applied Surface Science 47, 243 (1991).

    Google Scholar 

  12. J. L. Smialek, Metallurgical Transactions 22A, 739 (1991).

    Article  Google Scholar 

  13. J. A. Haynes, B. A. Pint, K. L. More, Y. Zhang, and I. G. Wright, Oxidation of Metals 58, 513 (2002).

    Google Scholar 

  14. Y. Cadoret, D. Monceau, M. P. Bacos, P. Josso, V. Maurice, and P. Marcus, Oxidation of Metals 64, 185 (2005).

    Google Scholar 

  15. P. Y. Hou, and K. F. McCarty, Scripta Material 54, 937 (2006).

    Google Scholar 

  16. D. G. Lees, Oxidation of Metals 27, 75 (1987).

    Article  Google Scholar 

  17. J. G. Smeggil, A. W. Funkenbusch, and N. S. Bornstein, Metallurgical and Transactions A 17A, 923 (1986).

    Article  Google Scholar 

  18. M. Chieux, C. Duhamel, R. Molins, L. Rémy, and J.Y. Guedou, 8th International Symposium on High-Temperature Corrosion and Protection of Materials, Les Embiez (2012).

  19. R. Molins, I. Rouzou, L. Rémy, K. Le Biavant-Guerrier, and F. Jomard, Materials at High Temperature 22, 359 (2005).

    Google Scholar 

  20. C. Duhamel, M. Chieux, R. Molins, L. Remy, D. Monceau, A. Vande Put, and J. Y. Guedou, Materials at High Temperature 29, 136 (2012).

  21. A. W. Funkenbusch, J. G. Smeggil, and N. S. Bornstein, Metallurgical Transaction 16A, 1164 (1985).

    Google Scholar 

Download references

Acknowledgments

This work was carried out as part of the PEA Bartholdi project with financial support from the DGA (Direction Générale de l’Armement) and Snecma-SAFRAN. Snecma-SAFRAN is gratefully acknowledged for providing the TBC samples.

Author information

Authors and Affiliations

  1. MINES ParisTech, Centre des Matériaux, CNRS UMR 7633, BP 87, 91003, Evry Cedex, France

    Marion Chieux, Cécilie Duhamel, Régine Molins & Luc Rémy

  2. GEMaC, CNRS UMR 8633, 1 Place Aristide Briand, 92195, Meudon Cedex, France

    François Jomard

  3. SNECMA Groupe SAFRAN, Villaroche, 77550, Moissy-Cramayel, France

    Jean-Yves Guédou

Authors
  1. Marion Chieux
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Cécilie Duhamel
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Régine Molins
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. François Jomard
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Luc Rémy
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jean-Yves Guédou
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Cécilie Duhamel.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chieux, M., Duhamel, C., Molins, R. et al. Sulfur Localization in NiPtAl/Superalloy Systems After High Temperature Isothermal Oxidation. Oxid Met 81, 115–125 (2014). https://doi.org/10.1007/s11085-013-9428-5

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11085-013-9428-5

Keywords

Search

Navigation