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Non-isothermal crystallization kinetics, optical and structural properties of MgO-doped vanadate glasses

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Abstract

This paper deals with the crystallization kinetics, optical and structural features of V2−xMgxO5−δ (x = 0.15–0.30) glasses under non-isothermal conditions using Lasocka, Kissinger and Augis-Bennett approaches. Raman spectra confirm the layer structure of vanadium in the present glasses. The optical band gap decreases from 2.64 to 2.20 eV with an increase in MgO doping, while refractive index (n) increases from 2.50 to 2.65 with an increase in MgO doping. The activation energy of glass transition and crystallization increase from 150 to 229 kJ mol−1 and 256–442 kJ mol−1, respectively, with the doping of MgO in V2O5. The kinetic parameters calculated from different approaches are found to be in a good agreement with each other. The fragility index increases from 29 to 51 with increasing MgO content in place of V2O5. The values of \({f}_{\text{g}}\) and \({E}_{\text{c}}\) are found to enhance with changes in heating rates due to the strong influence of heating rates on glass transition temperature.

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Acknowledgements

One of the authors (Savidh Khan) thanks Haya Khan, Department of Chemistry, School of Natural Sciences, Shiv Nadar Institutions of Eminence (Deemed to be University), Dadri, Gautam Budh Nagar-201314, UP, India, for her help during UV-visible characterization.

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Authors and Affiliations

  1. Department of Physics, RIMT University, Mandi Gobindgarh, Punjab, 147301, India

    Savidh Khan

  2. Department of Physics and Material Science, Thapar Institute of Engineering and Technology, Patiala, Punjab, 147004, India

    Santosh Kumar & K. Singh

  3. Department of Chemistry, KVSCOS, Swami Vivekanand Subharti University, Meerut, Uttar Pradesh, 25005, India

    Km Abida

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Khan, S., Kumar, S., Abida, K. et al. Non-isothermal crystallization kinetics, optical and structural properties of MgO-doped vanadate glasses. J Therm Anal Calorim (2024). https://doi.org/10.1007/s10973-024-13173-w

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