This paper presents the technology of producing, in vacuum arc furnaces, master alloys based on nickel and rare refractory metals (rhenium, ruthenium, and hafnium) of ReNi-1, RuNi-2, and HfNi10 grades. The technology involves the use of metal powders as initial components, which are pre-compressed into tablets and degassed in a vacuum electric resistance furnace. Though this process, an ultra-low content of gas impurities in the master alloys is provided, which increased their manufacturability when introduced into the melt and contributed to the quality improvement of the smelted cast heat-resistant nickel alloys. Alloys ZhS32, VZhM4, and VKNA-1VR, melted using the developed master alloys, have high chemical composition stability, low levels of harmful impurities and gases, and consistently high levels of mechanical properties, which comply with the requirements of technical specifications and alloy certificates.
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S. A. Krylov, E. V. Egorov, A. A. Makarov, and M. A. Druzhnov, “Mastering of alloys based on chromium in smelting of heat-resistant nickel alloys and steels,” Tr. VIAM: Elektron. Nauch.-Tekhnich. Zh., No. 1, 02 (2021); URL: http://www.viam-works.ru (accessed 04/01/2022). https://doi.org/10.18577/2307-6046-2021-0-1-13-22.
P. N. Nechaev, V. N. Nechaev, “Application of metal-thermal technology to obtain titanium-containing master alloys and compounds,” Titan, No. 2 (52), 28–32 (2016).
S. A. Savchenkov, V. L. Ugolkov, “Synthesis of magnesium master alloys during metallothermic reduction of compounds of rare earth metals,” Vest. Irkutskogo Gos.Tekhn. Univ., 23, No. 3 (146), 628–639 (2019).
A. I. Kovtunov, Yu. P. Chernyshova, D. A. Semistenov, and Yu. Yu. Khokhlov, “Study of the processes of production of aluminum-iron master alloys by arc remelting,” Lit. Rossii, No. 6, 39–40 (2011).
L. Wei, H. Zhou, H. Li, and Y. Zhou, “Arc deflection model and arc direction control for DC arc furnace,” J. Univ. Sci. Technol. Beijing Min. Metallurgy, Mater., 11, No. 4, 378–382 (2004).
P. G. Min, V. E. Vadeev, “Technology for obtaining Ni-RZM master alloys in a vacuum induction furnace for microalloying heat-resistant nickel alloys,” Technol. Met., No. 9, 19–25 (2016).
V. M. Trubachev, A. N. Rylov, V. M. Chumarev, and A. V. Larionov, “Testing extra-furnace and vacuum-induction methods for smelting Al-Zr-Mo-Sn master alloy,” Titan, No. 2 (48), 4–10 (2015).
E. N. Kablov, V. V. Sidorov, V. A. Nikolaev, V. E. Rigin, V. A. Makeev, and P. P. Tararaev, “Vacuum induction melting and pouring unit VIAM-2002 for production of high-quality special alloys,” Elektrometallurgiya, No. 1, 2–5 (2007).
E. N. Kablov, P. G. Min, V. E. Vadeev, and V. V. Kramer, Patent 2734222 RF, IPC S22S35/00. A Method of Making Master Alloys in a Vacuum Arc Furnace with a Non-Consumable Electrode, No. 2020108525; Submitted 02/27/2020; Publ. 10/13/2020. Bull. No. 23. 11.
F. N. Karachevtsev, A. V. Alekseev, A. F. Letov, and R. M. Dvoretskov, “Plasma methods for the analysis of the elemental chemical composition of alloys,” Aviats. Mater. Tekhnol., No. S, 483–497 (2017); URL: https://doi.org/10.18577/2071-9140-2017-0-S-483-497.
P. V. Yakimovich, A. V. Alekseev, “Improving the analytical characteristics of the determination of impurities in heat-resistant nickel alloys by ICP-MS,” Tr. VIAM: Elektron. Nauch.-Tekhnich. Zh., No. 5, 02 (2019); URL: http://www.viam-works.ru (accessed 04/01/2022). https://doi.org/10.18577/2307-6046-2019-0-5-3-11.
N. P. Lyakishev, O. A. Bannykh, L. L. Rokhlin et al., Diagrams of the State of Binary Metal Systems [in Russian], a reference book in 3 volumes, 2, Mashinostroenie, Moscow, 885–889 (1997).
E. N. Kablov, N. V. Petrushin, and I. L. Svetlov, “Modern cast nickel heat-resistant alloys,” in: Proceedings of the International Scientific and Technological Conference «Nauchnyye idei S. T. Kishkina i Sovremennoye Materialovedeniye (2006), pp. 39–55.
E. N. Kablov, V. V. Sidorov, D. E. Kablov, and P. G. Min, “Metallurgical bases for ensuring high quality of single-crystal heat-resistant nickel alloys,” Aviats. Mater. Tekhnol., No. S, 55–71 (2017); https://doi.org/10.18577/2071-9140-2017-0-S-55-71.
P. G. Min, V. E. Vadeev, and V. V. Kramer, “Development of a new heat-resistant nickel alloy VZhM200 and its production technology for casting by the method of directed crystallization of working blades of promising engines,” Aviats. Mater. Tekhnol.: Elektron. Nauch.-Tekhnich. Zhurn., No. 3(64), 2 (2020); URL: http://www.journal.viam.ru (accessed 03/18/2022). 10.18577/ 2713-0193-2021-0-3-11-18.
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Translated from Metallurg, Vol. 66, No. 11, pp. 88–94, November, 2022. Russian https://doi.org/10.52351/00260827_2022_11_88.
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Min, P.G., Vadeev, V.E. & Pitelin, N.S. Technology for the Production of High-Melting-Point Metal Master Alloys and their Testing in the Melting of Foundry Heat-Resistant Nickel Alloys. Metallurgist 66, 1442–1451 (2023). https://doi.org/10.1007/s11015-023-01459-7
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DOI: https://doi.org/10.1007/s11015-023-01459-7