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Study of structural features and thermal properties of barium hexaferrite upon indium doping

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Abstract

The crystal structure, magnetic and thermal properties of M-type BaFe11.9In0.1O19-doped hexaferrite were investigated. It was found that the crystal structure of this solid solution has hexagonal symmetry with P63/mmc space group (No 194) and a = 5.8992(1) Å, c = 23.2275(7) Å unit cell parameters. It was determined that the average grain size is \(\overline{d }\) = 6 μm. The ferromagnetic-paramagnetic phase transition occurs near TC = 420 °C. It was also established that the water steams that react in active centers are shattered on the surface as a result of the solvothermic reaction being in a weak mutual influence on the temperature interval 30 ≤ T ≤ 317 °C. Thermal transitions repeated as the temperature rises to the highest available values have been established. The oxidation behavior was determined using thermogravimetric spectra in a wide temperature range.

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Acknowledgements

The work was supported by the Russian Science Foundation (Agreement No. 19-72-10071-П).

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Agayev, F.G., Trukhanov, S.V., Trukhanov, A.V. et al. Study of structural features and thermal properties of barium hexaferrite upon indium doping. J Therm Anal Calorim 147, 14107–14114 (2022). https://doi.org/10.1007/s10973-022-11742-5

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