Abstract
This paper reports about a study of the local plasmonic resonance (LSPR) produced by metal nanoparticles embedded in a dielectric or semiconductor matrix. It is presented an analysis of the LSPR for different nanoparticle metals, shapes, and embedding media composition. Metals of interest for nanoparticle composition are Aluminum and Gold. Shapes of interest are nanospheres and nanotriangles. We study in this work the optical properties of metal nanoparticles diluted in water or embedded in amorphous silicon, ITO and ZnO as a function of size, aspect-ratio and metal type. Following the analysis based on the exact solution of the Mie theory and DDSCAT numerical simulations, it is presented a comparison with experimental measurements realized with arrays of metal nanospheres. Simulations are also compared with the LSPR produced by gold nanotriangles (Au NTs) that were chemically produced and characterized by microscope and optical measurements.
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Acknowledgements
This work was supported by FCT (CTS multi annual funding) through the PIDDAC Program funds (UID/EEA/00066/2013) and by the IPL IDI&CA 2016 MANASE project. The friendly collaboration of Dr. Manuel João Mendes from CENIMAT-I3 N is gratefully acknowledged. Financial support from Fundação para a Ciência e a Tecnologia, FCT, is also gratefully acknowledged (research grants UID/BIO/04565/2013, Ph.D. Grant from BIOTECnico Program SFRH/BPD/111906/2015 to RP Oliveira-Silva). Funding received by IBB-Institute for Bioengineering and Biosciences from Programa Operacional Regional de Lisboa 2020 (Project No. 007317) is also acknowledged.
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Fantoni, A., Fernandes, M., Vygranenko, Y. et al. Analysis of metallic nanoparticles embedded in thin film semiconductors for optoelectronic applications. Opt Quant Electron 50, 246 (2018). https://doi.org/10.1007/s11082-018-1523-z
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DOI: https://doi.org/10.1007/s11082-018-1523-z