Skip to main content
Log in

Evaluation of the Anticorrosion Efficiency of Apricot Pomace Extract in Neutral Aqueous Media

  • Published:
Materials Science Aims and scope

We study apricot pomace extract as a novel ecologically friendly inhibitor of the corrosion of steel in neutral aqueous solutions. It is shown that the efficiency of corrosion protection of steel with the help of apricot pomace extract in a 0.5 M NaCl solution increases with its concentration and the duration of holding. The data of gravimetric and electrochemical measurements demonstrate that a film is gradually formed on the steel surface with time (~ 48 h) and its thickness exceeds 800 nm. The morphology of the protective film is studied by the methods of scanning-electron microscopy and atomic-force microscopy. The chemical composition of the protective film is investigated by the method of FT-IR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

References

  1. S. Devikala, P. Kamaraj, M. Arthanareeswari, and M. B. Patel, “Green corrosion inhibition of mild steel by aqueous Allium sativum extract in 3.5% NaCl,” Mater. Today-Proc., 14, Part 2, 580–589 (2019).

  2. Y. Qianga, S. Zhanga, B. Tana, and S. Chen, “Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution,” Corros. Sci., 133, No 1, 6–16 (2018); https://doi.org/10.1016/j.corsci.2018.01.008.

    Article  CAS  Google Scholar 

  3. X. H. Li, S. D. Deng, X. G. Xie, and H. Fu, “Inhibition effect of bamboo leaves’ extract on steel and zinc in citric acid solution,” Corros. Sci., 87, 15–26 (2014).

    Article  CAS  Google Scholar 

  4. A. Singh, V. K. Singh, and M. A. Quraishi, “Aqueous extract of kalmegh (Andrographis paniculata) leaves as green inhibitor for mild steel in hydrochloric acid solution,” Int. J. Corros., 2010, ID 275983, 1–10 (2010); https://doi.org/10.1155/2010/275983.

  5. V. Vorobyova, O. Chygyrynetś, M. Skiba, and I. Kurmakova, “Self-assembled monoterpenoid phenol as vapor phase atmospheric corrosion inhibitor of carbon steel,” Int. J. Corros. Scale Inhibit., 6, No. 4, 485–503 (2017).

    CAS  Google Scholar 

  6. V. Vorobyova, O. Chygyrynets, and M. Skiba, “4-hydroxy-3-methoxybenzaldehyde as a volatile inhibitor on the atmospheric corrosion of carbon steel,” J. Chem. Technol. Metall., 53, No. 2, 336–345 (2018).

    CAS  Google Scholar 

  7. V. Vorobyova, O. Chygyrynets', M. Skiba, T. Zhuk, І. Kurmakova, and О. Bondar, “A comprehensive study of grape pomace extract and its active components as effective vapour phase corrosion inhibitor of mild steel,” Int. J. Corros. Scale Inhibit., 7, No. 2, 185–202 (2018).

    CAS  Google Scholar 

  8. V. I. Vorob’iova, O. E. Chyhyrynets’, and O. I. Vasyl’kevych, “Mechanism of formation of the protective films on steel by volatile compounds of rapeseed cake,” Fiz.-Khim. Mekh. Mater., 50, No. 5, 91–101 (2014); English translation: Mater. Sci., 50, No. 5, 726–735 (2015); https://doi.org/10.1007/s11003-015-9778-z.

  9. V. I. Vorob’iova, O. E. Chyhyrynets’, and O. I. Vasyl’kevych, “Mechanism of formation of the protective films on steel by volatile compounds of rapeseed cake,” Fiz.-Khim. Mekh. Mater., 50, No. 5, 91–101 (2014); English translation: Mater. Sci., 50, No. 5, 726–735 (2015); https://doi.org/10.1007/s11003-015-9778-z.

  10. O. E. Chyhyrynets, Y. F. Fateev, V. I. Vorobiova, and M. I. Skiba, “Study of the mechanism of action of the isopropanol extract of rapeseed oil cake on the atmospheric corrosion of copper,” Fiz.-Khim. Mekh. Mater., 51, No. 5, 48–55 (2015); English translation: Mater. Sci., 51, No. 5, 644–651 (2016); https://doi.org/10.1007/s11003-016-9886-4.

  11. Order of the Council of Ministers of Ukraine No. 820-r of 08.11.2017 “On the National Strategy of Control over the Wastes in Ukraine up to 2030 [in Ukrainian], Kyiv (2017).

  12. A. Y. El-Etre, M. Abdallah, and Z. E. El-Tantawy, “Corrosion inhibition of some metals using Lawsonia extract,” Corros. Sci., 47, 385–395 (2005).

    Article  CAS  Google Scholar 

  13. D. E. Abd-El-Khalek, B. A. Abd-El-Nabeyb, and A. M. Abdel-Gaber, “Evaluation of nicotiana leaves extract as corrosion inhibitor for steel in acidic and neutral chloride solutions,” Port. Electrochim. Acta., 30, 247–259 (2012).

    Article  CAS  Google Scholar 

  14. M. B. Radovanović, M. B. Petrović, A. T. Simonović, S. M. Milić, and M. M. Antonijević, “Cysteine as a green corrosion inhibitor for Cu37Zn brass in neutral and weakly alkaline sulphate solutions,” Environ. Sci Pollut Res., 20, 4370–4381 (2013); https://doi.org/10.1007/s11356-012-1088-5.

  15. M. I. Khaled, “Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions,” Electrochim. Acta, 52, No. 28, 7811–7819 (2007); https://doi.org/10.1016/j.electacta.2007.02.053.

    Article  CAS  Google Scholar 

  16. V. Vorobyova, A. Shakun, O. Chygyrynets,’ and M. Skiba, “Determination of the chemical composition of the extract of apricot pomace (Prunus armeniaca L.),” Chem. Chem. Technol., 13, No. 3, 391–398 (2019).

  17. V. Vorobyova and M. Skіba, “Apricot cake extract as corrosion inhibitor of steel: chemical composition and anti-corrosion properties,” Сhem. J. Mold., 14, No. 1, 77–87 (2019); https://doi.org/10.19261/cjm.2018.525.

    Article  CAS  Google Scholar 

  18. V. I. Vorobyova, M. I. Skiba, A. S. Shakun, and S. V. Nahirniak, “Relationship between the inhibition and antioxidant properties of the plant and biomass wastes extracts—A Review,” Int. J. Corros. Scale Inhibit., 8, No. 2, 150–178 (2019); https://doi.org/10.17675/2305-6894-2019-8-2-1.

    Article  CAS  Google Scholar 

  19. G. Vasyliev and V. Vorobiova, “Rape grist extract (Brassica napus) as a green corrosion inhibitor for water systems,” Mater. Today-Proc., 6, No. 2, 178–186 (2019); https://doi.org/10.1016/j.matpr.2018.10.092.

    Article  CAS  Google Scholar 

  20. Y. Fang, B. Suganthan, and R. P. Ramasamy, “Electrochemical characterization of aromatic corrosion inhibitors from plant extracts,” J. Electroanal. Chem., https://doi.org/10.1016/j.jelechem.2019.03.052.

  21. I. Horcas, R. Fernandez, J. M. Gomez-Rodriguez, J. Colchero, J. Gomez-Herrero, and A. M. Baro, “WSXM: A software for scanning probe microscopy and a tool for nanotechnology,” Rev. Sci. Instrum., 78, 0137052007 (2007); https://doi.org/10.1063/1.2432410.

  22. V. Vorobyova, O. Chygyrynets’, and M. Skiba, “Experimental and theoretical investigations of anti-corrosive properties of thymol,” Chem. Chem. Technol., 13, No. 2, 261–268 (2019); https://doi.org/10.23939/chcht13.02.261.

  23. V. Vorobyova, O. Chygyrynets’, M. Skiba, I. Trus, and S. Frolenkova, “A study pomaces of grapes extract as eco-friendly vapor phase corrosion inhibitor,” Chem. Chem. Technol., 12, No. 3, 410–418 (2018); https://doi.org/10.23939/chcht12.03.410.

  24. S. V. Gushchina, V. M. Kosman, and I. G. Zenkevich, “Kinetic regularities of oxidation of quercetin by atmospheric oxygen in aqueous solutions,” in: Proc. of the Internat. Conf. “Chemistry of Compounds with Multiple Carbon-Carbon Bonds” [in Russian], St. Petersburg (2008), pp. 149–150.

  25. Y. Bin, A. Kensuke, and K. Fumiyo, “Electrochemical behaviors of quercetin and kaempferol in neutral buffer solution,” Analyt. Sci., 17, 987–989 (2001).

    Article  Google Scholar 

  26. G. K. Ziyatdinova and H. C. Budnikov, “Evaluation of the antioxidant properties of spices by cyclic voltammetry,” Zh. Analyt. Khim., 69, No. 10, 1086–1093 (2014).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to О. Е. Chygyrynets.

Additional information

Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 57, No. 1, pp. 95–102, January–February, 2021.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vorobyova, V.І., Chygyrynets, О.Е. & Fateev, Y.F. Evaluation of the Anticorrosion Efficiency of Apricot Pomace Extract in Neutral Aqueous Media. Mater Sci 57, 101–109 (2021). https://doi.org/10.1007/s11003-021-00520-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11003-021-00520-7

Keywords

Navigation