Abstract
Sustainable development and mitigation of the climate changes are one of the main challenges of the circular economy, while the use of food industry residues could make an important contribution in tackling these challenges. In order to improve energy efficiency aspects of the industry residue treatment, generally, the drying process as the first step of the entire processing chain should be further analyzed. Regarding this, a comprehensive kinetic study was performed to provide the detailed mechanism of moisture removal from base raw material. Industrial residues from apple juice production were used for isothermal thermogravimetric analysis in the air atmosphere at different temperatures. Based on experimental data, different kinetic models were applied to determine kinetic parameters and dominant conversion functions. The dependence of the activation energy evaluated by Friedman’s isoconversional method on the conversion degree shows that the drying process is complex one. The mechanism of drying process and corresponding kinetic parameters were determined by multivariate nonlinear regression program (model-based analysis) and checked by modulated isothermal prediction (for quasi-isothermal conditions) and the isothermal prediction (for different isothermal conditions) tests. It was pointed out that temperature-dependent reaction step controlling overall mechanism represents releasing of CO2 which can suppress autocatalytic action of the ethylene, influencing the flavor and texture changes of the apple tissue. Obtained results can be used for prediction of the life-time of studied material, corresponding to selected temperatures and different conversion levels.
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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
FAO. Food wastage footprint. FAO. 2013.
Roos YH. Water activity and glass transition, In: Water activity in foods: fundamentals and applications. Ames, Iowa: IFT Press; 2007.
Mujumdar AS, editor. Handbook of Industrial Drying. 4th ed. Boca Raton: CRC Press; 2014.
Müller J. Convective drying of medicinal, aromatic and spice plants: a review. Stewart Postharvest Rev. 2007;4:1–6.
Berna A, Rosselo C, Canellas J, Mulet A. Drying kinetics of apricots. Engineering and food. Elsevier Science Publishing; 1990. p. 628–36.
Kaymak-Ertekin F. Drying and rehydrating kinetics of green and red peppers. J Food Sci. 2002;67:168–75.
Martynenko A, Janaszek MA. Texture changes during drying of apple slices. Drying Technol. 2014;32:567–77.
Metin Ozguven M, Tarhan S, Polatci H, Telci I. A new way to improve the drying kinetics and final quality of peppermint. J Essent Oil Bear Plants. 2016;19:1368–79.
Martynenko A, Kudra T. Non-isothermal drying of medicinal plants. Drying Technol. 2015;33:1550–9.
Cuervo-Andrade SP, Hensel O. Stepwise drying of medicinal plants as alternative to reduce time and energy processing. IOP Conf Series Mater Sci Eng. 2016;138:12014.
Liapis AI, FreezeDrying BR. Handbook of industrial drying. Boca Raton: CRC Press; 2006. p. 282–309.
Gardeli C, Evageliou V, Poulos C, Yanniotis S, Komaitis M. Drying of fennel plants: oven, freeze drying, effect of freeze-drying time, and use of biopolymers. Drying Technol. 2010;28:542–9.
Litvin S, Mannheim CH, Miltz J. Dehydration of carrots by a combination of freeze drying, microwave heating and air or vacuum drying. J Food Eng. 1998;36:103–11.
Strumillo C, Adamiec J. Energy and quality aspects of food drying. Drying Technol. 1996;14:423–48.
Díaz-Maroto MC, Sánchez Palomo E, Castro L, González Viñas MA, Pérez-Coello MS. Changes produced in the aroma compounds and structural integrity of basil (Ocimum basilicum L) during drying. J Sci Food Agricul. 2004;84:2070–6.
L. I. Handbook of Drying (In Hungarian). Budapest, Hungary: M´u´szaki Könyvkiadó; 1974.
AS. G. Principles of drying theory and techniques of foods (In Hungarian). Mez´o´gazdasa´gi Kiado´; 1976.
Joardder MUH, Karim A, Kumar C, Brown RJ. Determination of effective moisture diffusivity of banana using thermogravimetric analysis. Proc Eng. 2014;90:538–43.
Zhang J, Ma P, Zhang X, Wang B, Wu J, Xing X. Isothermal drying kinetics of paddy using thermogravimetric analysis. J Therm Anal Calorimet. 2018;134:2359–65.
Pani P, Signorelli M, Schiraldi A, Torreggiani D. Osmo-dehydration of apple pulp studied by means of classical and Knudsen thermogravimetric approach. J Therm Anal Calorimet. 2010;102:383–90.
Masłowska J, Więdłocha M. Thermal dehydration of some food products and kinetic parameters of this process. J Therm Anal. 1995;43:123–32.
Rahib Y, Sarh B, Chaoufi J, Bonnamy S, Elorf A. Physicochemical and thermal analysis of argan fruit residues (AFRs) as a new local biomass for bioenergy production. J Therm Anal Calorim. 2021;145:2405–16.
Lacerda LG, da SilvaCarvalhoFilho MA, Bauab T, Demiate IM, Colman TAD, Andrade MMP, et al. The effects of heat-moisture treatment on avocado starch granules; Thermoanalytical and structural analysis. J Therm Anal Calorimet. 2015;120:387–93.
Friedman HL. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. J Polym Sci Part C Polym Symposia. 1964;6:183–95.
Opfermann J. Kinetic analysis using multivariate non-linear regression. J Therm Anal Calorim. 2000;60:641–58.
Manić N, Janković B, Dodevski V. Model-free and model-based kinetic analysis of Poplar fluff (Populus alba) pyrolysis process under dynamic conditions. J Therm Anal Calorimet. 2021;143:3419–38.
Sbirrazzuoli N. Advanced isoconversional kinetic analysis for the elucidation of complex reaction mechanisms: a new method for the identification of rate-limiting steps. Molecules. 2019;24.
Khan MIH, Joardder MUH, Kumar C, Karim MA. Multiphase porous media modelling: a novel approach to predicting food processing performance. Crit Rev Food Sci Nutr. 2018;58:528–46.
Vyazovkin S, Burnham AK, Favergeon L, Koga N, Moukhina E, Pérez-Maqueda LA, et al. ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics. Thermochim Acta. 2020;689:178597.
Lieberman M, Kunishi A, Mapson LW, Wardale DA. Stimulation of ethylene production in apple tissue slices by methionine. Plant Physiol. 1966;41:376–82.
Pirrung MC. Ethylene biosynthesis. 2. Stereochemistry of ripening, stress, and model reactions. J Am Chem Soc. 1983;105:7207–9.
Joardder MUH, Karim A, Kumar C, Brown RJ. Pore formation and evolution during drying. In: Porosity, Establishing the Relationship between Drying Parameters and Dried Food Quality. Springer; 2016.
Segura LA, Badillo GM, Alves-Filho O. Microstructural changes of apples (Granny Smith) during drying: visual microstructural changes and possible explanation from capillary pressure data. Drying Technol. 2014;32:1692–8.
Zlatanovic S, Ostojic S, Micic D, Rankov S, Dodevska M, Vukosavljevic P, et al. Thermal behaviour and degradation kinetics of apple pomace flours. Thermochim Acta. 2019;673:17–25.
Funding
The research was funded by the Ministry of Education, Science and Technological Development of the Republic of Serbia contract no. 451–03-68/2022–14/200105 (N. Manić).
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MM involved in investigation, data curation, and writing—original draft. MK involved in investigation, validation, visualization, and supervision. BJ involved in conceptualization, formal analysis, writing—review and editing, visualization, and supervision. DS involved in investigation, validation, data curation, and supervision. NM involved in investigation, data curation, methodology, writing—Original Draft, writing—review and editing, and supervision. All authors contributed to the study conception and design.
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Milanović, M., Komatina, M., Janković, B. et al. The kinetic study of juice industry residues drying process based on TGA-DTG experimental data. J Therm Anal Calorim 147, 10109–10129 (2022). https://doi.org/10.1007/s10973-022-11289-5
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DOI: https://doi.org/10.1007/s10973-022-11289-5