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MgO-coated-Fe3O4 nanoparticles as a magnetically recoverable and reusable catalyst for the synthesis of 1-hydroxyphosphonates

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Abstract

Nanosize magnetic particles coated with magnesium oxide (core/shell nanoparticles) have been prepared and used for the synthesis of 1-hydroxyalkyl phosphonates. Catalytic activity studies show that the magnetic particles coated with magnesium oxide have highly catalytic activity toward the phosphorylation of aldehydes for the synthesis of 1-hydroxyalkyl phosphonates under solvent-free conditions. Reusability of the prepared magnetic nanoparticles was successfully examined five times with a very slight loss of catalytic activity.

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Acknowledgments

The authors gratefully acknowledge the support by the Institute for Advanced Studies in Basic Sciences (IASBS). Thanks are also given to Professor Behzad Haghighi for the atomic absorption analysis of the catalyst.

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Authors and Affiliations

  1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Gava Zang, Zanjan, 45137-66731, Iran

    Babak Kaboudin, Foad Kazemi & Fereshteh Habibi

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  1. Babak Kaboudin
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  2. Foad Kazemi
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  3. Fereshteh Habibi
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Correspondence to Babak Kaboudin.

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Kaboudin, B., Kazemi, F. & Habibi, F. MgO-coated-Fe3O4 nanoparticles as a magnetically recoverable and reusable catalyst for the synthesis of 1-hydroxyphosphonates. J IRAN CHEM SOC 12, 469–475 (2015). https://doi.org/10.1007/s13738-014-0504-9

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  • DOI: https://doi.org/10.1007/s13738-014-0504-9

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