Abstract
Sonicated EtOH-dispersed magnetic nanoparticles of γ-Fe2O3 represent a straightforward and green catalyst for the rapid three-component synthesis of α-aminophosphonate derivatives as biologically interest skeletons. The aminophosphonates were prepared over magnetic nanoparticles of γ-Fe2O3 without any salt or additives. Dispersed nano-γ-Fe2O3 has many advantages such as stability in air, reactions with high efficiency, frequent usage, simple separation with magnetic external field from mixture reactions, and chemical stability, also low toxicity.
Similar content being viewed by others
References
Azizi N, Saidi MR (2003) Synthesis of tertiary α-amino phosphonate by one-pot three-component coupling mediated by LPDE. Tetrahedron 59:5329–5332. doi:10.1016/s0040-4020(03)00759-2
Beers SA, Schwender CF, Loughney DA, Malloy E, Demarest K, Jordan J (1996) Phosphatase inhibitors–III. Benzylaminophosphonic acids as potent inhibitors of human prostatic acid phosphatase. Bioorg Med Chem 4:1693–1701. doi:10.1016/0968-0896(96)00186-1
Pratt RF (1989) Inhibition of a class C beta-lactamase by a specific phosphonate monoester. Science 246(4932):917–919
Rostamnia S (2011) Eco-friendly supported nanoparticles as a green approach. Res J Chem Environ 15:89–91
Rostamnia S, Lamei K (2013) A rapid, catalyst-free, three-component synthesis of rhodanines in water using ultrasound. Synthesis 2011:3080–3082. doi:10.1055/s-0030-1260158
Rostamnia S, Zabardasti A (2012) SBA-15/TFE (SBA-15/2,2,2-trifluoroethanol) as a suitable and effective metal-free catalyst for the preparation of the tri- and tetra-substituted imidazoles via one-pot multicomponent method. J Fluor Chem 144:69–72. doi:10.1016/j.jfluchem.2012.07.006
Rostamnia S, Lamei K, Mohammadquli M, Sheykhan M, Heydari A (2012a) Nanomagnetically modified sulfuric acid (γ-Fe2O3@SiO2–OSO3H): an efficient, fast and reusable green catalyst for the Ugi-like Groebke–Blackburn–Bienaymé three-component reaction under solvent-free conditions. Tetrahedron Lett 53:5257–5260. doi:10.1016/j.tetlet.2012.07.075
Rostamnia S, Karimi Z, Ghavidel M (2012b) Cetyltrimethylammonium bromide-surfactant aqueous micelles as a green and ultra-rapid reactor for synthesis of 5-oxo-2-thioxo-2,5-dihydro-3-thiophenecarboxylate derivatives. J Sulfur Chem 33:313–318. doi:10.1080/17415993.2012.662980
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rostamnia, S., Amini, M. Synthesis and application of the uniform particle size of nano-γ-Fe2O3: dispersed nanoparticles of γ-Fe2O3 for green synthesis of aminophosphonates. J Nanopart Res 16, 2405 (2014). https://doi.org/10.1007/s11051-014-2405-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-014-2405-3