Abstract
Mg-doped InAlAs and InGaAs films were grown at 560 °C lattice matched to InP semi-insulting substrate by metalorganic vapor phase epitaxy (MOVPE) under various Cp2Mg flow conditions. Hall effect, photoluminescence (PL), high-resolution X-ray diffraction (HR-XRD), and secondary ion mass (SIMS) were the tools used in this work. The crystalline quality and the n-p conversion of the InAlAs and InGaAs/Mg films are described and discussed in relation to the Cp2Mg flow. Distinguishing triple emission peaks in PL spectra is observed and seems to be strongly dependent on the Cp2Mg flow. SIMS is employed to analyze the elements in the epitaxial layers. The variation of indium and magnesium components indicates a decrease of magnesium incorporation during the growth of InAlAs layers leading to a contracted lattice. In addition, the magnesium incorporation in the InGaAs lattice during growth has been confirmed by SIMS.
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References
Abernathy CR, Wisk PW, Pearton SJ, Ren F (1993) Mg doping of InP and InGaAs grown by metalorganic molecular beam epitaxy using bis-cyclopentadienyl magnesium. Appl Phys Lett 62(3):258–260
Alian A, Merckling C, Brammertz G, Meuris M, Heyns M, Meyeram KD (2012) InGaAs MOS transistors fabricated through a digital-etch gate-recess process and the influence of forming gas anneal on their electrical behavior. ECS J Solid State Sci Technol 1(6):P310–P314
Blaauw C, Emmerstorfer B, Springthorpe AJ (1987) Cadmium doping of InP grown by MOCVD. J Cryst Growth 84(3):431–435
Bouzgarrou S, Ben Salem MM, Hassen F, Kalboussi A, Souifi A (2005) DLTS and PL study of defects in InAlAs/InP heterojunctions grown by metal organic chemical vapor deposition. Mater Sci Eng B 116(2):202–207
Del Alamo JA, Antoniadis D, Guo A, Kim DH, Kim TW, Lin J, Lu W Vardi A (2013) InGaAs MOSFETs for CMOS. Recent advances in process technology 2156-017X
Dong HW, Zhao YW, Zeng YP, Jiao JH, Li JM, Lin LY (2003) Influence of semi-insulating InP substrates on InAlAs epilayers grown by molecular beam epitaxy. J Crystal Growth 250(3–4):364–369
El Kazzi S, Smets Q, Ezzedini M, Rooyackers R, Verhulst A, Douhard B, Bender H, Collaert N, Merckling C, Heyns MM, Thean A (2015) Staggered band gap n+In0.5Ga0.5As/p+GaAs0.5Sb0.5 Esaki diode investigations for TFET device predictions. J Cryst Growth 424(15):62–67
Ezzedini M, Zeydi I, El Kazzi S, Jiang S, Guo W, Sfaxi L, M’ghaieth R, Maaref H, Merckling C (2015) Comprehensive study of Cp2Mg p-type doping of InP with MOVPE growth technique. J Alloys Compd 651(5):344–349
Hoshi T, Sugiyama H, Yokoyama H, Kurishima K, Ida M, Matsuzaki H, Tateno K (2013) Carbon doping in InGaAsSb films on (001) InP substrate using CBr4 grown by metalorganic chemical vapor deposition. J Cryst Growth 380(1):197–204
Ito H, Ishibashi T (1991) Carbon incorporation in (AlGa)as, (AlIn)as and (GaIn)as ternary alloys grown by molecular beam epitaxy. Jpn J Appl Phys 30(6A):L944–L947
Lambert M, Huet D (1983) Epitaxie par jets moléculaires de In0,53Ga0,47As et de InP sur substrats de InP. Revue Phys Appl 18(12):757–761
Li X, Zhang J, Zhang W, Lu H (2015) Dayong Zhou, zinc-induced lattice contraction in metalorganic vapor phase epitaxy grown AlGaInP. Thin Solid Films 592(1):24–28
Lin JC, Yu SY, Mohney SE (2013) Characterization of low-resistance ohmic contacts to n- and p-type InGaAs. J Appl Phys 114(4):044509–044504
Moon Y, Si S, Yoon E, Kim SJ (1998) Low temperature photoluminescence characteristics of Zn-doped InP grown by metalorganic chemical vapor deposition. J Appl Phys 83(4):2261–2266
Tateno K, Amano C (2000) Zn-doped AlInAs grown at high temperature by metalorganic chemical vapor deposition. J Cryst Growth 220(4):393–400
Waldon N, Merkling C, Teugels L, Ong P, Ansar S, Sebaai F, Pourghaderi A, Barla K, Collaert N, Thean AV-Y (2014) InGaAs gate-all-around nanowire devices on 300 mm Si substrates. IEEE Electron Device Letters 35(11):1097–1099
Waldron N, Merckling C, Guo W, Ong P, Teugels L, AnsarI S, Tsvetanova D, Sebaai F, van Dorp DH, Milenin A, Lin D, Nyns L, Mitard J, Pourghaderi A, Douhard B, Richard O, Bender H, Boccardi G, Caymax M, Heyns M, Vandervorst W, Barla K, Collaert N, Thean AV-Y (2014) An InGaAs/InP quantum well finfet using the replacement fin process integrated in an RMG flow on 300 mm Si substrates. IEEE VLSI Technology 10(1109):6894349–6894350
Waldron N, Wang G, Nguyen ND, Ozrali T, Merckling C, Brammertz G, Ong P, Winderichx G, Hellings G, Eneman G, Caymax M, Meuris M, Horiguchi N, Thean A (2012) Integration of InGaAs channel n-MOS devices on 200 mm Si wafers using the aspect-ratio-trapping technique. ECS Transaction 45(4):115–128
Wu GM, Chen SH (2008) Blue InGaN/GaN light-emitting diodes AlGaN electron-blocking barriers. J Korean Phys Soc 52(5):1570–1574
Yokoyama H, Hoshi T, Shigekawa N, Ida M (2012) Reduction of In in heavily Zn-doped InAlGaAs layers grown at low temperature by metalorganic chemical vapor deposition. Jpn J Appl Phys 51(2012):02561–02567
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This research was supported by the KACST-Intel Consortium Center of Excellence in Nano-manufacturing Application (CENA) under the signed joint research and academic advising agreement between KACST and Monastir University.
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Ezzedini, M., Sfaxi, L. & M’Ghaieth, R. Magnesium doping in InAlAs and InGaAs/Mg films lattice-matched to InP grown by MOVPE. J Nanopart Res 19, 19 (2017). https://doi.org/10.1007/s11051-016-3713-6
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DOI: https://doi.org/10.1007/s11051-016-3713-6