Abstract
The structural and magnetic behaviors are studied in the composites (x) BiFe0.95Co0.05O3: (1-x) La0.7Ca0.3MnO3. An influence on the lattice parameters and magnetic states of BiFe0.95Co0.05O3 (BFCO) to the La0.7Ca0.3MnO3 (LCMO) are investigated. Although the variation of the relative X-ray intensity of LCMO to BFCO with composition (x) in XRD patterns and the randomly distributed small nanoparticle of LCMO (~200 nm) mixed in the large nanoparticle of BFCO (~900 nm) given by SEM images indicate an almost immiscibility of BFCO and LCMO in composites obtained by solid solution method, an obvious change of lattice parameters indicates their mutual influence on lattice structure. A detail magnetic investigation of the composites shows that the Griffiths phase is increased with increase of composition x due to the incorporation of ferromagnetism of BFCO to the paramagnetic phase of LCMO. An approximate magnetic phase diagram for the composites is established, which would be helpful for understanding the magnetic singularity of the composites with colossal magnetoresistance and multiferroics.
Similar content being viewed by others
References
Adams CP, Lynn JW, Mukovskii YM, Arsenov AA, Shulyatev DA (2000) Charge ordering and polaron formation in the magnetoresistive oxide La0.7Ca0.3MnO3. Phys Rev Lett 85(18):3954–3957. https://doi.org/10.1103/PhysRevLett.85.3954
Bray AJ (1987) Nature of the Griffiths phase. Phys Rev Lett 59(5):586–589. https://doi.org/10.1103/PhysRevLett.59.586
Bray AJ, Moore MA (1982) On the eigenvalue spectrum of the susceptibility matrix for random spin systems. J Phys C Solid State Phys 15(23):L765–L771. https://doi.org/10.1088/0022-3719/15/23/008
Calderón MJ, Liang S, Yu R, Salafranca J, Dong S, Yunoki S, Brey L, Moreo A, Dagotto E (2011) Magnetoelectric coupling at the interface of BiFeO3/La0.7Sr0.3MnO3. Phys Rev B 84(2):024422. https://doi.org/10.1103/PhysRevB.84.024422
Castro Neto AH (1998) Non-Fermi liquid behavior and Griffiths phase in f-electron compounds. Phys Rev Lett 81(16):3531–3534. https://doi.org/10.1103/PhysRevLett.81.3531
De Andrade MC, Chau R, Dickey RP, Dilley NR, Freeman EJ, Gajewski DA, Maple MB, Movshovich R, Castro Neto AH, Castilla G, Jones BA (1998) Evidence for a common physical description of non-Fermi-liquid behavior in chemically substituted f-electron systems. Phys Rev Lett 81(25):5620–5623. https://doi.org/10.1103/PhysRevLett.81.5620
De Teresa JM, Ibarra MR, Algarabel PA, Ritter C, Marquina C, Blasco J, García J, Del Moral A, Arnold Z (1997) Evidence for magnetic polarons in the magnetoresistive perovskites. Nature (London) 386(6622):256–259. https://doi.org/10.1038/386256a0
Deisenhofer J, Braak D, Krug von Nidda H-A, Hemberger J, Eremina RM, Ivanshin VA, Balbashov AM, Jug G, Loidl A, Kimura T, Tokura Y (2005) Observation of a Griffiths phase in paramagnetic La1-xSrxMnO3. Phys Rev Lett 95(25):257202. https://doi.org/10.1103/PhysRevLett.95.257202
Dey P, Nath TK, Nanda Goswami ML, Kundu TK (2007) Room temperature ferroelectric and ferromagnetic properties of multiferroics x La0.7Sr0.3MnO3-(1-x)ErMnO3 (weight percent x = 0.1, 0.2) composites. Appl Phys Lett 90(16):162510. https://doi.org/10.1063/1.2723198
Griffiths RB (1969) Nonanalytic behavior above the critical point in a random Ising ferromagnet. Phys Rev Lett 23(1):17–19. https://doi.org/10.1103/PhysRevLett.23.17
Haghiri-Gosnet A-M, Renard J-P (2003) CMR manganites: physics, thin films and devices. J Phys D Appl Phys 36(8):R127–R150. https://doi.org/10.1088/0022-3727/36/8/201
Jiang WJ, Zhou XZ, Williams G, Mukovskii Y, Glazyrin K (2007a) Is a Griffiths phase a prerequisite for colossal magnetoresistance? Phys Rev Lett 99(17):177203. https://doi.org/10.1103/PhysRevLett.99.177203
Jiang WJ, Zhou XZ, Williams G, Mukovskii Y, Glazyrin K (2007b) Extreme sensitivity of the Griffiths phase to magnetic field in single crystal La0.73Ba0.27MnO3. Phys Rev B 76(9):092404. https://doi.org/10.1103/PhysRevB.76.092404
Larson C, Von Dreele RB (2004) Los Alamos National Laboratory Report No. LAUR, p 84–748
Loudon JC, Midgley PA (2006) Micromagnetic imaging to determine the nature of the ferromagnetic phase transition in La0.7Ca0.3MnO3. Phys Rev Lett 96(2):027214. https://doi.org/10.1103/PhysRevLett.96.027214
Lu WJ, Luo X, Hao CY, Song WH, Sun YP (2008) Magnetocaloric effect and Griffiths-like phase in La0.67Sr0.33MnO3 nanoparticles. J Appl Phys 104:113908
Lynn JW, Argyriou DN, Ren Y, Chen Y, Mukovskii YM, Shulyatev DA (2007) Order and dynamics of intrinsic nanoscale inhomogeneities in manganites. Phys Rev B 76(1):014437. https://doi.org/10.1103/PhysRevB.76.014437
Mathe VL, Patankar KK, Patil RN, Lokhande CD (2004) Synthesis and dielectric properties of Bi1-xNdxFeO3 perovskites. J Magn Magn Mater 270(3):380–388. https://doi.org/10.1016/j.jmmm.2003.09.004
Park S, Hur N, Guha S, Cheong S-W (2004) Percolative conduction in the half-metallic-ferromagnetic and ferroelectric mixture of (La, Lu, Sr)MnO3. Phys Rev Lett 92(16):167206. https://doi.org/10.1103/PhysRevLett.92.167206
Rao SS, Prater JT, Wu F, Shelton CT, Maria J-P, Narayan J (2013) Interface magnetism in epitaxial BiFeO3-La0.7Sr0.3MnO3 heterostructures integrated on Si(100). Nano Lett 13(12):5814–5821. https://doi.org/10.1021/nl4023435
Ruette B, Zvyagin S, Pyatakov AP, Bush A, Li JF, Belotelov VI, Zvezdin AK, Viehland D (2004) Mangetic-field-induced phase transition in BiFeO3 observed by high-field electron spin resonance: cycloidal to homogeneous spin order. Phys Rev B 69(6):64114. https://doi.org/10.1103/PhysRevB.69.064114
Salamon MB, Lin P, Chun SH (2002) Colossal magnetoresistance is a Griffiths singularity. Phys Rev Lett 88(19):197203. https://doi.org/10.1103/PhysRevLett.88.197203
Schiffer P, Ramirez AP, Bao W, Cheong S-W (1995) Low temperature magnetoresistance and the magnetic phase diagram of La1-xCaxMnO3. Phys Rev Lett 75(18):3336–3339. https://doi.org/10.1103/PhysRevLett.75.3336
Sheu YM, Trugman SA, Yan L, Qi J, Jia QX, Taylor AJ, Prasankumar RP (2014) Polaronic transport induced by competing interfacial magnetic order in a La0.7Ca0.3MnO3/BiFeO3 heterostructure. Phys Rev X 4:021001
Sosnowska I, Peterlin-Neumaier T, Steichele E (1982) Spiral magnetic ordering in bismuth ferrite. J Phys C Solid State Phys 15(23):4835–4846. https://doi.org/10.1088/0022-3719/15/23/020
Souza JA, Neumeier JJ, Y-K Y (2008) Magnetic signatures of ferromagnetic polarons in La0.7Ca0.3MnO3: colossal magnetoresistance is not a Griffiths singularity. Phys Rev B 78(1):014436. https://doi.org/10.1103/PhysRevB.78.014436
Spaldin NA, Fiebig M (2005) The renaissance of mangetoelectric multiferroics. Science 309(5733):391–392. https://doi.org/10.1126/science.1113357
Teagure JR, Gerson R, James WJ (1970) Dielectric hysteresis in single crystal BiFeO3. Solid State Commun 8(13):1073–1074. https://doi.org/10.1016/0038-1098(70)90262-0
Toby BH (2001) EXPGUI, a graphical user interface for GSAS. J Appl Crystallogr 34(2):210–213. https://doi.org/10.1107/S0021889801002242
Venkatesan T, Rajeswari M, Dong ZW, Ogale SB, Ramesh R (1998) Manganite-based devices: opportunities, bottlenecks and challenges. Philos Trans R Soc London, Ser A 356:1661
Wang Y-F, Han Y-X, Zhu C-F (2009) Electronic transport and magnetic properties in ferroelectric-ferromagnetic composites La5/8Ca3/8MnO3:ErMnO3. Chin J Chem Phys 22(4):406–410. https://doi.org/10.1088/1674-0068/22/04/406-410
Wu SM, Cybart SA, Yu P, Rossell MD, Zhang JX, Rames, Dynes RC (2010) Reversible electric control of exchange bias in a multiferroic field-effect device. Nat Mater 9(9):756–761. https://doi.org/10.1038/nmat2803
Xu QY, Zai HF, Wu D, Qiu T, Xu MX (2009) The magnetic properties of Bi(Fe0.95Co0.05)O3 ceramics. Appl Phys Lett 95:112510
Yu P, Lee J-S, Okamoto S, Rossell MD, Huijben M, Yang C-H, He Q, Zhang JX, Yang SY, Lee MJ, Ramasse QM, Erni R, Chu Y-H, Arena DA, Kao C-C, Martin LW, Ramesh R (2010) Interface ferromagnetism and orbital reconstruction in BiFeO3-La0.7Sr0.3MnO3 heterostructures. Phys Rev Lett 105(2):027201. https://doi.org/10.1103/PhysRevLett.105.027201
Zhang H, Li Q, Liu H, Chen L, Chen Y, Li Y (2010) Observation of Griffiths phase in polycrystalline for La1-xCaxMnO3 for x ~ 0.20. IEEE Trans Magn 46(6):1483–1486. https://doi.org/10.1109/TMAG.2010.2044750
Acknowledgements
H.G. Zhang acknowledges the financial support from the National Natural Science Foundation of China (No. 11605092), the Jiangsu Youth Fund of Natural Science (No. BK20130858), and the Science Research Foundation of Nanjing University of Posts and Telecommunications (Nos. NY215091, NY213055, and NY213180). L. Xie acknowledges the support from the Beijing Municipal Education Commission (KM20150009012).
Funding
This study was funded by National Natural Science Foundation of China (grant number 11605092), Beijing Municipal Education Commission (grant number KM20150009012), Jiangsu Youth Fund of Natural Science (grant number BK20130858), and Science Research Foundation of Nanjing University of Posts and Telecommunications (grant numbers NY215091, NY213055, and NY213180).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that we have no conflict of interest.
Rights and permissions
About this article
Cite this article
Zhang, H., Fu, D., Wang, Y. et al. The structural and magnetic investigation of (x) BiFe0.95Co0.05O3: (1-x) La0.7Ca0.3MnO3 composites. J Nanopart Res 19, 382 (2017). https://doi.org/10.1007/s11051-017-4079-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-017-4079-0