Abstract
Exceptional optical and electrical characteristics of graphene based materials attract significant interest of the researchers to develop sensing center of surface plasmon resonance (SPR) based sensors by graphene application. In this research carrier density variant in the form of conductance gradient on graphene based SPR sensor response is modeled. The molecular properties such as electro-negativity, molecular mass, effective group number and effective outer shell factor are engaged. In addition each factor effect in the cumulative carrier variation is explored analytically. The refractive index shift equation based on these factors is defined and related coefficients are proposed. Finally a semi-empirical model for interpretation of changes in SPR curve is suggested and tested for some organic molecules.
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Bao, Q., Loh, K.P.: Graphene photonics, plasmonics, and broadband optoelectronic devices. ACS Nano 6(5), 3677–3694 (2012)
Chang, P.-Y., Huang, W.-M., Lin, H.-H.: Impurity-induced conductance anomaly in zigzag carbon nanotube. In: Kes P., Jochemsen R. (eds.) 25th International Conference on Low Temperature Physics, 1–4 (2009)
Cheon, S., et al.: How to optically count graphene layers. Opt. Lett. 37(18), 3765–3767 (2012)
Chiu, N.-F., et al.: Graphene oxide-based SPR biosensor chip for immunoassay applications. Nanoscale Res. Lett. 9(1), 1–7 (2014)
Choi, S.H., Kim, Y.L., Byun, K.M.: Graphene-on-silver substrates for sensitive surface plasmon resonance imaging biosensors. Opt. Express 19(2), 458–466 (2011)
Daghestani, H.N., Day, B.W.: Theory and applications of surface plasmon resonance, resonant mirror, resonant waveguide grating, and dual polarization interferometry biosensors. Sensors (Basel, Switzerland) 10(11), 9630–9646 (2010)
Eda, G., Chhowalla, M.: Chemically derived graphene oxide: towards large-area thin-film electronics and optoelectronics. Adv. Mater. 22(22), 2392–2415 (2010)
Guo, S., Dong, S.: Graphene and its derivative-based sensing materials for analytical devices. J. Mater. Chem. 21(46), 18503–18516 (2011)
Hamid, T., et al.: Graphene based surface plasmon resonance bio-sensor modeling. In: Annual International RIAPA Meeting on Low Dimensional Systems, 69–72 (2015)
Homola, J., Dostálek, J.: Surface Plasmon Resonance Based Sensors. Springer, Berlin (2006)
Hu, Y., et al.: Label-free electrochemical impedance sensing of DNA hybridization based on functionalized graphene sheets. Chem. Commun. 47(6), 1743–1745 (2011)
Jablan, M., Soljacic, M., Buljan, H.: Plasmons in graphene: fundamental properties and potential applications. Proc. IEEE 101(7), 1689–1704 (2013)
Johari, P., Shenoy, V.B.: Modulating optical properties of graphene oxide: role of prominent functional groups. ACS Nano 5(9), 7640–7647 (2011)
Kyle, J.R., Ozkan, C.S., Ozkan, M.: Industrial graphene metrology. Nanoscale 4(13), 3807–3819 (2012)
Lee, W.-C., et al.: Simple fabrication of glucose biosensor based on Graphene-Nafion composite by amperometric detections. In: 2012 IEEE Sensors Proceedings, pp. 1625–1628 (2012)
Liu, J., et al.: Toward a universal “adhesive nanosheet” for the assembly of multiple nanoparticles based on a protein-induced reduction/decoration of graphene oxide. J. Am. Chem. Soc. 132(21), 7279–7281 (2010)
Maharana, P.K., Jha, R., Palei, S.: Sensitivity enhancement by air mediated graphene multilayer based surface plasmon resonance biosensor for near infrared. Sens. Actuators B Chem. 190, 494–501 (2014a)
Maharana, P.K., Srivastava, T., Jha, R.: Low index dielectric mediated surface plasmon resonance sensor based on graphene for near infrared measurements. J. Phys. D Appl. Phys. 47(38), 1–11 (2014b)
Ovchinnikov, V., Shevchenko, A.: Self-organization-based fabrication of stable noble-metal nanostructures on large-area dielectric substrates. J. Chem. 2013, 1–10 (2013)
Palacios, T., Hsu, A., Wang, H.: Applications of graphene devices in RF communications. Commun. Mag. IEEE 48(6), 122–128 (2010)
Polichetti, T., Miglietta, M.L., Di Francia, G.: Overview on graphene properties, fabrication and applications. Chim Oggi-Chem Today 28(6), 6–9 (2010)
Sadrolhosseini, A.R.: Surface plasmon resonance characterization of biodiesel. Ph.D. thesis. Universiti Putra Malaysia (2011)
Salihoglu, O., Balci, S., Kocabas, C.: Plasmon-polaritons on graphene-metal surface and their use in biosensors. Appl. Phys. Lett. 100(21), 1–5 (2012)
Shang, J., et al.: The origin of fluorescence from graphene oxide. Sci. Rep. 2, (2012)
Shukla, S., Saxena, S.: Spectroscopic investigation of confinement effects on optical properties of graphene oxide. Appl. Phys. Lett. 98(7), 1–2 (2011)
Soldano, C., Mahmood, A., Dujardin, E.: Production, properties and potential of graphene. Carbon 48(8), 2127–2150 (2010)
Song, Y., Feng, M., Zhan, H.: Application of graphene edge effect in electrochemical biosensors. Prog Chem 25(5), 698–706 (2013)
Stebunov, Y.V., et al.: Highly sensitive and selective sensor chips with graphene-oxide linking layer. ACS Appl. Mater. Interfaces 7(39), 21727–21734 (2015)
Subramanian, P., et al.: Graphene-coated surface plasmon resonance interfaces for studying the interactions between bacteria and surfaces. ACS Appl. Mater. Interfaces 6(8), 5422–5431 (2014)
Tan, Y.B., Lee, J.-M.: Graphene for supercapacitor applications. J. Mater. Chem. A 1(47), 14814–14843 (2013)
Tang, L., et al.: Duplex DNA/graphene oxide biointerface: from fundamental understanding to specific enzymatic effects. Adv. Funct. Mater. 22(14), 3083–3088 (2012)
Valentini, F., Carbone, M., Palleschi, G.: Graphene oxide nanoribbons (GNO), reduced graphene nanoribbons (GNR), and multi-layers of oxidized graphene functionalized with ionic liquids (GO-IL) for assembly of miniaturized electrochemical devices. Anal. Bioanal. Chem. 405(11), 3449–3474 (2013)
Vosgueritchian, M., Lipomi, D.J., Bao, Z.: Highly conductive and transparent pedot:pss films with a fluorosurfactant for stretchable and flexible transparent electrodes. Adv. Funct. Mater. 22(2), 421–428 (2012)
Wan, Y., et al.: Graphene oxide sheet-mediated silver enhancement for application to electrochemical biosensors. Anal. Chem. 83(3), 648–653 (2011)
Wang, Z., et al.: Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase. J. Phys. Chem. C 113(32), 14071–14075 (2009)
Woan, G.: The Cambridge Handbook of Physics Formulas. Cambridge University Press, Cambridge (2000)
Wu, L., et al.: Highly sensitive graphene biosensors based on surface plasmon resonance. Opt. Express 18(14), 14395–14400 (2010)
Yin, Z., et al.: Graphene-based materials for solar cell applications. Adv. Energy Mater. 4(1), 1–19 (2014)
Zhao, J., et al.: Graphene quantum dots-based platform for the fabrication of electrochemical biosensors. Electrochem. Commun. 13(1), 31–33 (2011)
Zhou, M., Zhai, Y., Dong, S.: Electrochemical sensing and biosensing platform based on chemically reduced graphene oxide. Anal. Chem. 81(14), 5603–5613 (2009)
Zuppella, P., et al.: Graphene–noble metal bilayers for inverted surface plasmon resonance biosensors. J. Opt. 15(5), 055010 (2013)
Acknowledgments
The authors would like to acknowledge the financial support from research management center (RMC) of Universiti Teknologi Malaysia under visiting associate research professor (VRP) program, also it should be noted that two first authors (Meshginqalam and Toloue) contributed equally to this work.
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Appendix: Molecule shape effect
Appendix: Molecule shape effect
For the effective outer shell factor determination, the chemical Structure of Mannose, Lactose, PEI and PSS (Subramanian et al. 2014), should be considered. It is clear that only in the case of PSS molecule there are two dangling bonds, so the related value for parameter “V” is 2 for this material and zero for others (Table 3).
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Meshginqalam, B., Toloue, H., Ahmadi, M.T. et al. Graphene embedded surface plasmon resonance based sensor prediction model. Opt Quant Electron 48, 328 (2016). https://doi.org/10.1007/s11082-016-0597-8
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DOI: https://doi.org/10.1007/s11082-016-0597-8