Abstract
The radiation shielding properties of lead fluoroborate glasses containing 30 mol% SiO2 have been examined using Phy-X software. The mass attenuation coefficient (MAC) results demonstrated that the tetsed glasses are good attenuator against the low energy radiation, and their attenuation performance diminishes as the energy of the radiation increases. The MAC increases with the addition of PbF2, and the difference in MAC between the glasses with different PbF2 contents is significantly high at lower energy region. At high energy, the difference in MAC between the glasses is small which suggested that as the energy of the photons increases, the MAC for these glasses tend to converge. The linear attenuation coefficient (LAC) for the glasses is investigated and we found that the LAC for the glass with 49 mol% of PbF2 is 58% bigger than that of the glass with 21 mol%. We investigated the average half value layer (\(\overline{HVL }\)) for the tested glasses when exposed to 137Cs and 60Co and the results showed that the values of \(\overline{HVL }\) for 60Co are about double those for 137Cs for all glasses, which suggests that the energies emitted by 60Co in general penetrate the glass sample more deeply in comparison with the photons emitted by 137Cs. The mean free path (MFP) of the glasses against the density shows the desirable properties of PbF2, as the MFP values decrease when the density increases.
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References
Abdelmoneim Saleh, M.G., El-Feky, M.S., Hafiz, N., Kawady, A.: Experimental and theoretical investigation on physical, structure and protection features of TeO2-B2O3 glass doped with PbO in terms of gamma, neutron, proton and alpha particles. Radiat. Phys. Chem.. Phys. Chem. 202, 110586 (2022)
Abouhaswa, A.S.: Esra Kavaz, Bi2O3 effect on physical, optical, structural and radiation safety characteristics of B2O3-Na2O-ZnO-CaO glass system. J. Non-Cryst. Solidscryst. Solids 535, 119993 (2020a)
Abouhaswa, A.S., Kavaz, E.: A novel B2O3-Na2O-BaO-HgO glass system: synthesis, physical, optical and nuclear shielding features. Ceram. Int. 46, 16166–16177 (2020b)
Abualsayed, M.I.: Effect of tungsten on radiation attenuation features of yWO3–(90 − y)TeO2–10Na2O glasses. Radiochim. Acta. Acta 111(3), 225–230 (2023a)
Abualsayed, M.I.: Radiation attenuation attributes for BaO-TiO2- SiO2-GeO2 glass series: a comprehensive study using Phy-X software. Radiochim. Acta. Acta 111(3), 211–216 (2023b)
Aktas, B., Acikgoz, A., Yilmaz, D., Yalcin, S., Dogru, K., Yorulmaz, N.: The role of TeO2 insertion on the radiation shielding, structural and physical properties of borosilicate glasses. J. Nucl. Mater.nucl. Mater. 563, 153619 (2022)
Ambika, M.R., Nagaiah, N., Harish, V., Lokanath, N.K., Sridhar, M.A., Renukappa, N.M., Suman, S.K.: Preparation and characterisation of Isophthalic-Bi2O3 polymer composite gamma radiation shields. Radiat. Phys. Chem.. Phys. Chem. 130, 351–358 (2017)
Bagheri, R., et al.: Gamma ray shielding study of Barium-Bismuth-Borosilicate Glasses as transparent shielding materials using MCNP-4C Code. XCOM Progr Avail Exp Data Nucl Eng Technol 49, 216–223 (2017)
Chaiphaksa, W., Borisut, P., Chanthima, N., Kaewkhao, J., Sanwaranatee, N.W.: Mathematical calculation of gamma rays interaction in bismuth gadolinium silicate glass using WinXCom program. Mater. Today Proc. 65, 2412–2415 (2022)
Demir, I., Gümüş, M., Gökçe, H.S.: Gamma ray and neutron shielding characteristics of polypropylene fiber-reinforced heavyweight concrete exposed to elevated temperatures. Constr. Build. Mater. 257, 119596 (2020)
Dong, M., Xue, X., Yang, He., Liu, D., Wang, C., Li, Z.: A novel comprehensive utilization of vanadium slag: as gamma ray shielding material. J. Hazard. Mater. 318, 751–757 (2016)
Dong, M., Xue, X., Yang, He., Li, Z.: Highly cost-effective shielding composite made from vanadium slag and boron-rich slag and its properties. Radiat. Phys. Chem.. Phys. Chem. 141, 239–244 (2017)
El-Mallawany, R., Sayyed, M.I.: Comparative shielding properties of some tellurite glasses: Part 1. Physica B B 539, 133–140 (2018)
Geidam, I.G., Matori, K.A., Halimah, M.K., Chan, K.T., Muhammad, F.D., Ishak, M., Umar, S.A.: Oxide ion polarizabilities and gamma radiation shielding features of TeO2–B2O3–SiO2 glasses containing Bi2O3 using Phy-X/PSD software. Mater. Today Commun. 31, 103472 (2022)
Hamad, MKh.: Effects of bismuth substitution on the structural and ionizing radiation shielding properties of the novel basnbio perovskites: an experimental study. Mater. Chem. Phys. 308, 128254 (2023)
Hordieiev, Yu.S., Zaichuk, A.V.: Synthesis, structure and properties of PbO–PbF2–B2O3–SiO2 glasses. Chalcogen. Lett. 19(12), 891–899 (2022)
Issa, S.A.M., Mahmoud Ahmad, H.O., Tekin, Y.B., Saddeek, M.I.S.: Effect of Bi2O3 content on mechanical and nuclear radiation shielding properties of Bi2O3-MoO3-B2O3-SiO2-Na2O-Fe2O3 glass system. Res. Phys. 13, 102165 (2019)
Kaewjaeng, S., Kothan, S., Chaiphaksa, W., Chanthima, N., Rajaramakrishna, R., Kim, H.J., Kaewkhao, J.: High transparency La2O3-CaO-B2O3-SiO2 glass for diagnosis x-rays shielding material application. Radiat. Phys. Chem.. Phys. Chem. 160, 41–47 (2019)
Kim, S., Ahn, Y., et al.: Tungsten nanoparticle anchoring on boron nitride nanosheet-based polymer nanocomposites for complex radiation shielding. Compos. Sci. Technol. 221, 109353 (2022)
Naseer, K.A., Marimuthu, K., Mahmoud, K.A., Sayyed, M.I.: Impact of Bi2O3 modifier concentration on barium–zincborate glasses: physical, structural, elastic, and radiation-shielding properties. Eur. Phys. J. plus 136, 116 (2021)
Pacheco, M.H., Gibin, M.S., Silva, M.A., Montagnini, G., Viscovini, R.C., Steimacher, A., Pedrochi, F., Zanuto, V.S., Muniz, R.F.: BaO–reinforced SiO2–Na2O–Ca(O/F2)–Al2O3 glasses for radiation safety: on the physical, optical, structural and radiation shielding properties. J. Alloy. Compd. 960, 171019 (2023)
Rajesh, M., Kavaz, E.: Photoluminescence, radiative shielding properties of Sm3+ ions doped fluoroborosilicate glasses for visible (reddish-orange) display and radiation shielding applications. Mater. Res. Bull. 142, 111383 (2021)
Şakar, E., Özpolat, Ö.F., BünyaminAlım, M.I., Sayyed, M.K.: Phy-X/PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiat. Phys. Chem.. Phys. Chem. 166, 108496 (2020)
Saleh, A.: Comparative shielding features for X/Gamma-rays, fast and thermal neutrons of some gadolinium silicoborate glasses. Prog. Nucl. Energy. Nucl. Energy 154, 104482 (2022)
Saleh, A., Elshazly, R., AbdElghany, H.: The impact of CdO on the radiation shielding properties of zinc-sodium-phosphate glass containing barium. Arab. J. Nucl. Sci. Appl.nucl. Sci. Appl. 55(1), 1–11 (2021)
Sayyed, M.I.: The role of Bi2O3 on radiation shielding characteristics of ternary bismuth tellurite glasses. Optik 270, 169973 (2022)
Sayyed, M.I.: Investigation of radiation shielding features of lithium cadmium silicate glasses. SILICON (2023). https://doi.org/10.1007/s12633-023-02616-y
Sayyed, M. I.: Effect of WO3 on the attenuation parameters of TeO2–La2O3-WO3 glasses for radiation shielding application. Radiat. Phys. Chem. 215, 111319 (2024)
Sayyed, M.I., El-Mallawany, R.: Shielding properties of (100–x) TeO2-(x)MoO3 glasses. Mater. Chem. Phys. 201, 50–56 (2017)
Sayyed, M. I., Kaky , K. M., Şakar, E., Akbaba , U., Taki, M. M., Agar, O.: Gamma radiation shielding investigations for selected germanate glasses, J. Non-Cryst. Solids. 512, 33–40 (2019)
Sayyed, M.I., Mhareb, M.H.A., Alajerami, Y.S.M., Mahmoud, K.A., Imheidat, M.A., Alshahri, F., Alqahtani, M., Al-Abdullah, T.: Optical and radiation shielding features for a new series of borate glass samples. Optik 239, 166790 (2021)
Yonphan, S., Chaiphaksa, W., Kalkornsurapranee, E., Tuljittraporn, A., Kothan, S., Kaewjaeng, S., Intachai, N., Wongdamnern, N., Kedkaew, C., Kim, H.J., Kaewkhao, J.: Development of flexible radiation shielding materials from natural rubber/Sb2O3 composites. Radiat. Phys. Chem.. Phys. Chem. 200, 110379 (2022)
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Sayyed, M.I. PbF2 as a key modulator of gamma radiation shielding in PbO–PbF2–B2O3–SiO2 glass systems. Opt Quant Electron 56, 153 (2024). https://doi.org/10.1007/s11082-023-05737-1
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DOI: https://doi.org/10.1007/s11082-023-05737-1