Nano-zinc sulfide (ZnS)- and nano-titanium dioxide (TiO2)-reinforced polyetheretherketone (PEEK) composites for use under extreme mechanical and tribological loads were developed and investigated systematically. The nanocomposites were manufactured with particle concentrations of 1 to 15 vol.% by using an optimized twin-screw extrud er technology. A simultaneous increase in the strength and elastic modulus of PEEK and an improvement in the tribological properties of PEEK/ZnS compounds were observed. Also, the specific wear rate decreased with increasing ZnS content, reaching its minimum at 3 vol.%. This minimum corresponded to a 60% reduction in the wear rate com pared with that of the neat PEEK. A wear map was re corded for the 3 vol.% composite, which depicted the in fluence of the sliding speed and the normal force on the wear rate over a wide range of parameters.
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References
S. Komarneni, “Nanocomposites,” J. Mater. Chem., 2, No. 12, 1219-1230 (1992).
R. Roy, “Purposive design of nanocomposites: entire class of new materials,” Mater. Sci. Res., 21, 25-32 (1986).
R. Dagani, “Nanostructured materials promise to advance range of technologies,” Chem. Eng. News, 23, 18-24 (1992).
M. Z. Rong, M. Q. Zhang, Y. X. Zheng, R. Walter, and K. Friedrich, “Structure-property relation ships of irradiation grafted nano-inorganic particle filled poly propylene composites,” Polymer, 42, 167-183 (2001).
M. Z. Rong, M. Q. Zhang, H. Liu, and H. M. Zeng, “Synthesis of silver nanoparticles and their self-organization behavior in epoxy resin,” Polymer, 40, 6169-6178 (1999).
C. Van Bellingen, N. Probst, and E. Grivei, “Specific conductive carbon blacks in plastics applications,” Polym. Polym. Compos., 10, No. 1, 63-71 (2002).
N. Knör, F. Haupert, and A. K. Schlarb, “Zum besseren geändert — Prozessoptimierte Herstellung von thermoplastischen Nanoverbundwerkstoffen,” Plastverarbeiter, 6, 66-67 (2007).
Q. L. Ji, M. Q. Zhang, M. Z. Rong, B. Rong, and K. Friedrich, “Tribological properties of surface-modified nano-alumina/epoxy composites,” J. Mater. Sci., 256, 1072-1081 (2004).
G. Shi, M. Q. Zhang, M. Z. Rong, B. Wetzel, and K. Friedrich, “Friction and wear of low nanometer Si3N4-filled epoxy composites,” Wear, 254, 784-796 (2003).
X. S. Xing and R. K. Y. Li, “Wear behavior of epoxy matrix composites filled with uniform sized sub-micron spherical silica particles,” Wear, 256, 21-26 (2004).
G. Shi, M. Q. Zhang, M. Z. Rong, B. Wetzel, and K. Friedrich, “Effect of particle surface treatment on the tribological performance of epoxy-based nanocomposites,” Wear, 253, 1086-1093 (2002).
B. Wetzel, F. Haupert, and M. Q. Zhang, “Epoxy nanocomposites with high mechanical and tribological performance,” Compos. Sci. Technol., 63, 2055-2067 (2003).
M. Z. Rong, M. Q. Zhang, Y. X. Zheng, R. Walter, and K. Friedrich, “Structure–property relationships of irradiation-grafted nano-inorganic particle-filled poly propylene composites,” Polymer, 42, 167-183 (2001).
O. Jacobs, G. Rüdiger, and B. Schädel, “Verschleiβverhalten von Nano-SiO2-gefülltem Epoxidharz,” Tribol. Schmierungstechn., 54, 19-24 (2007).
U. S. Tewari, J. Bijwe, J. N. Mathur, and I. Sharma, “Studies on the abrasive wear of carbon fibre (short) reinforced polyamide composites,” Tribol. Int., 25, 53-60 (1992).
J. Bijwe, C. M. Logani, and U. S. Tewari, “Influence of fillers and fibre reinforcement on abrasive wear resistance of some polymeric composites,” Wear, 138, 77-92 (1990).
A. A. Cenna, P. Dastoor, A. Beehag, and N. W. Page, “Effects of graphite particle addition upon the abrasive wear of polymer surfaces,” J. Ma ter. Sci., 36, 891-900 (2001).
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Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 45, No. 2, pp. 289-298, March-April, 2009.
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Knör, N., Gebhard, A., Haupert, F. et al. Polyetheretherketone (PEEK) nanocomposites for extreme mechanical and tribological loads. Mech Compos Mater 45, 199–206 (2009). https://doi.org/10.1007/s11029-009-9071-z
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DOI: https://doi.org/10.1007/s11029-009-9071-z