Skip to main content
Log in

Studying of the photoluminescence characteristics of AgInS2 quantum dots

  • Research Paper
  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

The optical properties of AgInS2 quantum dots (QDs), with the average size being 5 nm, are studied in detail. The photoluminescence (PL) of AgInS2 QDs in solution and aggregation state exhibits an unusual temperature-dependent peak shift behaviour. Therefore, the relaxation process of excited QDs is detected using transient absorption technique, which shows that two kinds of emission states (involving the exciton state and trapping state) participate in the PL process of QDs. The emission of trapping state is expected to play an important role in the temperature-dependent evolution of PL peak.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Crooker SA, Barrick T, Hollingsworth JA, Klimov VI (2003) Multiple temperature regimes of radiative decay in CdSe nanocrystal quantum dots: intrinsic limits to the dark-exciton lifetime. Appl Phys Lett 82:2793–2795

    Article  Google Scholar 

  • Gabka G, Bujak P, Giedyk K, Ostrowski A, Malinowska K, Herbich J, Golec B, Wielgus I, Pron A (2014) A simple route to alloyed quaternary nanocrystals Ag–In–Zn–S with shape and size control. Inorg Chem 53:5002–5012

    Article  Google Scholar 

  • Hamanaka Y, Ogawa T, Tsuzuki M (2011) Photoluminescence properties and its origin of AgInS2 quantum dots with chalcopyrite structure. J Phys Chem C 115:1786–1792

    Article  Google Scholar 

  • Hardman R (2006) A toxicologic review of quantum dots: toxicity depends on physicochemical and environmental factors. Environ Health Perspect 114(2):165–172

    Article  Google Scholar 

  • Huang TH, Wang YH, Kang ZH, Yao JB, Lu R, Zhang HZ (2014) Investigation on photophysical properties of D-π-A-π-D-Type fluorenone-based linear conjugated oligomers by using femtosecond transient absorption spectroscopy. Photochem Photobiol 90:29–34

    Article  Google Scholar 

  • Lanzani G, Cerullo G, Polli D, Gambetta A, Zavelani-Rossi M, Gadermaier C (2004) Photophysics of conjugated polymers: the contribution of ultrafast spectroscopy. Phys Status Solidi A 201:1116–1131

    Article  Google Scholar 

  • Liu LW, Hu R, Law WC, Roy I, Zhu J, Ye L, Hu SY, Zhang XH, Yong KT (2013) Optimizing the synthesis of red- and near-infrared CuInS2 and AgInS2 semiconductor nanocrystals for bioimaging. Analyst 138:6144–6153

    Article  Google Scholar 

  • Mao BD, Chuang CH, Wang JW, Burda C (2011) Synthesis and photophysical properties of ternary I-III–VI AgInS2 nanocrystals: intrinsic versus surface states. J Phys Chem C 115(18):8945–8954

    Article  Google Scholar 

  • Ogawa T, Kuzuya T, Hamanaka Y, Sumiyama K (2010) Synthesis of Ag–In binary sulfide nanoparticles—structural tuning and their photoluminescence properties. J Mater Chem 20:2226–2231

    Article  Google Scholar 

  • Peng XG, Manna L, Yang WD, Wickham J, Scher E, Kadavanich A, Alivisatos AP (2000) Shape control of CdSe nanocrystals. Nature 404:59–61

    Article  Google Scholar 

  • Polimeni A, Capizzi M, Geddo M, Fischer M, Reinhardt M, Forchel A (2000) Effect of temperature on the optical properties of (InGa)(AsN)/GaAs single quantum wells. Appl Phys Lett 77:2870–2872

    Article  Google Scholar 

  • Qu LH, Peng XG (2002) control of photoluminescence properties of CdSe nanocrystals in growth. J Am Chem Soc 124(9):2049–2055

    Article  Google Scholar 

  • Qu LL, Wang YH, Kang ZH, Ma YG, Zhang HZ (2014) Investigation on excited-state photophysical characteristics of low bandgap polymer APFO3. Chin J Chem Phys 27:109–114

    Article  Google Scholar 

  • Sharma P, Brown S, Walter G, Santra S, Moudgil B (2006) Nanoparticles for bioimaging. Adv Colloid Interface Sci 123–126:471–485

    Article  Google Scholar 

  • Sun Q, Wang YA, Li LS, Wang DY, Zhu T, Xu J, Yang CH, Li YF (2007) Bright, multicoloured light-emitting diodes based on quantum dots. Nat Photon 1:717–722

    Article  Google Scholar 

  • Tsuji I, Kato H, Kobayashi H, Kudo A (2004) Photocatalytic H2 evolution reaction from aqueous solutions over band structure-controlled (AgIn) x Zn2(1−x)S2 solid solution photocatalysts with visible-light response and their surface nanostructures. J Am Chem Soc 126(41):13406–13413

    Article  Google Scholar 

  • Varshni YP (1967) Temperature dependence of the energy gap in semiconductors. Physica 34:149–154

    Article  Google Scholar 

  • Wang YH, Zou L, Kang ZH, Qian C, Ma YG, Zhang HZ (2013) Ultra-fast excitation dynamics in low bandgap polymer solar cell. Appl Phys Lett 103:073902-1–073902-4

    Google Scholar 

  • Xiang WD, Xie CP, Wang J, Zhong JS, Liang XJ, Yang HL, Luo L, Chen ZP (2014) Studies on highly luminescent AgInS2 and Ag–Zn–In–S quantum dots. J Alloy Compd 588:114–121

    Article  Google Scholar 

  • Xie RG, Rutherford M, Peng XG (2009) Formation of high-quality I–III–VI semiconductor nanocrystals by tuning relative reactivity of cationic precursors. J Am Chem Soc 131(15):5691–5697

    Article  Google Scholar 

  • Yoshie T, Scherer A, Hendrickson J, Khitrova G, Gibbs HM, Rupper G, Ell C, Shchekin OB, Deppe DG (2004) Vacuum Rabi splitting with a single quantum dot in a photonic crystal nanocavity. Nature 432:200–203

    Article  Google Scholar 

  • Zhong HZ, Lo SS, Mirkovic T, Li YC, Ding YQ, Li YF, Scholes GD (2010) Noninjection gram-scale synthesis of monodisperse pyramidal CuInS2 nanocrystals and their size-dependent properties. ACS Nano 4(9):5253–5262

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 21103161, 11274142, 11304058 and 11474131), the China Postdoctoral Science Foundation (2011M500927 and 2013T60319) and National Found for Fostering Talents of basic Science (NO. J1103202).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yinghui Wang, Liwei Liu or Hanzhuang Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, F., Wang, Y., Gao, J. et al. Studying of the photoluminescence characteristics of AgInS2 quantum dots. J Nanopart Res 17, 159 (2015). https://doi.org/10.1007/s11051-015-2970-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11051-015-2970-0

Keywords

Navigation