Abstract
Conditions for the appearance of thermodynamically unstable states and changes in the stored energy, in the effective characteristic temperature, and in the moduli of uniform compression upon energy excitation of condensed phase are considered. Topics of the energy threshold of metastability and local energy excitation upon formation of a chemical bond, diffusion activation energy, pressure of the vapor of energy-excited substance, and energy excitation and formation of metastable phases are discussed.
Similar content being viewed by others
References
M. A. El’yashevich, A Physical Encyclopedia, Vol. 1 [in Russian], Moscow (1988).
I. P. Selinov, Isotope, Vols. I and II [in Russian], Moscow (1970).
N. N. Sirota, Cryst. Res. Technol., 17(6), 661 (1982).
N. N. Sirota, Cryst. Res. Technol., 22(11), 1343 (1987).
P. Gambosh, A Statistical Theory of Atoms and Its Applications [Russian translation], Moscow (1951).
I. K. Dmitrieva and G. I. Plindov, Properties of Atoms and Ions in the Light of Statistical Theory [in Russian], Minsk (1991).
S. Lundquist and N. March (eds.), The Theory of Inhomogeneous Electron Gas [Russian translation], Moscow (1987).
P. Gambas and T. Sondy, Solution of the Simplified Self-statistic Field for All Atoms of the Periodic System Elements from Z = 2 to Z = 92, Budapest (1970).
J. Gibbs, Works on Thermodynamics [Russian translation], Moscow, Leningrad (1950).
V. K. Semenchenko, Selected Chapters from Theoretical Physics [in Russian], Moscow (1966).
J. Waller, Phys., 51, 213 (1923).
R. Barrer, Diffusion in Solids, Cambridge (1941).
S. Glasstone and H. Eyring, The Theory of Absolute Reaction Rates. Kinetics of Chemical Reactions, Viscosity, Diffusion, and Electrochemical Phenomena [in Russian translation], Moscow (1948).
N. N. Sirota, “Thermodynamics of excited states,” in: N. N. Sirota (ed.), Structure and Properties of Ferrites [in Russian], Minsk (1974).
V. P. Skripov, Metastable Liquid [in Russian], Moscow (1972).
N. N. Sirota, Dokl. Akad. Nauk SSSR, 59(7), 1309 (1948).
N. N. Sirota, Zh. Teor. Fiz., 18(9), 1136–1148 (1948).
Author information
Authors and Affiliations
Additional information
__________
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 12, pp. 4–9, December, 2005.
Rights and permissions
About this article
Cite this article
Sirota, N.N. About the thermodynamics of excited states. Met Sci Heat Treat 47, 531–537 (2005). https://doi.org/10.1007/s11041-006-0027-9
Issue Date:
DOI: https://doi.org/10.1007/s11041-006-0027-9