Skip to main content
Log in

Tuning the optical characteristics of SiO2/MnO2 nanostructures doped organic blend for photodegradation of organic dyes

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

In present work, the structural and optical characteristics of (PEO–PVP–SiO2–MnO2) nanocomposites films for photodegradation of organic dyes have been investigated. The optical properties of (PEO–PVP–SiO2–MnO2) nanocomposites were studied in the wavelength range (220–820) nm. The results indicated that the optical parameters of (PEO–PVP) blend were enhanced with the increase in SiO2/MnO2 nanoparticles concentration. The absorbance and optical conductivity were increased about 52% and 34% respectively with adding of 4.5 wt% MnO2 NPs, this behavior is useful for optoelectronics, photocatalysis, the solar cells and diodes applications. The energy gap for allowed and forbidden transitions were decreased about 68.4% and 92.4% respectively with adding of 4.5 wt% MnO2 nanoparticles which is useful in low cost and lightweight electronics and optics devices. The results of photodegradation applications showed good degradation, high diffusion and dispersion of nanoparticles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15

Similar content being viewed by others

References

  • Abbas, M., Ali, U., Faizan, M., et al.: Spirofluorene based small molecules as an alternative to traditional non-fullerene acceptors for organic solar cells. Opt. Quant. Electron. 53, 246 (2021). https://doi.org/10.1007/s11082-020-02672-3

    Article  Google Scholar 

  • Abdelghany, A., Abdelrazek, E., Rashad, D.: Impact of in situ preparation of CdSflled PVP nano-composite. J. Spectrochim. Acta A Mol. Biomol. Spectrosc. 130, 302–308 (2014)

    Article  ADS  Google Scholar 

  • Agool, I.R., Kadhim, K.J., Hashim, A.: Preparation of (polyvinyl alcohol–polyethylene glycol–polyvinyl pyrrolidinone–titanium oxide nanoparticles) nanocomposites: electrical properties for energy storage and release. Int. J. Plast. Technol. (2016). https://doi.org/10.1007/s12588-016-9144-5

    Article  Google Scholar 

  • Ahmad, A., Awatif, A., Abdul-Majied, Z.: Doppingefect on optical constants of polymethylmethacrylate (PMMA). J. Eng. Technol. 25(4), 558–568 (2007)

    Google Scholar 

  • Ahmed, H., Hashim, A.: Fabrication of PVA/NiO/SiC nanocomposites and studying their dielectric properties for antibacterial applications. Egypt. J. Chem. (2020). https://doi.org/10.21608/EJCHEM.2019.11109.1712

    Article  Google Scholar 

  • Akram, M., Siddique, S.A., Iqbal, J., Hussain, R., Mehboob, M.Y., Siddique, M.B.A., Naveed, S., Ali, B., Hanif, A., Sajid, M., Shoukat, S.: End-capped engineering of bipolar diketopyrrolopyrrole based small electron acceptor molecules for high performance organic solar cells. Comput. Theor. Chem. (2021). https://doi.org/10.1016/j.comptc.2021.113242

    Article  Google Scholar 

  • Al-Attiyah, K.H.H., Hashim, A., Obaid, S.F.: Fabrication of novel (carboxy methyl cellulose–polyvinylpyrrolidone–polyvinyl alcohol)/lead oxide nanoparticles: structural and optical properties for gamma rays shielding applications. Int. J. Plast. Technol. (2019). https://doi.org/10.1007/s12588-019-09228-5

    Article  Google Scholar 

  • Ambrosio, R., Carrillo, A., de la Luz Mota, M., de la Torre, K., Torrealba, R., Moreno, M., Vazquez, H., Flores, J., Vivaldo, I.: Polymeric nanocomposites membranes with high permittivity based on PVA—ZnO nanoparticles for potential applications in flexible electronics. Preprints (2018)

  • Asogwa, P.U.: Band gap shift and optical characterization of PVA- Capped PbO thin films: effect of thermal annealing. Chalcogenide Lett. 8(3), 163–170 (2011)

    Google Scholar 

  • Attia, G., Abd El-Kader, M.F.H.: Structural, optical and thermal characterization of PVA/2HEC polyblendflms. Int. J. Electrochem. Sci. 8, 5672–5687 (2013)

    Google Scholar 

  • Batool, M., Khurshid, S., Qureshi, Z., Hassan, A., Siddique, M.B.A., Naveed, S., Siddique, S.A.: Study of biogenically fabricated transition metal oxides nanoparticles on oral cavity infectious microbial strains. Inorgan. Nano-Metal Chem. 51(6), 856–866 (2021a). https://doi.org/10.1080/24701556.2020.1811729

    Article  Google Scholar 

  • Batool, M., Khurshid, S., Daoush, W.M., Siddique, S.A., Nadeem, T.: Green synthesis and biomedical applications of ZnO nanoparticles: role of PEGylated-ZnO nanoparticles as doxorubicin drug carrier against MDA-MB-231(TNBC) cells line. Curr. Comput. Aided Drug Des. 11(4), 344 (2021b). https://doi.org/10.3390/cryst11040344

    Article  Google Scholar 

  • Chiladova, A., Wiener, J., Polakova, M.: Testing the phoyocatalytic activity of TiO2 nanoparticles with potassium permanganate solution. NanoConTM 21, 9 (2011)

    Google Scholar 

  • DeMerlis, C.C., Schoneker, D.R.: Review of the oral toxicity of polyvinyl alcohol (PVA). Food Chem. Toxicol 41(3), 319–326 (2003)

    Article  Google Scholar 

  • Hadi, A., Rashid, F.L., Hussein, H.Q., Hashim, A.: Novel of water with (CeO2–WC) and (SiC–WC) nanoparticles systems for energy storage and release applications. IOP Conf. Ser. Mater. Sci. Eng. 518(3), 5 (2019). https://doi.org/10.1088/1757-899X/518/3/032059

    Article  Google Scholar 

  • Hadi, A., Hashim, A., Al-Khafaji, Y.: Structural, optical and electrical properties of PVA/PEO/SnO2 new nanocomposites for flexible devices. Trans. Electr. Electron. Mater. (2020). https://doi.org/10.1007/s42341-020-00189-w

    Article  Google Scholar 

  • Hashim, A.: Enhanced structural, optical, and electronic properties of In2O3 and Cr2O3 nanoparticles doped polymer blend for flexible electronics and potential applications. J. Inorganic Organ. Polym. Mater. (2020). https://doi.org/10.1007/s10904-020-01528-3

    Article  Google Scholar 

  • Hashim, A., Hadi, A.: A novel piezoelectric materials prepared from (carboxymethyl cellulose-starch) blend-metal oxide nanocomposites. Sensor Lett. (2017). https://doi.org/10.1166/sl.2017.3910

    Article  Google Scholar 

  • Hashim, A., Hadi, A.: Novel pressure sensors made from nanocomposites (biodegradable polymers–metal oxide nanoparticles): fabrication and characterization. Ukrain. J. Phys. (2018). https://doi.org/10.15407/ujpe63.8.754

    Article  Google Scholar 

  • Hashim, A., Hamad, Z.S.: Fabrication and characterization of polymer blend doped with metal carbide nanoparticles for humidity sensors. J. Nanostruct. 9(2), 340–348 (2019). https://doi.org/10.22052/JNS.2019.02.016

    Article  Google Scholar 

  • Hashim, A., Hamad, Z.S.: Lower cost and higher UV-absorption of polyvinyl alcohol/silica nanocomposites for potential applications. Egypt. J. Chem. (2020). https://doi.org/10.21608/EJCHEM.2019.7264.1593

    Article  Google Scholar 

  • Hashim, A., Habeeb, M.A., Hadi, A., Jebur, Q.M., Hadi, W.: Fabrication of novel (PVA–PEG–CMC–Fe3O4) magnetic nanocomposites for piezoelectric applications. Sensor Lett. (2017). https://doi.org/10.1166/sl.2018.3935

    Article  Google Scholar 

  • Hashim, A., Al-Khafaji, Y., Hadi, A.: Synthesis and characterization of flexible resistive humidity sensors based on PVA/PEO/CuO nanocomposites. Trans. Electr. Electron. Mater. (2019). https://doi.org/10.1007/s42341-019-00145-3

    Article  Google Scholar 

  • Hashim, A., Abduljalil, H.M., Ahmed, H.: Fabrication and characterization of (PVA–TiO2)1–x/SiCx nanocomposites for biomedical applications. Egypt. J. Chem. (2020). https://doi.org/10.21608/EJCHEM.2019.10712.1695

    Article  Google Scholar 

  • Indolia, A., Gaur, M.: Optical properties of solution grown PVDF–ZnO nanocomposite thin flms. J. Polym. Res. 20, 43–50 (2013)

    Article  Google Scholar 

  • Jadoon, T., Carter-Fenk, K., Siddique, M.B.A., Herbert, J.M., Hussain, R., Iqbal, S., Iqbal, J., Ayub, K.: Silver clusters tune up electronic properties of graphene nanoflakes: a comprehensive theoretical study. J. Mol. Liquids (2020). https://doi.org/10.1016/j.molliq.2019.111902

    Article  Google Scholar 

  • Kesavan, K., Mathew, C.M., Rajendran, S., Ulaganathan, M.: Preparation and characterization of novel solid polymer blend electrolytes based on poly (vinyl pyrrolidone) with various concentrations of lithium perchlorate. Mater. Sci. Eng. 184, 26–33 (2014a)

    Article  Google Scholar 

  • Kesavan, K., Mathew, C.M., Rajendran, S.: Lithium ion conduction and ion–polymer interaction in poly(vinyl pyrrolidone) based electrolytes blended with different plasticizers. Chinese Chem. Lett. 25, 1428–1434 (2014b)

    Article  Google Scholar 

  • Kumar, K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K., Narasimha, V.: Electrical conduction mechanism in NaClcomplexed PEO/PVP polymer blend electrolytes. J. Non-Cryst. Solids 358(23), 3205–3211 (2012)

    Article  ADS  Google Scholar 

  • Kumar, K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K., Narasimha, V.: Investigations on PEO/PVP/NaBrcomplexed polymer blend electrolytes for electrochemical cell applications. J. Membrsci. 454, 200–211 (2014a)

    Google Scholar 

  • Kumar, K.N., Sivaiah, K., Buddhudu, S.: Structural, thermal and optical properties of Tb3+, Eu3+ and co-doped (Tb3++ Eu3+): PEO + PVP polymer films. J. Lumin. 147, 316–323 (2014b)

    Article  Google Scholar 

  • Kumar, K.K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K., Rao, V.V.R.N.: Investigations on PEO/PVP/NaBrcomplexed polymer blend electrolytes for electrochemical cell applications. J. Memb. Sci. 454, 200–211 (2014c)

    Article  Google Scholar 

  • Meng, D., Cao, X.Z., Xia, R., Zhou, Z., Jin, S., Wang, B.: Magnetic field aligned orderly arrangement of Fe3O4 nanoparticles in CS/PVA/Fe3O4 membranes. Chin. Phys. b. 27(2), 027805 (2018)

    Article  ADS  Google Scholar 

  • Misra, N., Biswal, J., Gupta, A., Sainis, J.K., Sabharwal, S.: Gamma radiation induced synthesis of gold nanoparticles in aqueous polyvinyl pyrrolidone solution and its application for hydrogen peroxide estimation. Radiat. Phys Chem. 81, 195–200 (2012)

    Article  ADS  Google Scholar 

  • Mohammed, A.: Improvement of thermal properties for binary systems PVF-Ph, PVF-B by addition of silicon carbide. Eng. Technol. 25(7), 256–949 (2007)

    Google Scholar 

  • Noweell, M., Pandel, N., Liu, X.: Characterization of sputtered CdTe thin films electron batterdifraction and correlation with device performance. J. Micosc. Microanal. 21(4), 27–35 (2015)

    Google Scholar 

  • Phukan, P., Saikia, D.: Optical and structural investigation of CdSe quantum dots dispersed in PVA matrix and photovoltaic applications. Int. J. Photoenergy 728280 (2013). https://doi.org/10.1155/2013/728280

  • Rashid, F.L., Talib, S.M., Hadi, A., Hashim, A.: Novel of thermal energy storage and release: water/(SnO2–TaC) and water/(SnO2–SiC) nanofluids for environmental applications. IOP Conf. Ser. Mater. Sci. Eng. 454, 012113 (2018a). https://doi.org/10.1088/1757-899X/454/1/012113

    Article  Google Scholar 

  • Rashid, F.L., Hadi, A., Al-Garah, N.H., Hashim, A.: Novel phase change materials, MgO nanoparticles, and water based nanofluids for thermal energy storage and biomedical applications. Int. J. Pharm. Phytopharmacol. Res. 8, 46–56 (2018b)

    Google Scholar 

  • Salman, S., Abduallah, M., Bakr, N.: Optical characterization of red methyl doped poly (vinyl alcohol) flms. Int. J Eng. Technol. Res. 2(4), 126–128 (2014a)

    Google Scholar 

  • Salman, S., Bakr, N., Mahmood, M.: Preparation and study of some optical properties of (PVA Ni(CH3COO)2) composites. Int. J. Curr. Res. 6(11), 9638–9643 (2014b)

    Google Scholar 

  • Sekhar, B., Subramanyam, C., Bose, G., VenkataRamanaiah, M., Ravikumar, R.: Investigation on spectroscopic properties Of CO2+ doped CdSe nanopolymer. RJPBCS 9(4), 798–805 (2018)

    Google Scholar 

  • Siddique, M.B.A., Hussain, R., Siddique, S.A., Mehboob, M.Y., Irshad, Z., Iqbal, J., Adnan, M.: Designing triphenylamine-configured donor materials with promising photovoltaic properties for highly efficient organic solar cells. Chem. Select (2020a). https://doi.org/10.1002/slct.202001989

    Article  Google Scholar 

  • Siddique, S.A., Siddique, M.B.A., Hussain, R., Liu, X., Mehboob, M.Y., Irshad, Z., Adnan, M.: Efficient tuning of triphenylamine-based donor materials for high-efficiency organic solar cells. Comput. Theor. Chem. (2020b). https://doi.org/10.1016/j.comptc.2020.113045

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ahmed Hashim.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hussien, H.A.J., Kadhim, R.G. & Hashim, A. Tuning the optical characteristics of SiO2/MnO2 nanostructures doped organic blend for photodegradation of organic dyes. Opt Quant Electron 53, 501 (2021). https://doi.org/10.1007/s11082-021-03157-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-021-03157-7

Keywords

Navigation