Skip to main content
Log in

Raising the Corrosion Resistance of Low-Carbon Steels by Electrolytic-Plasma Saturation with Nitrogen and Carbon

  • Published:
Metal Science and Heat Treatment Aims and scope

Structural features of the external oxide layer and internal nitrided, carbonitrided and carburized layers in steels 10, 20 and St3 produced by the method of electrolytic plasma treatment are studied. Specimens of the steels are tested for corrosion in a naturally aerated 1-N solution of sodium chloride. The condition of the metal/sodium chloride solution interface is studied by the method of electrochemical impedance spectroscopy. It is shown that the corrosion resistance of low-carbon steels can be raised by anode electrolytic-plasma saturation with nitrogen and carbon. Recommendations are given on the choice of carbonitriding modes for structural steels.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

Notes

  1. Here and below in the paper the content of elements is given in mass percent.

References

  1. M. Aliofkhazraei, Rouhaghdam A. Sabour, and P. Gupta, “Nano-fabrication by cathodic plasma electrolysis,” Critical Rev. Solid State Mater. Sci., 36, 174 – 190 (2011).

    Article  Google Scholar 

  2. M. Kh. Aliev, A. Sabour, and P. Taheri, “Study of corrosion protection of different stainless steels by nanocrystalline plasma electrolysis,” Protect. Met. Phys. Chem. Surf., 44(4), 402 – 407 (2008).

    Article  Google Scholar 

  3. M. K. Zarchi, M. H. Shariat, S. A. Dehghan, et al., “Characterization of nitrocarburized surface layer on AISI 1020 steel by electrolytic plasma processing in an urea electrolyte,” J. Mater. Res. Technol., 2(3), 213 – 220 (2013).

    Article  Google Scholar 

  4. H. Tavakoli, S. M. Mousavi Khoie, S. P. H. Marashi, et al., “Effect of electrolyte composition on characteristics of plasma electrolysis nitrocarburizing,” J. Mater. Eng. Perform. (2013), DOI: 10.1007/s11665-013-0505-3.

  5. H. Tavakoli, S. M. Mousavi Khoie, S. P. H. Marashi, et al., “Characterization of submicron-size layer protected by pulsed bipolar plasma electrolytic carbonitriding,” J. Alloys Compd., 583, 382 – 389 (2014).

    Article  Google Scholar 

  6. M. Aliofkhazraei, P. Taheri, Rouhaghdam A. Sabour, et al., “Systematic study of nanocrystalline plasma electrolytic nitrocarburising of 316L austenitic stainless steel for corrosion protection,” J. Mater. Sci. Technol., 23(5), 665 – 671 (2007).

    Google Scholar 

  7. J. D. Smith and S. E. Vanes, Manufacture of Corrosion Resistant Components, Patent 4.881.983 USA, C23C 8/34, C23C 11/08.

  8. Shingi Fushimi and Takeshi Miyata, Steel Article Having a Nitrided and Partly Oxidized Surface and Method for Producing Same, Patent 4.131.492 USA, C23C 11/16 (1978), publ. Dec. 26.

  9. Sh. Fuji, S. Fushimi, and M. Hashimoto, “Analyses of heat-resistant steel surface treated by oxinitriding,” J. Jpn. Soc. Heat Treat., 22(2), 105 – 110 (1982).

    Google Scholar 

  10. Z. Li, D. Yu, H. Pau, et al., “Study of mechanism of increasing of thickness and hardness of diffusion layer on steel using liquid nitriding in carbamide,” J. Zhejiang Univ., No. 2, 91 – 104 (1982).

  11. K. H. Lee, K. S. Nam, P.W. Shin et al, “Effect of post-oxidizing time on corrosion properties of plasma nitrocarburized AISI 1020 steel,” Mater. Lett., 57, 200 – 206 (2003).

    Google Scholar 

  12. T. Bell, Y. Sun, and A. Suhadi, “Environmental and technical aspects of plasma nitrocarburizing,” Vacuum, 59, 14 – 23 (2000).

    Article  Google Scholar 

  13. G. P. Chernova, N. L. Bogdashkina, V. V Parshutin, et al., “Electrochemical and corrosion behavior of steel 40Kh nitrided in “electrolytic plasma,” Zashchita Met., 20(3), 408 – 411 (1984).

  14. V. G. Revenko, V. V Parshutin, G. P. Chernova, et al., “Effect of nitriding in electrolytic heating on electrochemical and corrosion behavior of St45,” Elektron. Obrab. Mater., No. 5, 5 – 59 (1985).

  15. E. A. Pasinkovskii, I. M. Gol’dman, and R. P. Sorokina, “Nitriding of stainless steel in electrolytic plasma,” Electron. Obrab. Mater., No. 2, 86 – 87 (1976).

  16. V. G. Revenko, G. P. Chernova, V. V. Parshutin, et al., “Effect of nitriding process in electrolyte on protective properties of conversion coatings,” Zashchita Met., 24(2), 204 – 210 (1988).

    Google Scholar 

  17. V. V. Parshutin and E. A. Pasinkovskii, “Raising the corrosion resistance of steels by thermochemical treatment in electrolytes,” Elektron. Obrab. Mater., No. 6, 26 – 28 (2007).

  18. V. V. Parshutin and E. A. Pasinkovskii, “A method for treating steel articles for forming an anticorrosion surface layer, Patent Moldova, C23c 20/00, C23c 20/06, C23c 20/08, No. 2959,” Byull. Izobr. Polezn. Modeli, No. 1 (2006).

  19. V. Andrei, Gh. Vlaicu, M. Fulger, et al., “Chemical and structural modifications induced in structural materials by electrochemical processes,” Romanian Rep. Phys., 61(1), 95 – 104 (2009).

    Google Scholar 

  20. P. N. Belkin, B. L. Krit, I. G. D’yakov, et al., “Anodic saturation of steels with carbon in aqueous solutions of electrolytes containing carbamide,” Metalloved. Term. Obrab. Met., No. 1, 32 – 36 (2010).

  21. E. P. Grishina, A. V. Zhirov, P. N. Belkin, et al., “Effect of anode electrochemical-thermal oxidizing on corrosion resistance of steel 45,” Elektron. Obrab. Mater., No. 5, 57 – 62 (2008).

  22. P. N. Belkin and E. A. Pasinkovskii, “Heat and thermochemical treatment of steels under heating in electrolyte solutions,” Metalloved. Term. Obrab. Met., No. 5, 12 – 17 (1989).

  23. S. A. Kusmanov, S. Yu. Shadrin, and P. N. Belkin, “Carbon transfer from aqueous electrolytes to steel by anode plasma electrolytic carburizing,” Surf. Coat. Technol., 258, 727 – 733 (2014).

    Article  Google Scholar 

  24. S. A. Kusmanov, Yu. V. Kusmanova, A. R. Naumov, et al., “Features of anode plasma electrolytic nitrocarburizing of low carbon steel,” Surf. Coat. Technol., 272, 149 – 157 (2015).

    Article  Google Scholar 

  25. S. A. Kusmanov, Yu. V. Kusmanova, A. R. Naumov, et al., “Formation of diffusion layers by anode plasma electrolytic nitrocarburizing of low-carbon steel,” J. Mater. Eng. Perform., 24(8), 3187 – 3193 (2015).

    Article  Google Scholar 

  26. P. N. Belkin, A. A. Burbelko, E. A. Pasinkovskii, et al., “Kinetics of nitriding of commercial iron and steel 40Kh under electrolytic heating,” Elektron. Obrab. Mater., No. 2, 68 – 70 (1984).

Download references

The study has been performed with financial support of the Russian Scientific Foundation (Project No. 15-13-10018) to the Kostroma State University (nitriding, carburizing and nitrocarburizing of specimens, structural and phase analysis of the modified layers, participation in the discussion of the results, and preparation of the paper) and of the Ministry of Education and Science of the Russian Federation (Project No. 855).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. A. Kusmanov.

Additional information

Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 2, pp. 52 – 59, February, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kusmanov, S.A., Grishina, E.P., Belkin, P.N. et al. Raising the Corrosion Resistance of Low-Carbon Steels by Electrolytic-Plasma Saturation with Nitrogen and Carbon. Met Sci Heat Treat 59, 117–123 (2017). https://doi.org/10.1007/s11041-017-0114-0

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11041-017-0114-0

Key words

Navigation