Abstract
The role of various substrate temperatures on the structural and optoelectronic properties of sputtered zinc sulfide (ZnS) thin films has been investigated in this work. The study of prepared film characterization has been done by XRD, AFM, UV–Vis spectrometry and Hall-effect measurement analysis. XRD patterns of the room temperature grown films reveal an amorphous nature, while the films deposited at 100 °C, 200 °C. 300 °C and 400 °C are found to be polycrystalline having the (111) preferential orientation. The optical bandgap values are found in the range of 3.18–3.61 eV depending on the substrate temperatures. The bulk and surface carrier densities are found in the order of 1012 cm−3 and 107 cm−3, respectively. The growth temperatures are also observed to have a significant effect on the electrical characteristic of the deposited films.
Similar content being viewed by others
References
Abou-Ras, D., Rudmann, D., Kostorz, G., Spiering, S., Powalla, M., Tiwari, A.N.: Microstructural and chemical studies of interfaces between Cu(In, Ga)Se2 and In2S3 layers. J. Appl. Phys. 97, 084908 (2005)
Ashokkumar, M., Muthukumaran, S.: Cu doping effect on optical, structural and morphological properties of Cd0.9Zn0.1S thin films. J. Lumin. 145, 167–174 (2014)
Assadi, M.K., Bakhoda, S., Saidur, R., Hanaei, H.: Recent progress in perovskite solar cells. Renew. Sustain. Energy Rev. 81, 2812–2822 (2018)
Balaji, G., Balasundaraprabhu, R., Prasanna, S., Prabavathy, N., Venkatraman, M.R., Asokan, V., et al.: Investigations on Hot-wall deposited Cadmium Sulphide buffer layer for thin film solar cell. Mater. Lett. 222, 82–87 (2018)
Benyahia, K., Benhaya, A., Aida, M.S.: ZnS thin films deposition by thermal evaporation for photovoltaic applications. J. Semicond. 36, 103001 (2015)
Chalana, S.R., Vinodkumar, R., Navas, I., Ganesan, V., Mahadevan Pillai, V.P.: Influence of argon ambience on the structural, morphological and optical properties of pulsed laser ablated zinc sulfide thin films. J. Lumin. 132, 944–952 (2012)
Chelvanathan, P., Yusoff, Y., Haque, F., Akhtaruzzaman, M., Alam, M.M., Alothman, Z.A., et al.: Growth and characterization of RF-sputtered ZnS thin film deposited at various substrate temperatures for photovoltaic application. Appl. Surf. Sci. 334, 138–144 (2015)
Cherouana, A., Labbani, R.: Study of CZTS and CZTSSe solar cells for buffer layers selection. Appl. Surf. Sci. 424, 251–255 (2017)
Deguchi, H.: Application of solar cell using II–III–VI compound thin film fabricated by conventional sputtering process. Phys. Status Solidi C 11, 1286–1291 (2014)
Desgreniers, S., Beaulieu, L., Lepage, I.: Pressure-induced structural changes in ZnS. Phys. Rev. B. 61, 8726–8733 (2000)
Dhawale, D.S., Ali, A., Lokhande, A.C.: Impact of various dopant elements on the properties of kesterite compounds for solar cell applications: a status review. Sustain. Energy Fuels 3, 1365–1383 (2019)
Eid, A.H., Salim, S., Sedik, M.B., Abd Elkader, O., Dahy, T., Abouelkhair, H.: Preparation and characterization of ZnS thin films. J. Appl. Sci. Res. 6, 777–784 (2010)
Faiazul, H., Kazi Sajedur, R., Md, A., Huda, A., Tiong Sieh, K., Nowshad, A.: Properties of sputtered ZnS thin films for photovoltaic application. Mater. Res. Express. 5, 096409 (2018)
Fang, L., Jiang, Y., Zhu, S., Ding, J., Zhang, D., Yin, A., et al.: Substrate temperature dependent properties of sputtered AlN: Er thin film for in-situ luminescence sensing of Al/AlN multilayer coating health. Mater. (Basel). 11, 2196 (2018)
Ghosh, A., Thangavel, R., Gupta, A.: Solution-processed Cd free kesterite Cu2ZnSnS4 thin film solar cells with vertically aligned ZnO nanorod arrays. J. Alloy. Compd. 694, 394–400 (2017)
Giraldo, S., Jehl, Z., Placidi, M., Izquierdo-Roca, V., Pérez-Rodríguez, A., Saucedo, E.: Progress and perspectives of thin film kesterite photovoltaic technology: a critical review. Adv. Mater. 31, 1806692 (2019)
Han, G., Zhang, S., Boix, P.P., Wong, L.H., Sun, L., Lien, S.-Y.: Towards high efficiency thin film solar cells. Prog. Mater Sci. 87, 246–291 (2017)
Haque, F., Rahman, K.S., Islam, M.A., Chelvanathan, P., Chowdhury, T.H., Alam, M.M., et al: A comparative study on ZnS thin films grown by thermal evaporation and magnetron sputtering. In: 2013 IEEE Student Conference on Research and Developement. pp. 260–264 (2013)
Haque, F., Khan, N.A., Rahman, K.S., Islam, M., Alam, D.M.M., Sopian, K., et al.: Prospects of zinc sulphide as an alternative buffer layer for CZTS solar cells from numerical analysis. In: 8th International Conference on Electrical and Computer Engineering. pp. 504–507 (2014a)
Haque, F., Rahman, K.S., Islam, M.A., Rashid, M.J., Akhtaruzzaman, M., Alam, M.M., et al.: Growth optimization of ZnS thin films by RF magnetron sputtering as prospective buffer layer in thin film solar cells. Chalcogenide Lett. 11, 189–197 (2014b)
Haque, F., Elumalai, N.K., Wright, M., Mahmud, M.A., Wang, D., Upama, M.B., et al.: Annealing induced microstructure engineering of antimony tri-selenide thin films. Mater. Res. Bull. 99, 232–238 (2018a)
Haque, F., Wright, M., Mahmud, M.A., Yi, H., Wang, D., Duan, L., et al.: Effects of hydroiodic acid concentration on the properties of CsPbI3 perovskite solar cells. ACS Omega. 3, 11937–11944 (2018b)
Hernández-Fenollosa, M.A., López, M.C., Donderis, V., González, M., Marí, B., Ramos-Barrado, J.R.: Role of precursors on morphology and optical properties of ZnS thin films prepared by chemical spray pyrolysis. Thin Solid Films 516, 1622–1625 (2008)
Hong, J., Lim, D., Eo, Y.-J., Choi, C.: Chemical bath deposited ZnS buffer layer for Cu(In, Ga)Se2 thin film solar cell. Appl. Surf. Sci. 432, 250–254 (2018)
Hsu, C.T.: Epitaxial growth of II–VI compound semiconductors by atomic layer epitaxy. Thin Solid Films 335, 284–291 (1998)
Hwang, D.H., Ahn, J.H., Hui, K.N., Hui, K.S., Son, Y.G.: Structural and optical properties of ZnS thin films deposited by RF magnetron sputtering. Nanoscale Res. Lett. 7, 26 (2012)
Islam, M.M., Ishizuka, S., Yamada, A., Sakurai, K., Niki, S., Sakurai, T., et al.: CIGS solar cell with MBE-grown ZnS buffer layer. Sol. Energy Mater. Sol. Cells 93, 970–972 (2009)
Islam MA, Hossain MS, Aliyu MM, Husna J, Karim MR, Sopian K, et al.: Effects of thermal annealing on structural and optical properties of sputtered CdS thin films for photovoltaic application. In: 2012 38th IEEE Photovoltaic Specialists Conference, pp. 000151-5 (2012a)
Islam, M.A., Hossain, M.S., Aliyu, M.M., Sulaiman, Y., Karim, M.R., Sopian, K. et al.: Comparative study of ZnS thin films grown by chemical bath deposition and magnetron sputtering. In: 2012 7th International Conference on Electrical and Computer Engineering, pp. 86–89 (2012b)
Islam, M.A., Huda, Q., Hossain, M.S., Aliyu, M.M., Karim, M.R., Sopian, K., et al.: High quality 1μm thick CdTe absorber layers grown by magnetron sputtering for solar cell application. Curr. Appl. Phys. 13, S115–S121 (2013)
Kim, J., Park, C., Pawar, S.M., Inamdar, A.I., Jo, Y., Han, J., et al.: Optimization of sputtered ZnS buffer for Cu2ZnSnS4 thin film solar cells. Thin Solid Films 566, 88–92 (2014)
Lee, T.D., Ebong, A.U.: A review of thin film solar cell technologies and challenges. Renew. Sustain. Energy Rev. 70, 1286–1297 (2017)
Lee, W.-J., Cho, D.-H., Yoo, J., Yoo, J., Wi, J.-H., Han, W.S., et al.: Interface and bulk properties of Cu(In, Ga)Se2 solar cell with a cracker-ZnS buffer layer. Curr. Appl. Phys. 18, 405–410 (2018)
Li, W., Chen, J., Yan, C., Hao, X.: The effect of ZnS segregation on Zn-rich CZTS thin film solar cells. J. Alloy. Compd. 632, 178–184 (2015)
Lindahl, J., Keller, J., Donzel-Gargand, O., Szaniawski, P., Edoff, M., Törndahl, T.: Deposition temperature induced conduction band changes in zinc tin oxide buffer layers for Cu(In, Ga)Se2 solar cells. Sol. Energy Mater. Sol. Cells 144, 684–690 (2016)
Minemoto, T., Okamoto, A., Takakura, H.: Sputtered ZnO-based buffer layer for band offset control in Cu(In, Ga)Se2 solar cells. Thin Solid Films 519, 7568–7571 (2011)
Mo, C.B., Park, S.J., Bae, S., Lim, M-h, Nam, J., Kim, D., et al.: Impact of buffer layer process and Na on shunt paths of monolithic series-connected CIGSSe thin film solar cells. Sci. Rep. 9, 3666 (2019)
Moradi, M., Teimouri, R., Saadat, M., Zahedifar, M.: Buffer layer replacement: a method for increasing the conversion efficiency of CIGS thin film solar cells. Opt. Int. J. Light Electron Opt. 136, 222–227 (2017)
Nagoya, A., Asahi, R., Kresse, G.: First-principles study of Cu2ZnSnS4and the related band offsets for photovoltaic applications. J. Phys. Condens. Matter 23, 404203 (2011)
Nair, P.K., Nair, M.T.S., Garcı́a, V.M., Arenas, O.L., Peña, A.C.Y., Ayala, I.T., et al.: Semiconductor thin films by chemical bath deposition for solar energy related applications. Sol. Energy Mater. Sol. Cells 52, 313–344 (1998)
Nakada, T., Mizutani, M., Hagiwara, Y., Kunioka, A.: High-efficiency Cu(In, Ga)Se2 thin-film solar cells with a CBD-ZnS buffer layer. Sol. Energy Mater. Sol. Cells 67, 255–260 (2001)
Nguyen, M., Ernits, K., Tai, K.F., Ng, C.F., Pramana, S.S., Sasangka, W.A., et al.: ZnS buffer layer for Cu2ZnSn(SSe)4 monograin layer solar cell. Sol. Energy 111, 344–349 (2015)
Offor, P.O., Okorie, B.A., Lokhande, C.D., Patil, P.S., Ezema, F.I., Omah, A.D., et al.: The properties of spray-deposited zinc sulfide thin films using trisodium citrate complexant. Int. J. Adv. Manuf. Technol. 95, 1849–1857 (2018)
Pal, K., Singh, P., Bhaduri, A., Thapa, K.B.: Current challenges and future prospects for a highly efficient (> 20%) kesterite CZTS solar cell: a review. Sol. Energy Mater. Sol. Cells 196, 138–156 (2019)
Park, J.Y., Chalapathy, R.B.V., Lokhande, A.C., Hong, C.W., Kim, J.H.: Fabrication of earth abundant Cu2ZnSnSSe4 (CZTSSe) thin film solar cells with cadmium free zinc sulfide (ZnS) buffer layers. J. Alloy. Compd. 695, 2652–2660 (2017)
Pettersson, J., Platzer-Björkman, C., Edoff, M.: Temperature-dependent current–voltage and lightsoaking measurements on Cu(In, Ga)Se2 solar cells with ALD-Zn1-xMgxO buffer layers. Prog. Photovolt. Res. Appl. 17, 460–469 (2009)
Qi, L., Mao, G., Ao, J.: Chemical bath-deposited ZnS thin films: preparation and characterization. Appl. Surf. Sci. 254, 5711–5714 (2008)
Rahman, K.S., Haque, F., Khan, N.A., Islam, M., Alam, M.M., Alothman, Z., et al.: Effect Of CdCl2 treatment on thermally evaporated CdTe thin films. Chalcogenide Lett. 11, 129–139 (2014)
Ramanujam, J., Verma, A., González-Díaz, B., Guerrero-Lemus, R., del Cañizo, C., García-Tabarés, E., et al.: Inorganic photovoltaics—planar and nanostructured devices. Prog. Mater Sci. 82, 294–404 (2016)
Rumberg, A., Sommerhalter, C., Toplak, M., Jäger-Waldau, A., Lux-Steiner, M.C.: ZnSe thin films grown by chemical vapour deposition for application as buffer layer in CIGSS solar cells. Thin Solid Films 361–362, 172–176 (2000)
Shao, L.-X., Chang, K.-H., Hwang, H.-L.: Zinc sulfide thin films deposited by RF reactive sputtering for photovoltaic applications. Appl. Surf. Sci. 212–213, 305–310 (2003)
Shim, H.J., Ghorpade, U.V., Surywanshi, M.P., Gang, M., Kim, J.H.: Studies on the influence of etching solution on the properties of Cu2ZnSn(S, Se4) thin film solar cells. Thin Solid Films 670, 1–5 (2019)
Shin, S.W., Ra Kang, S., Ho Yun, J., Moholkar, A.V., Moon, J.-H., Yong Lee, J., et al.: Effect of different annealing conditions on the properties of chemically deposited ZnS thin films on ITO coated glass substrates. Sol. Energy Mater. Sol. Cells 95, 856–863 (2011)
Sinha, S., Nandi, D.K., Kim, S.-H., Heo, J.: Atomic-layer-deposited buffer layers for thin film solar cells using earth-abundant absorber materials: a review. Sol. Energy Mater. Sol. Cells 176, 49–68 (2018)
Takata, S., Minami, T., Miyata, T., Nanto, H.: Growth of hexagonal ZnS thin films by MOCVD using CS2 gas as a sulfur source. J. Cryst. Growth 86, 257–262 (1988)
Tec-Yam, S., Rojas, J., Rejón, V., Oliva, A.I.: High quality antireflective ZnS thin films prepared by chemical bath deposition. Mater. Chem. Phys. 136, 386–393 (2012)
Tumbul, A., Aslan, F., Göktaş, A., Mutlu, I.H.: All solution processed superstrate type Cu2ZnSnS4 (CZTS) thin film solar cell: effect of absorber layer thickness. J. Alloy. Compd. 781, 280–288 (2019)
Ubale, A.U., Kulkarni, D.K.: Preparation and study of thickness dependent electrical characteristics of zinc sulfide thin films. Bull. Mater. Sci. 28, 43–47 (2005)
Valenzuela, A.A., Russer, P.: High Q coplanar transmission line resonator of YBa2Cu3O7−x on MgO. Appl. Phys. Lett. 55, 1029–1031 (1989)
Vigil-Galán, O., Courel, M., Andrade-Arvizu, J.A., Sánchez, Y., Espíndola-Rodríguez, M., Saucedo, E., et al.: Processing pathways of Cu2Zn(SnGe)Se4 based solar cells: the role of CdS buffer layer. Mater. Sci. Semicond. Process. 67, 14–19 (2017)
Wu, X., Lai, F., Lin, L., Lv, J., Zhuang, B., Yan, Q., et al.: Optical inhomogeneity of ZnS films deposited by thermal evaporation. Appl. Surf. Sci. 254, 6455–6460 (2008)
Zhang, J., Feng, J., Feng, Y., Liao, J., Xue, S., Shao, L., et al.: Fabrication of Zn(O, S) thin films by ozone assisted photochemical deposition and its potential applications as buffer layers in kesterite-based thin film solar cells. Thin Solid Films 670, 80–85 (2019)
Zhou, L., Xue, Y., Li, J.: Study on ZnS thin films prepared by chemical bath deposition. J. Environ. Sci. 21, S76–S79 (2009)
Zhuk, S., Kushwaha, A., Wong, T.K.S., Masudy-Panah, S., Smirnov, A., Dalapati, G.K.: Critical review on sputter-deposited Cu2ZnSnS4 (CZTS) based thin film photovoltaic technology focusing on device architecture and absorber quality on the solar cells performance. Sol. Energy Mater. Sol. Cells 171, 239–252 (2017)
Acknowledgements
The authors wish to express the deepest appreciation to the Ministry of Education Malaysia for the support through FRGS grant with the code of FRGS/1/2018/TK05/UNITEN/02/1. Authors would also like to acknowledge the contribution of the Universiti Tenaga Nasional (@The National Energy University) of Malaysia for their contribution through BOLD2025 Program. Gratitude is also attributed to the Center for Integrated Systems Engineering and Advanced Technologies (INTEGRA) of The National University of Malaysia (@UKM) for other supports.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Haque, F., Rahman, K.S., Islam, M.A. et al. Effects of growth temperatures on the structural and optoelectronic properties of sputtered zinc sulfide thin films for solar cell applications. Opt Quant Electron 51, 278 (2019). https://doi.org/10.1007/s11082-019-1994-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11082-019-1994-6