Aluminum/glass-fiber-reinforced polypropylene (Al/GFPP) laminates were manufactured by using various surface pretreatment techniques. Adhesion at the composite/metal interface was achieved by a surface pretreatment of Al sheets with amino-based silane coupling agents, incorporation of a polyolefin-based adhesive film and modification with a PP-based film containing 20 wt.% of maleic-anhydride-modified polypropylene (PP-g-MA). In order to increase the effect of bonding between components of the laminates, the combination of silane treatment and the addition of the PP-based film was also investigated. The mechanical properties (shear, peel, and bending strengths) of adhesively bonded Al/GFPP laminates were examined to evaluate the effects of the surface treatments mentioned. It was revealed that the adhesion in the laminated Al/GFPP systems could be improved by the treatment of aluminum surface with an amino-based silane coupling agent. Judging from the results of peel and bending strength, with incorporation of polyolefin-based films, adhesion in the Al/GFPP laminates increased significantly. The modification of Al/GFPP interfaces with a PP-g-MA/PP layer led to the highest improvement in their adhesion properties. The combination of surface modification with silane and addition of PP-based films did not yield the high bending strength desired. This may be due to the insufficient bonding between silane groups and PP-based films.
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References
G. Reyes and H. Kang, “Mechanical behavior of lightweight thermoplastic fiber-metal laminates,” J. Mater. Proc. Technol., 186, 284–290 (2007).
B. M. Weager and C. D. Rudd, “Evaluation of the interface durability of hybrid composite/metal laminates for lightweight automotive body structures,” University of Nottingham, UK School of Mechanical, Materials, Manufacturing Engineering & Management: 1–8, 1999.
G. Reyes and W. J. Cantwell, “The mechanical properties of fibre-metal laminates based on glass-fibre-reinforced polypropylene,” Compos. Sci. Technol., 60, 1085–1094 (2000).
B. D. Roover, M. Sclavons, V. Carlier, J. Devaux, R. Legras, and A. Momtaz, “Molecular characterization of maleic anhydride-functionalized polypropylene,” Polymer Sci. Pt A, 33, 829–842 (1995).
X. Zhou, G. Dai, W. Guo, and Q. Lin, “Influence of functionalized polyolefin on interfacial adhesion of glass-fiberreinforced polypropylene,” Application of Polymer Sci., 76, 1359–1365 (2000).
A. Baker, L. R. F. Rose, and R. Jones, Advances in the Bonded Composite Repair of Metallic Aircraft Structure, Elsevier, 2002.
H. Hamada, K. Fujihara, and A. Harada, “The influence of sizing conditions on bending properties of continuous glass fiber reinforced polypropylene composites,” Composites: A, 31, 979–990 (2000).
Z. Demjen, “Possible coupling reactions of functional silanes and polypropylene,” Polymer, 40, 1763–1773 (1999).
M.-A. Chen, H.-Z. Li, and X.-M. Zhang, “Improvement of shear strength of aluminum/polypropylene lap joints by grafting maleic anhydride onto polypropylene,” Int. J. of Adhesion and Adhesives, 27, 175–187 (2007).
P. Compston, W. J. Cantwell, C. Jones, and N. Jones, “Impact perforation resistance and fracture mechanisms of a thermoplastic based fiber-metal laminate,” J. of Materials Sci. Letters, 20, 597–599 (2001).
Dow Corning. www.dowcorning.com. Z-6032 Silane Product Information. 2009.
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Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 49, No. 3, pp. 465–476 , May-June, 2013.
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Baştürk, S.B., Guruşçu, A. & Tanoğlu, M. Interfacial properties of aluminum/glass-fiberreinforced polypropylene sandwich composites. Mech Compos Mater 49, 317–324 (2013). https://doi.org/10.1007/s11029-013-9349-z
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DOI: https://doi.org/10.1007/s11029-013-9349-z