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Influence of a Constant Magnetic Field on the Structure and Thermomechanical and Electrophysical Properties of Systems Based on Epoxy Polymers, Metal Oxides, and Polyaniline

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We study the structure and thermomechanical and electrophysical properties of systems based on epoxy polymers, metal oxides (Al2O3 or Fe2O3), and polyaniline. By the X-ray diffraction analysis, it is shown that, under the action of a constant magnetic field, the period of short-range ordering of the fragments of interstitial molecular links of the epoxy polymer increases. It is demonstrated that the coefficient of linear expansion for the composites formed in constant magnetic fields is much (two times) lower than for ones formed in the absence of magnetic fields; it is also shown that the composites with (PANI, Al2O3) and (PANI, Fe2O3) mixtures are characterized by the increase in conductivity by 3–4 orders of magnitude.

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References

  1. H. Lee and K. Neville, Handbook on Epoxy Resins, McGraw-Hill, New York, 1967.

    Google Scholar 

  2. M. W. Ho, C. K. Lam, K. Lau, et al., “Mechanical properties of epoxy-based composites using nanoclays,” Compos. Struct., 75, No. 4, 415–421 (2006).

    Article  Google Scholar 

  3. C. Chen, R. S. Justice, D. W. Schaefer, and J. W. Baur, “Highly dispersed nanosilica–epoxy resins with enhanced mechanical properties,” Polymer, 49, No. 17, 3805–3815 (2008).

    Article  Google Scholar 

  4. P. J. Hine, R. A. Duckett, A. S. Kaddour, et al. “The effect of hydrostatic pressure on the mechanical properties of glass fiber/epoxy unidirectional composites,” Composites Part A: Appl. Sci. Manufact., 36, No. 2, 279–289 (2005).

    Article  Google Scholar 

  5. J. Cho, J. J. Luo, and I. M. Daniel, “Mechanical characterization of graphite/epoxy nanocomposites by multiscale analysis,” Compos. Sci. Technol., 67, No. 11–12, 2399–2407 (2007).

    Article  Google Scholar 

  6. V. L. Demchenko, V. I. Shtompel’, V. O. Vilens’kyi, and Yu. Yu. Kercha, “Influence of a constant magnetic field on the structure of composites based on epoxy polymer and Fe(ΙΙΙ) or Al(ΙΙΙ) oxide,” Polim. Zh., 30, No. 4, 302–310 (2008).

    Google Scholar 

  7. V. L. Demchenko and V. O. Vilens’kyi, “Influence of magnetic and electric fields on the structure and properties of filled polymers,” Polim. Zh., 31, No. 2, 97–110 (2009).

    Google Scholar 

  8. V. L. Demchenko and V. O. Vilens’kyi, “Influence of a constant magnetic field on the structure and properties of composites on the basis of the epoxy polymer and (Fe2O3, Al2O3) metal oxides,” Zh. Fiz. Dosl., 14, No. 1, 1401(1)–1401(6) (2010).

    Google Scholar 

  9. V. O. Vilens’kyi and V. L. Demchenko, “Influence of the intensity of constant magnetic field on the structure and properties of composites based on epoxy polymers and Fe(III) or Al(III) oxides,” Fiz.-Khim. Mekh. Mater., 45, No. 3, 76–82 (2009); English translation: Mater. Sci., 45, No. 3, 409–416 (2009).

    Article  Google Scholar 

  10. T. Sehei, Means to Obtain Thin Films of Conducting Organic Polymers, Patent 61-266435 (Japan), No. 60-109988; Applic. 21.05.85, Publ. 26.11.86.

  11. V. A. Vilens’kyi, A. E. Fainerman, and Yu. Yu. Kercha, Physical Methods for the Investigation of Polymers [in Russian], Naukova Dumka, Kiev (1981), pp. 71–79.

    Google Scholar 

  12. R. Perret and W. Ruland, “Eine verbesserte Auswertungsmethode fur die Röntgen-kleinewinkelstreuung von Hochpolymeren,” Kolloid Z.—Z. Polym., 247, 835–843 (1971).

    Article  Google Scholar 

  13. O. R. Bilohubka and O. V. Shyichuk, “Solidification of epoxy oligomers by aromatic diamine in microwave fields,” Polim. Zh., 26, No. 3, 201–206 (2004).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry of High-Molecular Compounds, Ukrainian Academy of Sciences, Kiev, Ukraine

    V. L. Demchenko, V. O. Vilens’kyi & V. I. Shtompel’

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  1. V. L. Demchenko
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  2. V. O. Vilens’kyi
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  3. V. I. Shtompel’
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Correspondence to V. L. Demchenko.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 50, No. 3, pp. 101–106, May–June, 2014.

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Demchenko, V.L., Vilens’kyi, V.O. & Shtompel’, V.I. Influence of a Constant Magnetic Field on the Structure and Thermomechanical and Electrophysical Properties of Systems Based on Epoxy Polymers, Metal Oxides, and Polyaniline. Mater Sci 50, 425–430 (2014). https://doi.org/10.1007/s11003-014-9737-0

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  • DOI: https://doi.org/10.1007/s11003-014-9737-0

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