Abstract
In this work, we reported the radiation-shielding properties of PbO-PbF2-B2O3-SiO2 glass systems. Using Phy-X software, we determined the mass and linear attenuation coefficients, and other related parameters to understand the radiation-shielding performance of these glasses. The mass attenuation coefficient (MAC) values for the glasses at 0.284 MeV range from 0.308 to 0.355 cm2/g, while at 1.333 MeV they are all around 0.055 cm2/g. The MAC results demonstrated that the attenuation capability of the glasses decreased when faced against higher energy photons, while they have better attenuation performing against lower energy radiation. Glass with a composition of 14PbO-42PbF2-14B2O3-30SiO2 possesses the highest MAC and LAC, which means that this glass has the greatest advantage over the other samples. We evaluated the percentage decrease in half value layer (HVL) between the glasses with 21 and 42 mol% of PbF2 and 42PbF2. At 0.284 MeV, the percentage decrease is equal to 24.8%, demonstrating a huge advantage in adding more PbF2 at low energies. As the photon energy increases to 1.333 MeV, the percentage decreases to 13.6%. We investigated the relation between the tenth value layer (TVL) of the glasses and their PbF2 to B2O3 ratio, and we found that the ratio varies from 0.6 to 3 cm. This indicated that raising the PbF2 content relative to the concentration of B2O3 leads to a glass with greater space efficiency. The mean free path (MFP) values for the glasses at 0.284 MeV are equal to 0.669, 0.587, 0.538, and 0.503 cm at 21, 28, 35, and 42 PbF2 mol%, respectively,
Similar content being viewed by others
Data Availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Code Availability
Not applicable.
References
Saleh A (2022) Comparative shielding features for X/Gamma-rays, fast and thermal neutrons of some gadolinium silicoborate glasses. Prog Nucl Energy 154:104482
Chaiphaksa W, Borisut P, Chanthima N, Kaewkhao J, Sanwaranatee NW (2022) Mathematical calculation of gamma rays interaction in bismuth gadolinium silicate glass using WinXCom program. Mater Today: Proceedings 65:2412–2415
Acikgoz A, Demircan G, Yılmaz D, Aktas B, Yalcin S, Yorulmaz N (2022) Structural, mechanical, radiation shielding properties and albedo parameters of alumina borate glasses: role of CeO2 and Er2O3. Mater Sci Eng: B 276:115519
Hanfi MY, Sayyed MI, Lacomme E, Akkurt I, Mahmoud KA (2021) The influence of MgO on the radiation protection andmechanical properties of tellurite glasses. Nucl Eng Technol 53:2000–2010
Kang Du, Wang H, Ma Y, Guan H, Rozelle S (2022) Effect of eyeglasses on student academic performance: what matters? Evidence from a randomized controlled trial in China. Int J Environ Res Public Health 19(17):10923. https://doi.org/10.3390/ijerph191710923
Zubair M, Ahmed E, Hartanto D (2022) Comparison of different glass materials to protect the operators from gamma-rays in the PET using MCNP code. Radiat Phys Chem 190:109818
Aktas B, Acikgoz A, Yilmaz D, Yalcin S, Dogru K, Yorulmaz N (2022) The role of TeO2 insertion on the radiation shielding, structural and physical properties of borosilicate glasses. J Nucl Mater 563:153619
Issa SA, Kumar A, Sayyed MI, Dong MG, Elmahroug Y (2018) Mechanical and gamma-ray shielding properties of TeO2-ZnO-NiO glasses. Mater Chem Phys 212(12):20
Naseer KA, Marimuthu K, Mahmoud KA, Sayyed MI (2021) Impact of Bi2O3 modifier concentration on barium–zincborate glasses: physical, structural, elastic, and radiation-shielding properties. Eur Phys J Plus 136:116
Abouhaswa AS, Kavaz E (2020) Bi2O3 effect on physical, optical, structural and radiation safety characteristics of B2O3-Na2O-ZnO-CaO glass system. J Non-Cryst Solids 535:119993
Naseer KA, Sathiyapriya G, Marimuthu K, Piotrowski T, Alqahtani MS, Yousef ES (2022) Optical, elastic, and neutron shielding studies of Nb2O5 varied Dy3+ doped barium-borate glasses. Optik (Stuttg) 251:168436. https://doi.org/10.1016/j.ijleo.2021.168436
Fidan M, Acikgoz A, Demircan G, Yilmaz D, Aktas B (2022) Optical, structural, physical, and nuclear shielding properties, and albedo parameters of TeO2–BaO–B2O3–PbO–V2O5 glasses. J Phys Chem Solids 163:110543
Kozlovskiy AL, Zdorovets MV (2021) Effect of doping of Ce4+/3+ on optical, strength and shielding properties of (0.5-x)TeO2-0.25MoO-0.25Bi2O3-xCeO2 glasses. Mater Chem Phys 263:124444
Akçalı O, Çaglar M, Toker O, Bayram Bilmez H, Kavanoz B, Içelli O (2020) An investigation on gamma-ray shielding properties of quaternary glassy composite (Na2Si3O7/Bi2O3/ B2O3/Sb2O3) by BXCOM and MCNP 6.2 code. Prog Nucl Energy 125:103364
Bilici S, Kamislioglu M, Guclu EEA (2023) A Monte Carlo simulation study on the evaluation of radiation protection properties of spectacle lens materials. Eur Phys J Plus 138(1):80
Kamislioglu M (2021) Research on the effects of bismuth borate glass system on nuclear radiation shielding parameters. Result Phys 22:103844
Sayyed MI, Kaky KM, Şakar E, Akbaba U, Taki MM, Agar O (2019) Gamma radiation shielding investigations for selected germanate glasses. J Non Cryst Solids 512:33–40
Saleh A, El-Feky MG, Hafiz MS, Kawady NA (2022) Experimental and theoretical investigation on physical, structure and protection features of TeO2-B2O3 glass doped with PbO in terms of gamma, neutron, proton and alpha particles. Radiat Phys Chem 202:110586
Sharma A, Sayyed MI, Agar O, Tekin HO (2019) Simulation of shielding parameters for TeO2-WO3-GeO2 glasses using FLUKA code. Results Phys 13:102199
Shahboub A, El Damrawi G, Saleh A (2021) A new focus on the role of iron oxide in enhancing the structure and shielding properties of Ag2O–P2O5 glasses. Eur Phys J Plus 136:947
Kamislioglu M (2021) An investigation into gamma radiation shielding parameters of the (Al:Si) and (Al+Na):Si-doped international simple glasses (ISG) used in nuclear waste management, deploying Phy-X/PSD and SRIM software. J Mater Sci: Mater Electron 32:12690–12704
Rajesh M, Kavaz E, Raju DP (2021) Photoluminescence, radiative shielding properties of Sm3+ ions doped fluoroborosilicate glasses for visible (reddish-orange) display and radiation shielding applications. Mater Res Bull 142:111383
Sayyed MI (2023) Investigation of radiation shielding features of lithium cadmium silicate glasses. Silicon. https://doi.org/10.1007/s12633-023-02616-y
Geidam IG, Matori KA, Halimah MK, Chan KT, Muhammad FD, Ishak M, Umar SA (2022) Oxide ion polarizabilities and gamma radiation shielding features of TeO2–B2O3–SiO2 glasses containing Bi2O3 using Phy-X/PSD software. Mater Today Commun 31:103472
Pacheco MH, Gibin MS, Silva MA, Montagnini G, Viscovini RC, Steimacher A, Pedrochi F, Zanuto VS, Muniz RF (2023) BaO–reinforced SiO2–Na2O–Ca(O/F2)–Al2O3 glasses for radiation safety: on the physical, optical, structural and radiation shielding properties. J Alloy Compd 960:171019
Kaewjaeng S, Kothan S, Chaiphaksa W, Chanthima N, Rajaramakrishna R, Kim HJ, Kaewkhao J (2019) High transparency La2O3-CaO-B2O3-SiO2 glass for diagnosis x-rays shielding material application. Radiat Phys Chem 160:41–47
Abualsayed MI (2023) Radiation attenuation attributes for BaO-TiO2- SiO2-GeO2 glass series: a comprehensive study using Phy-X software. Radiochim Acta 111(3):211–216
Bagheri R, Moghaddam AK, Yousefnia H (2017) Gamma ray shielding study of barium-bismuth-borosilicate glasses as transparent shielding materials using MCNP-4C code XCOM program, and available experimental data. Nucl Eng Technol 49(216):223
Abualsayed MI (2023) Effect of tungsten on radiation attenuation features of yWO3–(90 − y)TeO2–10Na2O glasses. Radiochim Acta 111(3):225–230
Şakar E, Özpolat ÖF, Alım B, Sayyed MI, Kurudirek M (2020) Phy-X / PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiat Phys Chem 166:108496
Hordieiev YuS, Zaichuk AV (2022) Synthesis, structure and properties of PbO–PbF2–B2O3–SiO2 glasses. Chalcogenide Lett 19(12):891–899
Acknowledgements
Not applicable.
Funding
Not applicable.
Author information
Authors and Affiliations
Contributions
Writing the first draft of the manuscript and reviewing-editing were performed by M. I. Sayyed. All authors reviewed the manuscript.
Corresponding author
Ethics declarations
Ethics Approval
Not applicable.
Consent to Participate
Not applicable.
Consent for Publication
Not applicable.
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Sayyed, M.I. PbO–PbF2–B2O3–SiO2 Glasses: Exploring the Impact of PbF2 in Modulating Radiation Shielding Characteristics. Silicon 16, 1321–1328 (2024). https://doi.org/10.1007/s12633-023-02764-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12633-023-02764-1