Special features of structural and phase transformations occurring in annealing of an explosion-welded Al – Zr bimetal are considered. It is shown that heat treatment causes formation and growth of an intermetallic layer on the interface, which has a hardness of 9 GPa. The methods of microscopic x-ray spectrum analysis and of phase analysis with the use of synchrotron radiation are used to show that the intermetallic layer is represented by a ZrAl3 phase with a D023-type structure. The lattice constants of this phase vary gradually from the metal-intermetallic interfaces to the center of the layer. Quantum-chemical modeling by the method of density functional is used to show that the zirconium trialuminide is in the steadiest state at a certain distance from the interface due to the process of secondary recrystallization and the accompanying annihilation of crystal structure defects.
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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 7, pp. 49 – 58, July, 2023.
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Emurlaeva, Y.Y., Khomyakov, M.N., Aleksandrova, N.S. et al. Structure and Phase Composition of Heat Treated Al – Zr Bimetal. Met Sci Heat Treat 65, 441–449 (2023). https://doi.org/10.1007/s11041-023-00952-9
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DOI: https://doi.org/10.1007/s11041-023-00952-9